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Your search keyword '"Andraos J"' showing total 2 results
Start Over Author "Andraos J" Topic carboxylic acids
2 results on '"Andraos J"'

1. Kinetics and mechanism of the isomerization of 1H-indene-1-carboxylic acid to 1H-indene-3-...

Author

Andraos, J. and Kresge, A.J.

Subjects
*ISOMERIZATION, *CARBOXYLIC acids, *CHEMICAL equilibrium, *BIOCHEMICAL mechanism of action
Abstract

Reports on the kinetics and mechanism of the isomerization of 1H-indene-1-carboxylic acid to 1H-indene-3-carboxylic acid in aqueous solution. Determination of the keto-enol equilibrium constants and acid dissociation constants of the keto and enol forms; Implication on the photolysis of diazonaphthoquinones.

Published
1994
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2. Flash photolytic generation and study of ketene and carboxylic acid enol intermediates formed by...

Author

Andraos, J. and Chiang, Y.

Subjects
*DIAZO compounds, *KETENES, *CARBOXYLIC acids, *FLASH photolysis
Abstract

Describes the flash photolysis of five diazonaphthoquinones in aqueous solution. Production of ketene and carboxylic enol intermediates preceding the ultimate indenecarboxylic acid reaction products; Catalysis of the decay of the two intermediates.

Published
1993
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