1. Transesterification of Pistacia chinensis seed oil using a porous cellulose-based magnetic heterogeneous catalyst.
- Author
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Li, Tian-Feng, Shen, Chen, Zhang, Hua-Xia, Wang, Xi-Qing, Jiao, Jiao, Wang, Wei, Gai, Qing-Yan, Liu, Ju-Zhao, Liu, Tian-Shu, and Fu, Yu-Jie
- Subjects
TRANSESTERIFICATION ,OILSEEDS ,POROUS materials ,CELLULOSE ,MAGNETIC materials ,HETEROGENEOUS catalysts - Abstract
In the present work, a novel cellulose-based porous heterogeneous solid acid catalyst encapsulation of ferriferous oxide (Fe
3 O4 ) and sulfonated graphene (GO-SO3 H) into cellulose to form composite porous microspheres catalyst (GO-SO3 H/CM@Fe3 O4 )3 H/CM@Fe3 O4 owned stronger active sites and GO-SO3 H dispersed well in porous surface and inside of cellulose support. Under the optimum conditions, microwave-assisted transesterification process was carried out with the best catalyst amount, i.e. 5 wt% GO-SO3 H/CM@Fe3 O4 (weight ratio of GO-SO3 H/cellulose), and conversion yield reached 94%. The prepared catalyst could be easily separated from reaction solution by extra magnetic field and reclaimed at least five runs. [ABSTRACT FROM AUTHOR]- Published
- 2019
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