1. Nickel Catalysts on Carbon-Mineral Sapropel-Based Supports for Liquid-Phase Hydrogenation of Nitrobenzene.
- Author
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Terekhova, Elena N., Belskaya, Olga B., Izmaylov, Rinat R., Trenikhin, Mikhail V., and Likholobov, Vladimir A.
- Subjects
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NICKEL catalysts , *NITROBENZENE , *NICKEL sulfide , *CATALYST supports , *HYDROGENATION , *CATALYTIC activity - Abstract
Nickel catalysts with carbon-mineral supports derived from sapropel were synthesized; the effect exerted by the nature of the support (type of the initial sapropel) and active component precursor on the activity of the catalysts in the model reaction of liquid-phase nitrobenzene hydrogenation was studied. The catalysts, synthesized using the support with a smaller fraction of carbon, were more active irrespective of the precursor nature. The highest activity was observed for the catalysts synthesized from nickel nitrate and formate; nitrobenzene conversion was 65% and 51%, respectively, after 1 h of reaction. The catalysts retained high activity after six reaction cycles at 100% aniline selectivity. The presence of sulfur in the nickel precursor deteriorated the catalytic activity (convection less than 3%) due to formation of the sulfide phase. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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