Search

A high voltage cathode material, LiNi0.5Mn1.5O4, is synthesized with a two-step approach, in which the nickel–manganese oxalate precipitate is firstly obtained by adding oxalic acid to the solution of nickel and manganese ions precursors, followed by calcining the oxalates to obtain spinel nickel–manganese oxide, incorporating lithium ions with ball milling and calcining at 900 °C for 15 h. The materials are characterized with TG, XRD, SEM, BET and FTIR; it is revealed that both nickel–manganese oxide and final LiNi0.5Mn1.5O4 have well defined spinel structure. The LiNi0.5Mn1.5O4 spinel materials exhibit high capacities and good cyclic stability, the capacity of the materials is in the range from 126 to 136 mAh −1, depending on the calcining temperatures. The sample calcined at an optimal temperature of 900 °C exhibits best performance, the capacity is high up to 136 mAh g−1 at tenth cycle and the capacity retention after 50 cycles is 93%. For the sample prepared by mixing and milling oxalate with lithium salt, the discharge capacity is only 115 mAh g−1. We suggest that the spinel oxide derived from oxalate may play an important role for the high performance and high stability of the final cathode materials. [ABSTRACT FROM AUTHOR]

Highly effective cathode materials are critical to improve existing Li–O 2 batteries. In this paper, we report a free-standing Co 3 O 4 @NiCo 2 O 4 sheet array cathode, which is prepared by in-situ growing an array of sword-like cobalt-based metal-organic framework (Co-MOF) sheets on a carbon cloth (CC) substrate, followed by impregnated with nickel nitrate solution and pyrolyzed in air flow. The Co 3 O 4 @NiCo 2 O 4 /CC cathode exhibits excellent ORR/OER bifunctional activity and high cathodic performance in a Li–O 2 battery, achieving a specific capacity of 10645 mAh g−1 and a stability of 225 cycles. We suggest the high performance of our cathode can be ascribed to its well-defined 3D sheet array structure, which can facilitate O 2 diffusion and electrolyte impregnation, provide sufficient space for the discharge products, and the synergistic effect between Co 3 O 4 and NiCo 2 O 4. This work provides an effective method for the rational design of electrode composition and structure. Image 1 • A sword-like Co 3 O 4 @NiCo 2 O 4 nanosheet array cathode for Li–O 2 battery is prepared. • The cathode exhibited enhanced bifunctional OER/ORR activities in Li–O 2 batteries. • The high performance can be ascribed to its hybrid and array structure. • A high specific capacity of 10645 mAh g−1 with stability of 225 cycles is achieved. [ABSTRACT FROM AUTHOR]