1. Recent advances in improving SO2 resistance of Ce-based catalysts for NH3-SCR: Mechanisms and strategies.
- Author
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Song, Jiayao, Sun, Xin, Zhang, Guomeng, Cheng, Siyuan, Xu, Yichao, and Jiang, Ye
- Subjects
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CATALYSTS , *CATALYSIS , *COAL-fired power plants , *AMMONIUM sulfate , *METALS - Abstract
• Major SO 2 deactivation mechanisms of Ce-based catalysts are summarized. • The positive and negative effects of metal sulfates on Ce-based catalysts are discussed. • Regulatory measures against SO 2 poisoning are proposed. Selective catalytic reduction with ammonia (NH 3 -SCR) technology is an effective process for industrial flue gas denitrification. Ce-based catalysts are widely studied due to their excellent redox properties and superior oxygen storage and release capacity (OSC). However, the unavoidable presence of SO 2 and H 2 O in the coal-fired flue gas leads to their limitations in the application of denitrification technology. SO 2 poisoning not only causes the formation of metal sulfates, but its synergistic interaction with H 2 O also results in the deposition of ammonium sulfate species. All this leads to severe deactivation of Ce-based catalysts in NH 3 -SCR. The development of Ce-based catalysts with excellent sulfur and water resistance is an urgent requirement for SCR technology. This review elucidates the poisoning mechanism of SO 2 , and analyzes the effects of metals/non-metals modification and structural optimization on the anti-SO 2 performance of Ce-based catalysts. This provides the reference and guidance for the subsequent development of Ce-based catalysts resistance to SO 2. [Display omitted] [ABSTRACT FROM AUTHOR]
- Published
- 2024
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