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Start Over Author "Velo-Heleno, Isabel" Topic catalase activity
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1. A Dinuclear Copper(II) Complex Electrochemically Obtained via the Endogenous Hydroxylation of a Carbamate Schiff Base Ligand: Synthesis, Structure and Catalase Activity.

Author

Fernández-Fariña, Sandra, Velo-Heleno, Isabel, Rodríguez-Silva, Laura, Maneiro, Marcelino, González-Noya, Ana M., and Pedrido, Rosa

Subjects
*SCHIFF bases, *HYDROXYLATION, *COPPER, *COPPER compounds, *MAGNETIC susceptibility, *ELECTRIC batteries, *CARBAMATE derivatives, *ELECTRON donors, *CATALASE
Abstract

In the present work, we report a neutral dinuclear copper(II) complex, [Cu2(L1)(OH)], derived from a new [N,O] donor Schiff base ligand L1 that was formed after the endogenous hydroxylation of an initial carbamate Schiff base H2L coordinated with copper ions in an electrochemical cell. The copper(II) complex has been fully characterized using different techniques, including X-ray diffraction. Direct current (DC) magnetic susceptibility measurements were also performed at variable temperatures, showing evidence of antiferromagnetic behavior. Its catalase-like activity was also tested, demonstrating that this activity is affected by temperature. [ABSTRACT FROM AUTHOR]

Published
2024
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