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Sandy-conglomerate reservoir has gradually become a major target of oil and gas exploration. Complex diagenetic process and diagenetic fluid play a significant role in affecting reservoir heterogeneity. Carbonate cements form at various stages of the diagenesis process and record various geological fluid information. Recently, one-billion-ton sandy conglomerate oil field was exposed in Triassic Baikouquan Formation, Mahu sag, Junggar Basin. Therefore, an integrated study applying casting thin sections, cathodeluminescence, fluorescence, carbon and oxygen stable isotopes, electronic probe microanalysis and aqueous fluid inclusions measurements was performed in order to identify the types of carbonate mineral and its representative diagenetic environment and discuss the influences of different CO2 injections on reservoir quality. The main findings are as follows: The reservoir is mainly composed of 70.33% conglomerate and 16.06% coarse-grained sandstone. They are characterized by low compositional maturity and abundant lithic debris. Four types carbonate cements are identified according to the petrological and geochemical characteristics, including two types of Mn-rich calcite, ferroan calcite, siderite and dawsonite. They display an unusual broad spectrum of δ13C values (−54.99‰ to +8.8‰), suggesting both organic and inorganic CO2 injections. The δ13C values of siderite are close to 0, and its formation is related to meteoric water. The δ13C values of ferroan calcite and the occurrence of dawsonite indicate the trace of inorganic mantle-derived magmatic fluids. The δ13C values and trace elements of Mn-rich calcite record the information of hydrocarbon-bearing fluids. The fluid inclusions measurement data and reservoir properties and oil-test data show that the oil content of reservoir is not only affected by the formation time of different cements, but also by the relative content of dissolution and cementation. For these reservoirs altered by carbonate cements, it does not cause poor oil-bearing due to blockage of secondary minerals. [ABSTRACT FROM AUTHOR]

The characteristics, heterogeneous distribution and origins of carbonate cements within beach-bar sandstones in the Boxing Sag and implications on the mass transfer from mudstone to sandstone during diagenetic process was investigated systematically by an integrated analysis invoking petrography, carbon and oxygen stable isotopes and porosity-permeability, with specific references to the contrasts among the sharp (S)-change lithology (S-mudstone-S-sandstone interbeds), the gradual (G) -change lithology (G-mudstone-G-sandstone interbeds) and the center of sandstones. There are distinct differences in the occurrence, content, distribution, carbon and oxygen isotopic compositions and precipitation temperatures of the carbonate cements among the S-sandstone, G-sandstone and center of sandstone. Material sources of carbonate cements in the S-sandstones are mainly derived from the diagenetic alterations of the nearby S-mudstones through mass transfer with the participation of organic CO 2 , while in the G-sandstones, the material sources are mainly internal and originated from the calcareous matrix. Dissolution of feldspars and conversion of clay minerals provided the main materials for the precipitation of carbonate cements in the center of sandstones. Mass transfer of carbonate cements mainly occurred between the S-mudstones and the S-sandstones with limited transmission distance, which controlled the distribution of carbonate cements in the S-mudstones. There was almost no mass transfer between the G-mudstones and G-sandstones because of the small concentration gradient, instead, the depositional components and recrystallization controlled the carbonate distribution of the G-sandstones. • Material sources of carbonates in S-sandstones were mainly from nearby S-mudstones. • Material sources of carbonates in G-sandstones were mainly from in situ recrystallization. • Mass transfer of carbonate cements mainly occurred through sharp contact between mudstone and sandstone. [ABSTRACT FROM AUTHOR]

• Carbonate cements and chlorite can alter some pore spaces from water-wet to oil-wet. • High oil saturation occurred in tight reservoirs with moderate carbonates or chlorite. • The high quality reservoirs mainly located in between with sandstone-mudstone interfaces and central parts of the sand bodies. Oil accumulation, being difficult and complicated, is an important issue in petroleum exploration researches. Authigenic minerals, such as carbonate cements and chlorite, can in certain reservoirs alter the wettability of some pore spaces from water-wet to oil-wet. Generally, these oil-wet pore spaces are favorable for oil accumulation. The alteration of reservoir wettability induced by authigenic minerals and the impacts on oil accumulation in tight sandstone reservoirs were investigated using a suite of mineralogical and geochemical characterization techniques, including thin section observation, SEM-EDS, XRD, QEMSEM, CL, quantitative grain fluorescence (QGF), fluorescence spectral analysis, contact angle measurement and sealed coring oil saturation testing on the fourth member of the Lower Cretaceous Quantou Formation (K 1 q 4) in the southern Songliao Basin, China. The study shows that the tight sandstone reservoirs are compositionally immature with detrital grains distributed homogeneously. Quartz, carbonates and clay minerals that show heterogeneous distribution characteristics are the major authigenic minerals in some parts of the intergranular pores. The detrital mineral assemblage suggests that the reservoir rocks at deposition and before diagenesis had characterized by strong water-wet properties. With the development of authigenic minerals, carbonate cements and authigenic chlorite tend to alter the wettability of some parts of the existing pore spaces from water-wet to oil-wet. In the K 1 q 4 sandstone reservoirs, oil prefers to accumulate in the cemented residual pore spaces around carbonate cements and chlorite. Reservoirs containing about 4–5% carbonate cements are suggested to be more preferable to oil accumulation. These reservoirs are mainly located between sandstone-mudstone interfaces and central parts of the sand bodies. Chlorites have mainly two effects: on one hand, chlorite alters the wettability of existing pore spaces and provides preferential accumulation sites for oil in the tight sandstone reservoirs, on the other hand it can reduce the adhesion of oil through forming "clay-oil flocs" and promote further migration. Consequently, the reservoirs with moderate amount of carbonate cements or chlorite always show relative high oil saturation in the K 1 q 4 tight sandstones. [ABSTRACT FROM AUTHOR]

The lacustrine deep-water gravity-flow sandstone reservoirs in the third member of the Shahejie Formation are the main exploration target for hydrocarbons in the Dongying Sag, Eastern China. Carbonate cementation is responsible for much of the porosity and permeability reduction in the lacustrine deep-water gravity-flow sandstone reservoirs. The sandstones are mainly lithic arkose with an average framework composition of Q 43 F 33 L 24 . The carbonate cements are dominated by calcite, ferroan calcite, ankerite and a small amount of dolomite. The calcite and ferroan calcite are mainly poikilotopic blocky crystals, while the dolomite and ankerite are mainly euhedral rhombohedra crystals filling intergranular and intragranular pores. The relatively positive δ 13 C values (−2‰ to +3.9‰) of the carbonate cements in the sandstone reflect a mainly inorganically sourced carbon. From 32 Ma to 25 Ma, the pore water was rich in bicarbonate and Ca 2+ due to carbonate dissolution in mudstone, and which were transported with the pore water from mudstone to sandstone via advection and precipitated calcite cementation in thinly bedded sandstones and some high permeability zones in the middle of medium-to-thick sandstone beds. From 12 Ma to present, abundant Ca 2+ , Fe 3+ , Fe 2+ , Mg 2+ and bicarbonate had been transported from mudstone to sandstone via diffusion to form tight ferroan calcite cementation in the upper and lower parts of the medium-to-thick bedded sandstones. Ankerite is mainly distributed in the reservoirs associated with oil migration or charge, because change of Fe 3+ to Fe 2+ from oil charge may supply sufficient Fe 2+ for ankerite precipitation. The center of sandstone beds (>0.6 m) is with potential of high-quality reservoirs in the research area. Carbonate cementation appears to be an important factor that controls the accumulation of oil in deep-water gravity-flow sandstone reservoirs in the study area. [ABSTRACT FROM AUTHOR]

Understanding reservoir heterogeneity and associated diagenesis, have a paramount importance for efficient petroleum exploration and development strategies. Diagenetic variations and factors that control these processes have, therefore, been investigated in this study using petrographic and geochemical methods, including cathodoluminescence, scanning electron microscopy, x-ray fluorescence, electron probe microanalyses and stable isotope analysis. Mechanical compaction and chemical diagenesis trends have obviously varied as a function of rock types and geological locations. The conglomerate reservoirs with high content of tuffaceous matrix and characterized by poor sorting showed stronger compaction. The tuffaceous matrix displays a large degree of dissolution during the progressive burial diagenesis due to its thermodynamic instability. The tuffaceous matrix in Na-rich conglomerate reservoir rocks mainly transformed into analcite, while it transformed into illite in K-rich conglomerate reservoir rocks. In most conglomerate reservoirs far away from deep-rooted faults, calcite cements are indicated to have been sourced from the decarboxylation of organic matter in the interbedded mudstones. Carbonate cements in conglomerate reservoirs near the deep-rooted faults possibly formed from hydrothermal fluids or thermochemical oxidation of pre-existing methane accumulations. This study can serve us an excellent example for the control of sediment composition and paleo-fluid evolution on diagenetic variations in fan-delta conglomerate reservoirs. • Compaction and dissolution in conglomerate reservoirs were controlled by sediment composition and texture. • Authigenic silicoaluminate minerals formation in conglomerate reservoirs were controlled by sediment composition. • Carbonate cements formation in conglomerate reservoirs were controlled by paleo-fluids evolution. [ABSTRACT FROM AUTHOR]

Diagenesis plays a crucial role in shale oil reservoir formation. However, complex organic-inorganic interactions result in pore system formation and heterogeneity changes at the centimeter, or even micrometer scale, which controls the evolution of shale oil reservoirs. In this paper, an integrated approach including core observation, thin section observation, cathodoluminescence thin section observation, scanning electron microscope, μ-XRF analysis, electron microprobe analysis, AMICS analysis, LA-ICP-MS analysis, and isotope analysis was used to clarify the laminae combination carbonate-rich shale, diagenetic alterations in different types of shale laminae and the controls on shale oil reservoir formation. According to the lamina combination, the carbonate-rich shale in the Permian Lucaogou Formation can be divided into three types. They are shale consists of dolomitic lamina and terrigenous felsic lamina (Type A shale), shale consists of calcite-rich tufaceous lamina and terrigenous felsic lamina (Type B shale) and shale consists of calcareous lamina and tufaceous lamina (Type C shale). Dolomite cementation is the major diagenesis in terrigenous felsic lamina of Type A shale. The dolomite can be identified as the early stage forming from recrystallization of micrite dolomite, and the late stage precipitate from adjacent dolomitic lamina. In the terrigenous felsic lamina of Type B shale, however, the calcite cementation is the dominated diagenesis, which was sourced from adjacent calcite-rich tufaceous lamina. Also, some feldspar dissolutions occurred in terrigenous felsic lamina during organic matter evolution. For the Type C shale, the main diagenetic alteration is micrite calcite recrystallization in calcareous lamina. The dissolution and precipitation of carbonate minerals between different laminae of carbonate-rich shale reveal that the organic matter evolution significantly influence the diagenetic alterations of inorganic minerals. Particularly, the diagenetic mass transfer and redistribution at the micro-scale in a relatively diagenetic system were confirmed by organic-inorganic interactions in laminated shale. In this process, dissolution pores and recrystallization pores have provided considerable reservoir pores for shale oil. • The laminae combination and diagenetic alterations of carbonate-rich shale were identified. • The diagenetic mass transfer at the micro-scale during organic-inorganic interactions in laminated shale were clarified. • The pores induced by diagenetic mass transfer within a closed system is crucial for shale reservoir formation. [ABSTRACT FROM AUTHOR]

The Ordovician carbonate fault-controlled reservoir in the Shunnan area is substantially different from the typical karst reservoir closely related to an unconformity. The development of fault-controlled reservoirs is controlled by the deep and large strike-slip fault in the Middle Caledonian period. The characteristics, diagenesis types, diagenetic fluid evolution characteristics, fluid-rock interactions, and reservoir response of fault-controlled reservoirs were investigated systematically by analyzing 3D seismic, logging, and drilling core data. Production data, reservoir petrology, and chemical filling geochemistry were also used. The formation and evolution of fault-controlled reservoirs are affected by the coupling of the structure, lithofacies, and fluid. The dolomitization in the quasi-syngenetic period in the early stage of Episode I in the Middle Caledonian provided the material basis for the development of fault-controlled reservoirs. The Mg-rich high-salinity thermal fluid in the late Caledonian and the Early Hercynian provided a constructive transformation for the development of fault-controlled reservoirs. In contrast, the transformation of reservoirs by the Si-rich magmatic thermal fluid in the late Hercynian was mainly destructive, and the action range of the deep thermal fluid was strongly controlled by strike-slip fault zones. The releasing bend and superimposed parts of different structural styles in the fault zone have high activity intensity. These are areas where dissolution and transformation of the fluid occur preferentially. Dolomite is often more conducive to the development of fault fracture zones and promotes the dissolution and transformation of the deep thermal fluid. Therefore, the strike-slip fault cutting through the basement causes the hydrothermal fluid to enter the fault, dissolving carbonate minerals and forming a hydrothermal-modified fault-controlled reservoir composed of fractures, dissolution pores, and dolomite intercrystalline pores. The results provide a new approach and direction for the study of different types of deep and ultra-deep carbonate reservoirs. • The fault zone controls the distribution of fault-controlled reservoirs. • The dolomitization and Mg-rich thermal fluid are factors affecting reservoirs. • Dolomite promotes fault development and thermal fluid dissolution. [ABSTRACT FROM AUTHOR]

Reservoir quality is the key parameter controlling shale oil enrichment. However, the complicated lithofacies, which control diagenesis, result in reservoir heterogeneity in the shale strata, creating challenges for reservoir prediction. Combining with the detail analysis of inorganic and organic geochemistry, characteristics of the main lithofacies and diagenetic alteration were investigated in Permian Lucaogou Formation, Jimusar sag, Junggar Basin. Laminated rocks with laminae combinations containing pyroclastic and terrigenous clastic laminae, terrigenous clastic and dolomite laminae, and pyroclastic and carbonate laminae were identified. Massive rocks mainly includes dolomicrite, dolomitic tuff, silt dolostone, dolomitic siltstone, and tuffaceous siltstone. Feldspar dissolution and carbonate cementation were the two dominant diagenetic types, further causing heterogeneity of the shale oil reservoirs. Feldspar dissolution generally occurred in laminated rocks containing pyroclastic laminae with low content of carbonate minerals (PL1), as well as in their adjacent interbedded siltstones. Carbonate cementation generally occurred in laminated rocks containing carbonate laminae, as well as in their adjacent interbedded siltstones. Whether in laminated and massive rocks, sparry carbonate crystals were also precipitated adjacent to organic matter and in microfractures. In the burial processes, enriched transition metal elements of V and Ti in pyroclastic laminae promote catalytic pyrolysis of organic matter. Abundant CO 2 produced during the catalytic pyrolysis promoted feldspar dissolution. Dissolution of sedimentary carbonate minerals by organic acids and CO 2 provided the material sources for secondary carbonate cements. It promoted the recrystallization and re-precipitation of sparry carbonate crystals adjacent to organic matter and in the terrigenous clastic laminae or interbedded siltstones. Ca2+, Mg2+ Sr2+, Fe2+, and Mn2+ produced by the transformation of smectite to illite in the pyroclastic laminae also provided Ca source for secondary carbonate cements. External diagenetic fluids providing materials along microfractures is another genesis of carbonate cements in the Permian Lucaogou Formation. • Petrographic features in the shale strata in Permian Lucaogou Formation were identified based on in situ analytical method. • Differential feldspar dissolution and carbonate precipitation generally occurred in different lithofacies. • Catalytic pyrolysis of organic matter in presence of transition metal elements in pyroclastic laminae promoted dissolution. • Development of carbonate cements in the shale strata were mainly provided by three material sources. [ABSTRACT FROM AUTHOR]

The influence of oil-wet calcite cements on oil migration in clastic reservoirs is of significant interest in the field of petroleum exploration. However, the microscopic migration of oil in microscopic pore spaces with oil-wet calcite cements has not been directly observed. Microscopic observations of oil migration were conducted in a glass micromodel at normal temperature and pressure to investigate the influence mechanism of oil-wet calcite cements on oil migration in pore spaces. The calcites were precipitated as cements prior to the oil migration. A two-dimensional glass micromodel with two interconnected spaces with the same pore throat structures was used in the experimental study. A new method to create firmly adhering calcites was used to precipitate equal amounts of calcites in the two interconnected spaces. The oil migration was recorded in real-time under a microscope throughout the experiment. The experimental results show that oil migration occurs faster in spaces with than without oil-wet calcites. During the oil migration in the pore-throat spaces, the oil migrates towards the surfaces of the oil-wet calcites when the oil is in contact with the calcites. The presence of oil-wet calcites significantly reduces the oil breakthrough pressure. The electrostatic attraction between the carboxylic groups and calcites and the intermolecular forces between the carboxylic groups and organic molecules in the oil cause the oil migration towards the surfaces of the oil-wet calcites. The experimental results indicate that oil preferentially migrates into clastic reservoirs that possess appropriate amounts of oil-wet calcite cements precipitated prior to oil emplacement. • Experimental method that allows calcite to precipitate and adhere tightly in glass micromodel was developed. • Microscopic processes of the influence of oil-wet calcites on oil migration in pore spaces were observed in micromodel. • Mechanism of oil-wet carbonate minerals affecting oil migration and accumulation in pore spaces was discussed. [ABSTRACT FROM AUTHOR]