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This study investigated the size-segregated carbonaceous components of particulate matter (PM), including ultrafine particles (UFP or PM 0.1 ), across three distinct urban settings in Phnom Penh, Cambodia: an educational site (University of Health Sciences, UHS), an institutional site (Ministry of Environment, MoE), and a residential area near a landfill. A cascade impactor-type sampler equipped with an inertial filter was used to collect size-segregated particles down to UFPs. Carbonaceous species, including organic carbon (OC) and elemental carbon (EC), were analyzed using a thermal/optical carbon analyzer to determine their composition and ratios. The results indicated no significant differences in mass concentration between weekdays and weekends at all sites; however, PM profiles varied across the location. The UHS site displayed higher EC levels in UFP, with concentrations suggesting significant local vehicular emissions, underscored by a lower OC/EC ratio (2.39 ± 1.13) compared to other sites. In contrast, the landfill site exhibited higher OC components in finer particles, suggesting emissions from organic sources such as waste burning and cooking activities, evidenced by higher OC/EC ratios across all particle sizes (e.g., OC/EC ratio in UFP at 3.78 ± 0.98). The MoE site presented a balanced profile with moderate levels of both OC and EC, influenced by its proximity to natural dispersion factors like the Tonle Sap River. Additionally, air mass backward trajectory analysis integrated with hotspot data indicated transboundary influences, particularly from agricultural burning in surrounding provinces, including Vietnam. Therefore, both local and transboundary emissions influenced the PM levels in Phnom Penh city., Competing Interests: Declarations. Ethical approval: This study did not include any tests on clinical samples or animals, so the related considerations are not applicable. Consent to participate: All authors of the article agree to participate in journal submission. Consent for publication: All authors approved the publication of this manuscript. Competing interests: The authors declare no competing interests., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

This study examines slag, fly ash, and deposited particles during melting of dewatered sewage sludge in a pilot plant. In addition, the chemical composition of particles in flue gas was simulated using a thermodynamics program, namely FACTSage 5.2. The results showed that the main components of slag were Al, Fe, Ca, P and Si; the minor components were Na, K, Mg, Cu, and Zn. The main chemical compound of slag was Ca4(Mg,Fe)5(PO4)6. For fly ash particles, heavy metals with the highest concentrations were in the order of Zn and As, Pb, Cu, and Cd, respectively. For non-heavy metals, Al, Fe and P were also found in significant amounts. The majority of deposited particles were composed of elements of Zn, P, S, Na, Fe, Al, Si, and Ca and such chemical compounds as Zn3(PO4)2, AlPO4, FePO4 and Fe(OH)3 while the minority consisted of elements of As, Cu, and Pb. Moreover, the compositions of deposited particles in each chamber differed due to different flue gas temperatures inside. In the secondary chamber at 760 degrees C, the amounts of Fe and Al were higher than Zn, whereas, in the other chambers (600-400 degrees C), the amount of Zn was higher. In other words, at the lower temperature the deposition of Zn was higher than the deposition of Fe and Al. In the water cooling section, volatile elements (i.e. Zn, As, Cu, Pb) were found in the highest concentrations due to a big difference in temperature between the wall surface and flue gas. From the simulation results, most of the elements in the gas phase were found to be chloride compounds, whereas those in the solid phase were in the form of oxide, sulfate, and phosphate compounds.

Seasonal variations in atmospheric ultrafine particulate matter (PM0.1) were monitored in Bangkok, Thailand, from 2016 to 2017. PM0.1-bound organic carbon (OC) and elemental carbon (EC) were collected by a cascade air sampler that can collect PM0.1 and were analyzed by a Thermal-Optical carbon analyzer following the IMPROVE-TOR protocol. The annual average PM0.1 in Bangkok was 14.5 ± 4.7 µg/m3, which is higher than in large Asian cities such as Shanghai and Hanoi. Biomass burning from neighboring areas was shown to increase the particle concentration. Apparent increases in carbon species such as OC and EC, and the OC/EC ratios in the wet and dry seasons were observed; the Char-EC/Soot-EC ratio revealed that the PM0.1 in the Bangkok atmosphere was influenced mainly by vehicle exhausts, even though the influence of biomass burning was greater during the dry season. The effective carbon ratio (ECR) shows that Bangkok’s carbonaceous aerosol is light-absorbing and -scattering. The higher SOC/OC in the dry season indicates the high level of secondary sources forming smaller particles from the combustion sources in Bangkok, increasing light scattering during these periods, and contributing to climate and air quality. The findings of this work are of great importance to air pollutant control policies in urban areas.

The concentration of total suspended particles (TSP) and nanoparticles (PM0.1) over Hat Yai city, Songkhla province, southern Thailand was measured in 2019. Organic carbon (OC) and elemental carbon (EC) were evaluated by carbon aerosol analyzer (IMPROVE-TOR) method. Thirteen trace elements including Al, Ba, K, Cu, Cr, Fe, Mg, Mn, Na, Ni, Ti, Pb, and Zn were evaluated by ICP-OES. Annual average TSP and PM0.1 mass concentrations were determined to be 58.3 ± 7.8 and 10.4 ± 1.2 µg/m3, respectively. The highest levels of PM occurred in the wet season with the corresponding values for the dry seasons being lower. The averaged OC/EC ratio ranged from 3.8–4.2 (TSP) and 2.5–2.7 (PM0.1). The char to soot ratios were constantly less than 1.0 for both TSP and PM0.1, indicating that land transportation is the main emission source. A principal component analysis (PCA) revealed that road transportation, industry, and biomass burning are the key sources of these particles. However, PM arising from Indonesian peatland fires causes an increase in the carbon and trace element concentrations in southern Thailand. The findings make useful information for air quality management and strategies for controlling this problem, based on a source apportionment analysis.

Air sampling for 12 h diurnal and nocturnal periods was conducted at two monitoring sites with different characteristics in Jambi City, Sumatra Island, Indonesia. The sampling was done at a roadside site and a riverside site from 2–9 August, and from 7–13 August in 2019, respectively. A cascade air sampler was used to obtain information on the status, characteristics and behavior of airborne particles with a particular focus on the ultrafine fraction (PM0.1). The number of light vehicles was best correlated with most PM size categories, while those of heavy vehicles and motorcycles with the 0.5–1 μm and with >10 μm for the nocturnal period, respectively. These findings suggest that there is a positive influence of traffic amount on the PM concentration. Using carbonaceous parameters related to heavy-vehicle emissions such as EC and soot-EC, HV emission was confirmed to account for the PM0.1 fraction more clearly in the roadside environment. The correlation between OC/EC and EC for 0.5–1 μm particles indicated that biomass burning has an influence on both in the diurnal period. A possible transboundary influence was shown as a shift in the PM0.1 fraction characteristic from “urban” to “biomass burning”.