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Surface charge density is a key factor that greatly enhances the performance of a natural-based triboelectric nanogenerator (TENG), which is essential for future sustainable sensing and harvesting devices. This work introduced a conductive interlayer between a main frictional layer and electrode. This approach can suppress the charge recombination rate and improve the amount of charges produced during the triboelectrification process. Bacterial cellulose (BC) film was selected as a main frictional layer for the TENG. A conductive nanomaterial, i.e. silver flake, was incorporated into the BC film as an intermediate layer for enhancing TENG performance. As firstly reported, the maximum electrical outputs for the multi-layer BC structure could be found when using silver flake/BC composite (ratio 1:5) as an intermediate layer, which has 122 V and 8.2 µA of output voltage and current, respectively. This is higher than the output voltage and current of a single layer BC TENG by approximately 3 and 8 times, respectively. The maximum output power of ∼440 µW is achieved by connecting with a load resistor of ∼10 MΩ. This demonstrates an efficient strategy for designing a high performance energy harvester by adding an intermediate layer for the target of practical purposes in sustainable systems. [ABSTRACT FROM AUTHOR]

There is a need to develop inexpensive, lightweight, and flexible high‐performance triboelectric nanogenerators (TENGs) from renewable resources. Here, a multifunctional cellulose filter paper (CFP)‐based TENG consisting of dielectric Ti0.8O2 nanosheets (Ti0.8O2 NSs) and conducting Ag nanoparticles (Ag NPs) is prepared by a simple dip coating method. The incorporation of dielectric Ti0.8O2 NSs onto the CFP significantly improves charge generation, while the inclusion of Ag NPs provides an electrically conductive path for charge transportation. The presence of these fillers can be deduced from XRD, SEM, EDS, X‐ray photoelectron spectroscopy, and Raman spectroscopy. Their distribution is visualized in 3D by synchrotron radiation X‐ray tomography. The present CFP‐based TENG provides an output voltage and current density of ≈42 V and ≈1 µA cm−2, respectively with the power density of ≈25 µW cm−2. It is capable of lighting up 40 light‐emitting diode bulbs and charging a 0.22 µF capacitor to 8 V in only 5 s. The developed TENG is also capable of detecting simple human motions, i.e., finger tapping, finger rubbing, and foot trampling. This work offers a facile design of low cost yet efficient paper‐based TENG by dual modification with multifunctional nanomaterials, and also demonstrates its use as a feasible power source that not only drives small electronics, but also scavenges energy from human actions. [ABSTRACT FROM AUTHOR]

Two-dimensional (2D) materials have emerged as a promising functional filler in nanocomposites due to their unique anisotropy and resilience to harsh conditions. We report herein the use of Ti 0.91 O 2 nanosheets as a protective component against γ -irradiation to cellulose paper. The titanate nanosheets were prepared via a sequence of solid-state synthesis of lepidocrocite-type Cs 0.7 Ti 1.825 O 4 , proton exchange to H 0.7 Ti 1.825 O 4 ·H 2 O, and exfoliation with tetrabutylammonium hydroxide. The nanosheets were incorporated into the commercial cellulose filter paper by a simple dip coating up to 0.6 mg cm−2, equivalent to 10 wt% TiO 2. The nanosheets distribution was demonstrated by energy dispersive X-ray (EDX) mapping, synchrotron radiation X-ray tomographic microscopy (SRXTM), and atomic force microscopy (AFM). It is found that γ -irradiation (up to 50 kGy) destroyed the cellulose I β crystallinity of uncoated paper, but this is less pronounced in the cellulose/titanate nanosheets composite. This was also confirmed by the lack of a 235 nm-absorption characteristics of irradiation-induced decomposition product(s) in nanosheets-containing papers, which also exhibit UVA shielding property. The coated samples remained white while the uncoated ones were darkened with γ -irradiation. In addition, the nanosheets-coated papers showed dielectric permittivity, loss tangent, and AC conductivity which were invariant of the γ -dose, unlike those from the uncoated ones. Our work demonstrates the use of lead-free Ti 0.91 O 2 nanosheets as a γ -shielding component to slow down/prevent structural, optical, and electrical properties damages in cellulose paper, which could extend to other nature-derived materials. [Display omitted] • Simple dip coating of commercial filter paper into titanate nanosheets suspension. • Nanosheets loadings were confirmed by several techniques. • The nanosheets (0.6 mg cm−2, or 10 wt% TiO 2) prevent structural, optical, and electrical properties damages by γ -irradiation (up to 50 kGy). [ABSTRACT FROM AUTHOR]