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Organic light‐emitting transistors (OLETs) are highly integrated and minimized optoelectronic devices with significant potential superiority in smart displays and optical communications. To realize these various applications, it is urgently needed for color‐tunable emission in OLETs, but remains a great challenge as a result of the difficulty for designing organic semiconductors simultaneously integrating high carrier mobility, strong solid‐state emission, and the ability for potential tunable colors. Herein, a high mobility emissive excimer organic semiconductor, 2,7‐di(2‐anthryl)‐9H‐fluorene (2,7‐DAF) was reasonably designed by introducing a rotatable carbon–carbon single bond connecting two anthracene groups at the 2,7‐sites of fluorene, and the small torsion angles simultaneously guarantee effective conjugation and suppress fluorescence quenching. Indeed, the unique stable dimer arrangement and herringbone packing mode of 2,7‐DAF single crystal enables its superior integrated optoelectronic properties with high carrier mobility of 2.16 cm2 ⋅ V−1 ⋅ s−1, and strong excimer emission with absolute photoluminescence quantum yield (PLQY) of 47.4 %. Furthermore, the voltage‐dependent electrically induced color‐tunable emission from orange to blue was also demonstrated for an individual 2,7‐DAF single crystal based OLETs for the first time. This work opens the door for a new class of high mobility emissive excimer organic semiconductors, and provides a good platform for the study of color‐tunable OLETs. [ABSTRACT FROM AUTHOR]

Organic light‐emitting transistors (OLETs) are highly integrated and minimized optoelectronic devices with significant potential superiority in smart displays and optical communications. To realize these various applications, it is urgently needed for color‐tunable emission in OLETs, but remains a great challenge as a result of the difficulty for designing organic semiconductors simultaneously integrating high carrier mobility, strong solid‐state emission, and the ability for potential tunable colors. Herein, a high mobility emissive excimer organic semiconductor, 2,7‐di(2‐anthryl)‐9H‐fluorene (2,7‐DAF) was reasonably designed by introducing a rotatable carbon–carbon single bond connecting two anthracene groups at the 2,7‐sites of fluorene, and the small torsion angles simultaneously guarantee effective conjugation and suppress fluorescence quenching. Indeed, the unique stable dimer arrangement and herringbone packing mode of 2,7‐DAF single crystal enables its superior integrated optoelectronic properties with high carrier mobility of 2.16 cm2 ⋅ V−1 ⋅ s−1, and strong excimer emission with absolute photoluminescence quantum yield (PLQY) of 47.4 %. Furthermore, the voltage‐dependent electrically induced color‐tunable emission from orange to blue was also demonstrated for an individual 2,7‐DAF single crystal based OLETs for the first time. This work opens the door for a new class of high mobility emissive excimer organic semiconductors, and provides a good platform for the study of color‐tunable OLETs. [ABSTRACT FROM AUTHOR]

[Display omitted] Tissue-equivalent pure organic semiconducting crystals (OSCs) have unique advantages in direct X-ray detectors (DXDs), especially for biological tissue fluoroscopy, but their low carrier mobility and inherent weak absorption restrict the limit-of-detection (LoD) and sensitivity of DXDs. High-mobility OSCs theoretically facilitate charge collection and performance leaps, however, they are rare and suffer from poor solubility due to high conjugation, leading to nearly impossible crystal growth from solution and subsequent device applications. Here we report an ingenious solution-processed crystal-growth and high-performance DXD using 2,6-diphenylanthracene (2,6-DPA), a high-mobility OSC we developed recently. In contrast to previous OSCs, high-mobility 2,6-DPA exhibits low dark current density and large photoconductive gain, resulting in record-breaking LoD of <85 nGy air s−1 and sensitivity of >103 μC Gy air −1 cm−2. Compared with semiconductors containing high- Z atoms (Z is atomic number), the accuracy of 2,6-DPA based DXDs is not affected by near-edge absorption effects. Moreover, the non-linear relationship between irradiation current and dose rate is confirmed as a high injection effect. High mobility and ingenious crystal growth strategy make 2,6-DPA an ideal active material for DXDs and also provide the possibility for more optoelectronic applications. [ABSTRACT FROM AUTHOR]

Organic semiconductors have received broad attention and research interest due to their unique integration of semiconducting properties with structural tunability, intrinsic flexibiltiy and low cost. In order to meet the requirements of organic electronic devices and their integrated circuits, p-type, n-type and ambipolar organic semiconductors are all necessary. However, due to the limitation in both material synthesis and device fabrication, the development of n-type and ambipolar materials is quite behind that of p-type materials. Recent development in synthetic methods of organic semiconductors greatly enriches the range of n-type and ambipolar materials. Moreover, the newly developed materials with multiple functions also put forward multi-functional device applications, including some emerging research areas. In this review, we give a timely summary on these impressive advances in n-type and ambipolar organic semiconductors with a special focus on their synthesis methods and advanced materials with enhanced properties of charge carrier mobility, integration of high mobility and strong emission and thermoelectric properties. Finally, multi-functional device applications are further demonstrated as an example of these developed n-type and ambipolar materials. [ABSTRACT FROM AUTHOR]

Organic semiconductors with combinative high carrier mobility and efficient solid‐state emission are full of challenges but urgently pursued for developing new emerging optoelectronics. Herein, by delicately regulating the crystal packing of an anthracene‐based molecular crystal via terminal tert‐butylation, we developed a superior high mobility emissive molecule, 2,6‐di(6‐tert‐butylnaphthyl)anthracene (TBU‐DNA). The unique "slipped herringbone" packing motif of TBU‐DNA enables its appropriate exciton‐exciton coupling and electron‐phonon coupling, thus resulting in remarkably high solid‐state emission (photoluminescence quantum yield, ΦF≈74.9 %) and efficacious charge transport (carrier mobility, μ=5.0 cm2 V−1 s−1). Furthermore, OLETs based on TBU‐DNA show an external quantum efficiency (EQE) of 1.8 %, which is among the highest EQE values for single component OLETs reported till now. This work presents a crystal engineering strategy via exquisite molecular design to realize high mobility emissive organic semiconductors. [ABSTRACT FROM AUTHOR]

Organic semiconductors with combinative high carrier mobility and efficient solid‐state emission are full of challenges but urgently pursued for developing new emerging optoelectronics. Herein, by delicately regulating the crystal packing of an anthracene‐based molecular crystal via terminal tert‐butylation, we developed a superior high mobility emissive molecule, 2,6‐di(6‐tert‐butylnaphthyl)anthracene (TBU‐DNA). The unique "slipped herringbone" packing motif of TBU‐DNA enables its appropriate exciton‐exciton coupling and electron‐phonon coupling, thus resulting in remarkably high solid‐state emission (photoluminescence quantum yield, ΦF≈74.9 %) and efficacious charge transport (carrier mobility, μ=5.0 cm2 V−1 s−1). Furthermore, OLETs based on TBU‐DNA show an external quantum efficiency (EQE) of 1.8 %, which is among the highest EQE values for single component OLETs reported till now. This work presents a crystal engineering strategy via exquisite molecular design to realize high mobility emissive organic semiconductors. [ABSTRACT FROM AUTHOR]

Abstract: The organic field‐effect transistor (OFET) is the basic building block of integrated circuits. The charge carrier mobility and operating frequency of OFETs have continued to increase; therefore, the power dissipation of OFETs can no longer be ignored. Many research efforts have been made to develop low‐power‐consumption OFETs and complementary circuits. Despite the switching function, OFETs can also be utilized in emerging energy‐related applications, such as near‐infrared (NIR) photodetectors and organic thermoelectric devices. Organic phototransistors show considerably higher photo responsivity than other photodetector architectures due to field‐effect charge modulation. The photoinduced gate modulating largely suppresses the dark current while simultaneously providing gain. These characteristics may favor NIR light detection and suggest that the organic phototransistor is a promising candidate for optoelectronic applications in the NIR regime. For organic thermoelectric applications, OFETs can work as a powerful tool for examining the charge and energy transport in the organic semiconductor, thus giving insight into organic thermoelectric studies. In this review, the authors highlight recent advances in OFET‐ related energy topics, including low‐power‐consumption OFETs, NIR photodetectors, and organic thermoelectric devices. The remaining challenges in the field will also be discussed. [ABSTRACT FROM AUTHOR]

A new thiophene/anthracene derivative, 2,5-di (anthracen-2-yl)thieno [3,2-b]thiophene (2,5-DATT) which integrates excellent charge carrier transport property with the highest mobility of 0.92 cm2 V−1 s−1, high fluorescence quantum yield of 46.08% and high photoresponsivity is developed. Ultrasensitive UV phototransistor with responsivity up to 1.5 × 104 AW−1 and detectivity exceeding 3 × 1015 Jones is also demonstrated. These results show a feasible method for designing and synthesizing multifunctional materials. A new organic semiconductor 2,5-di (anthracen-2-yl)thieno [3,2-b]thiophene (2,5-DATT) is designed and synthesized. The excellent optoelectronic properties make 2,5-DATT a good candidate applied to multifunctional optoelectronic devices and show a feasible method for designing and synthesizing multifunctional materials. Image 1 • A new organic semiconductor 2,5-DATT integrating anthracene and thiophene was designed and synthesized. • 2,5-DATT single crystals possess high charge carrier mobility and efficient photoluminescence. • A novel high mobility emissive materials with high photoresponsivity and detectivity. [ABSTRACT FROM AUTHOR]