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1. Organic Iodide Aided Carbonylation of Terminal Acetylenes with Palladium Catalyst

Author

SadakaneMasahiro, OkumotoHiroshi, XuLong He, and ToriiSigeru

Subjects
Diethylamine, Bicyclic molecule, medicine.drug_class, chemistry.chemical_element, Carboxamide, General Chemistry, Catalysis, chemistry.chemical_compound, chemistry, Polymer chemistry, medicine, Organic chemistry, Aliphatic compound, Carbonylation, Carbon monoxide, Palladium
Abstract

Carbonylation of various terminal acetylenes in the presence of a catalytic amount of organic iodides or amine•HI salt and palladium complexes was found to produce 2-substituted acrylamides in good yields under mild conditions (5 atm, 120 °C, 6 h).

Published
1991
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