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Start Over Author "Ruixue Deng" Topic butyl methyl ether
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1. Synthesis of Polysubstituted Cydopentenones via [4+1] Reactions of TIPS-Vinylketenes.

Author

Zhi Li, Moser, William H., Ruixue Deng, and Liangdong Sun

Subjects
*IMINES, *ORGANONITROGEN compounds, *ISOCYANIDES, *BUTYL methyl ether, *KETENES, *OXO compounds
Abstract

An efficient method for preparing a series of polysubstituted cyclopentenones from TIPS-vinylketenes and Kobrich re- agent has been developed in this paper. Additionally, highly substituted cyclopentenones can be prepared via [4+11 reaction of TIPS-vinylketenes with tert-butyl isocyanide and there is a remarkable preference for formation of products with an exocyclic (Z)-imine moiety. [ABSTRACT FROM AUTHOR]

Published
2007
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