1. Lithium Ion Battery Separators Based On Carboxylated Cellulose Nanofibers From Wood
- Author
-
Kim, Hyeyun, Guccini, Valentina, Lu, Huiran, Salazar-Alvarez, German, Lindbergh, Göran, and Cornell, Ann M.
- Subjects
separator ,Kemiteknik ,protonation ,Li-ion batteries ,Chemical Engineering ,TEMPO-oxidized cellulose ,cellulose - Abstract
Carboxylated cellulose nanofibers, prepared by TEMPO-mediated oxidation (TOCN), were processed into asymmetric mesoporous membranes using a facile paper-making approach and investigated as lithium ion battery separators. Membranes made of TOCN with sodium carboxylate groups (TOCN-COO-Na+) showed capacity fading after a few cycles of charging and discharging. On the other hand, its protonated counterpart (TOCN-COOH) showed highly improved electrochemical and cycling stability, displaying 94.5% of discharge capacity maintained after 100 cycles at 1 C rate of charging and discharging. The asymmetric surface porosity of the membranes must be considered when assembling a battery cell as it influences the rate capabilities of the battery. The wood-based TOCN-membranes have a good potential as an ecofriendly alternative to conventional fossil fuel-derived separators without adverse side effects. QC 20190326
- Published
- 2019