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The rhodium-catalyzed selective cyanation of CH bonds of indolines and indoles with N-cyano- N-phenyl- para-methylbenzenesulfonamide is described. This protocol offers a facile access to C-7 cyanated indolines and C-2 cyanated indoles with high site selectivity and excellent functional group tolerance. [ABSTRACT FROM AUTHOR]

A highly efficient palladium-catalyzed oxidative ortho-acylation of O-methyl ketoximes and O-methyl aldoximes with benzylic and aliphatic alcohols from the alcohol oxidation level is described. This protocol potentially provides new opportunities to use readily available alcohols as starting materials for catalytic reactions, and represents a catalytic alternative to transcend the barriers imposed by classical Friedel-Crafts acylation. [ABSTRACT FROM AUTHOR]

A palladium-catalyzed ortho-acylation of N-benzyltriflamides with aldehydes via direct sp2 CH bond activation is described. Benzylamines with a triflamide directing group in the presence of palladium acetate, acetic acid, and tert-butyl hydroperoxide as an oxidant can be effectively coupled with aryl and alkyl aldehydes to provide ortho-acyl- N-benzyltriflamides with a high regioselectivity. [ABSTRACT FROM AUTHOR]

A diagram of the Mild Rh(III)-Catalyzed C7-Allylation of Indolines with Allylic Carbonates is presented.

gives various allylic alcohols and terminal allylated products [ABSTRACT FROM AUTHOR]

Symmetrically substituted azobenzenes react with ethyl glyoxalate, and depending on the electronic properties of the aryl substitutents either a single or a mixture of two indazole products is formed. [ABSTRACT FROM AUTHOR]

The article presents chemical equations related to the article "Rhodium(III)-Catalyzed Heteroatom-Directed C-H Allylation with Allylic Phosphonates and Allylic Carbonates at Room Temperature" by and others, published in the "Tetrahedron" in 2016.

The reaction of N-pyrimidinylindoles and -pyrroles with alkyl- and aryl isocyanates affords the corresponding 2-carboxamides. [ABSTRACT FROM AUTHOR]

The method offers access to highly substituted scaffolds of biologically active compounds, the synthesis of which can be scaled up. [ABSTRACT FROM AUTHOR]

Other amide directing groups such as diethyl, methyl, dimethyl, or morpholinyl amido groups deliver the corresponding products with lower yields and lower regioselectivity than the pyrrolidinyl group. [ABSTRACT FROM AUTHOR]

An abstract to the article "Rh-Catalyzed Oxidative C-C Bond Formation and C-N Bond Cleavage: Direct Access to C2-Olefinated Free (NH)-Indoles and Pyrroles" by Satyasheel Sharma, Sangil Han, Mirim Kim, Neeraj Kumar Mishra, Jihye Park, Youngmi Shin, Jimin Ha, and colleagues is presented.

Title compounds (III), (V), and (X) are prepared via Rh-catalyzed C-H bond functionalization directed by a triflamide moiety, followed by an intramolecular aza-Mannich cyclization. [ABSTRACT FROM AUTHOR]

A palladium-catalyzed oxidative coupling of arene C-H bonds with benzylic ethers via C-H bond activation is described. [ABSTRACT FROM AUTHOR]

The title reaction represents a catalytic alternative to classical Friedel-Crafts acylation and proceeds with excellent levels of regio- and chemoselectivity and high functional group tolerance. [ABSTRACT FROM AUTHOR]

A wide range of biologically active ortho-acylated phenol derivatives is prepared using a Pd-catalyzed process requiring a pyridinyl directing group at oxygen. [ABSTRACT FROM AUTHOR]

The described approach represents the first ortho-acylation of the phenol derivatives. [ABSTRACT FROM AUTHOR]

An efficient protocol for the title reaction is developed. [ABSTRACT FROM AUTHOR]