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Textile‐based shields are one of the most used solutions for electromagnetic interference (EMI) shielding in the radiofrequency range for several applications, such as personal protection, military, and aircraft. Herein, EMI textile shields are produced based on knitted cotton textile substrates (Jersey and American Fleece) coated with industrial‐grade multiwalled carbon nanotubes (MWCNTs) and graphene nanoplatelets (GNPs). An easy and scalable dip‐pad‐dry process is used to fabricate the textile‐based shields. The shielding effectiveness (SE) is evaluated over the frequency range of 5.85–18 GHz. The MWCNT‐coated American Fleece fabric presents the highest EMI shielding, with an average SE of ≈35.6 dB, which corresponds to an excellent classification for general use applications. Additionally, the electrical properties of the carbon nanomaterials and the thickness of the shields reveal to be correlated with an EMI shielding process mostly through radiation absorption mechanism. Numerical simulations are used to further assist in a thorough investigation regarding the influence of the electrical properties of the nanomaterials on the SE of the resulting coated fabrics. [ABSTRACT FROM AUTHOR]

Textile supercapacitors (TESCs) are an emerging energy storage solution to power smart gadgets integrated on clothes. Herein, efficient solid-state TESCs with different active areas (2–8 cm2) were produced based on cotton fabrics coated with industrial grade multi-walled carbon nanotubes (MWCNTs) as electrodes and a safe polyelectrolyte. The textile electrodes were fabricated by an optimized eco-friendly scalable dip-pad-dry process. The lowest electrical resistance (2.62 Ω cm−2) and most uniform coating of the electrodes were achieved using 10 mg mL−1 CNTs dispersion and 8 dip-pad-dry steps. The TESCs exhibited a specific capacitance of 8.01 F g−1 (9.18 F cm−2) and high cyclability (5000 cycles). The energy and power densities were tuned by changing the electrode area: the largest TESC presented the highest energy density of 6.30 Wh kg−1, which was 14× higher than those of other EDLC-type carbon-based TESCs reported in the literature; the smallest TESC presented the highest power density of 2.72 kW kg−1, being 49× higher than the values reported for comparable systems. Finally, a sensor was powered for 47 min by coupling two TESCs in series (14 cm2). This work demonstrated the ability to produce efficient TESCs using industrial grade MWCNTs by processes implemented in the Textile Industry, boosting technological transfer for high-tech applications. [ABSTRACT FROM AUTHOR]

[Display omitted] • A dual-functional textile device with energy storage and fluorescence was produced. • A fluorescent redox-active solid-gel electrolyte based on ZnS:Mn was prepared for the first time. • The hybrid textile supercapacitor exhibited enhanced energy storage performance. • Excellent cycling stability (100%) after 8000 charge/discharge cycles. • The device could easily power a sensor for ~12 min when charged during 10 s. The evolution of wearable technologies boosted the development of energy storage textiles that can be charged faster and store energy for longer time. Achieving multifunctionality on textiles is a key milestone towards higher value-added smart products. Herein, we report on the fabrication of a novel dual-functional textile device merging enhanced energy storage performance with optical properties. A redox-active solid-gel electrolyte based on fluorescent manganese(II)-doped zinc(II) sulfide was for the first time used to endow the dual functionality to the device when combined with MWCNT-coated textile electrodes. The textile electrodes were prepared through an eco-sustainable straightforward dip-pad-dry process using a natural cotton fabric substrate. The fluorescent hybrid textile supercapacitor exhibited enhanced energy storage performance relative to the EDLC-type analogue containing the undoped electrolyte, namely 20% higher working voltage (1.64 V), 48% higher energy density (1.63 W h kg−1) and 74% higher power density (641.6 W kg−1). Additionally, it presented excellent cycling stability (100%) after 8000 charge/discharge cycles. The device exhibited intense yellow-orange fluorescence under UV light, while preserving the energy storage functionality. This work demonstrated the versatility of this type of devices for dark environment applications, namely in reflective/safety electronic clothing for nighttime users. [ABSTRACT FROM AUTHOR]

The development of effective dual-function energy harvesting/storage technologies is a milestone demand for the emerging generation of low-consumption autonomous electronics. This work reports the development of a multifunctional thermionic power textile device merging thermal energy harvesting and electrochemical energy storage for application in self-powered systems. An everyday cost-effective non-conductive natural fabric was transformed into an all-solid-state textile-based thermally-chargeable supercapacitor (T-TCSC) via dyeing with multiwalled carbon nanotubes and subsequent assembly with H 3 PO 4 -doped poly(vinyl alcohol) (PVA) solid-gel polyelectrolyte. When subjected to an out-of-plane temperature gradient, the T-TCSC was able to convert the thermal energy into electrical output and store the harvested energy. A Soret coefficient of 1.85 mV K−1 was obtained, which is the highest value achieved so far for TCSCs developed on non-conductive textile substrates reported in literature and ∼10× higher than those of conventional thermoelectric devices. Additionally, a maximum output potential of ∼30 mV was achieved for Δ T = 24.7 K. Concerning the energy storage performance, an energy density of 9.39 μW h cm−2 was obtained at 1.62 mW cm−2 power density. The smart T-TCSC outputs demonstrated its potentialities as a two-in-one self-chargeable textile device that can harvest the thermal energy generated by a temperature gradient, convert it into electrical energy and simultaneously store it. [Display omitted] • Design and assembly of textile-based system merging energy generation and storage. • All-solid-state device produced on natural fabric through scalable dyeing/coating. • Simultaneous thermal-to-electrical energy conversion and supercapacitive storage. • A Soret coefficient S i = 1.85 mV K−1 and maximum V output = 30 mV@Δ T = ∼25 K were reached. • Highest S i reached so far for TCSCs produced on non-conductive textile substrates. [ABSTRACT FROM AUTHOR]