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Li 2 MSiO 4 (M = Mn, Fe, Co, Ni, et al.) has received great attention because of the theoretical possibility to reversibly deintercalate two Li + ions from the structure. However, the silicates still suffer from low electronic conductivity, sluggish lithium ion diffusion and structural instability upon deep cycling. In order to solve these problems, a “hard-soft” templating method has been developed to synthesize three-dimensionally ordered macroporous (3DOM) Li 2 FeSiO 4 /C composites. The 3DOM Li 2 FeSiO 4 /C composites show a high reversible capacity (239 mAh g −1 ) with ∼1.50 lithium ion insertion/extraction, a capacity retention of nearly 100% after 420 cycles and excellent rate capability. The enhanced electrochemical performance is ascribed to the interconnected carbon framework that improves the electronic conductivity and the 3DOM structure that offers short Li ion diffusion pathways and restrains volumetric changes. [ABSTRACT FROM AUTHOR]