1. Flexible, ultrathin and integrated nanopaper supercapacitor based on cationic bacterial cellulose.
- Author
-
Zheng W, Fan L, Zhou J, Meng Z, Ye D, and Xu J
- Subjects
- Polymers, Pyrroles, Cations, Cellulose, Araceae
- Abstract
Cellulose composite nanopaper is extensively employed in flexible energy storage systems owing to their light weight, good flexibility and high specific surface area. Nevertheless, achieving flexible and ultrathin nanopaper supercapacitors with excellent electrochemical performance remains a challenge. Herein, surface cationization of bacterial cellulose (BC) nanofibers was conducted using 2,3-epoxypropyltrimethylammonium chloride (EPTMAC). Anion-doped polypyrrole (PPy) was incorporated onto the surface of the cationic bacterial cellulose (BCE) nanofibers by an interfacial electrostatic self-assembly process. The obtained PPy@BCE electrode exhibited excellent electrochemical performance, including an areal capacitance of 3988 mF cm
-2 at 1.0 mA cm-2 and a capacitance retention of 97 % after 10,000 cycles. A laminated paper-forming strategy was adopted to design and fabricate all-in-one integrated flexible supercapacitors (IFSCs) using PPy@BCE nanopaper as electrodes and BC nanopaper as a separator. The IFSCs showed superior areal capacitance (3669 mF cm-2 at 1 mA cm-2 ), high energy density (193.7 μWh cm-2 at a power density of 827.3 μW cm-2 ), and outstanding mechanical flexibility (with no significant capacitance attenuation after repeatedly bending for 1000 times). The present strategy paves a way for the large-scale production of paper-based energy storage devices., Competing Interests: Declaration of competing interest There is no conflict of interest for this manuscript., (Copyright © 2023. Published by Elsevier B.V.)- Published
- 2024
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