1. Foldamers in pseudo[2]rotaxanes and [2]rotaxanes: tuning the switching kinetics and metastability
- Author
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Zhang, Kang-Da, Zhao, Xin, Wang, Gui-Tao, Liu, Yi, Zhang, Ying, Lu, Hao-Jie, Jiang, Xi-Kui, and Li, Zhan-Ting
- Subjects
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OLIGOMERS , *ROTAXANES , *CHEMICAL kinetics , *CHEMICAL stability , *HYDROGEN bonding , *AMIDES , *TETRATHIAFULVALENE , *NUCLEAR magnetic resonance spectroscopy - Abstract
Abstract: Hydrogen bonded arylamide foldamers have been introduced in switchable pseudo[2]rotaxanes and [2]rotaxanes, which also include a cyclobisparaquat(p-phenylene) (CBPQT4+) ring and a ‘dumbbell’ containing tetrathiafulvalene (TTF) and 1,5-dioxynaphthalene (DNP, for rotaxanes). The foldamer size changes through folding and unfolding serve as a steric handle to modulate the mechanical movement of the CBPQT4+ ring along the dumbbell of the pseudo[2]rotaxanes and [2]rotaxanes. By varying the number of the repeating units in the foldamer, the kinetics of the solvent-dependent slippage/deslippage of pseudo[2]rotaxanes and the switching of the ring between TTF and DNP of the [2]rotoxanes can be tuned remarkably, with the time scope ranging from several minutes to several days, in twelve solvents of varying polarity, which have been confirmed by the 1H NMR, UV–vis spectroscopy, and cyclic voltammogram experiments. [Copyright &y& Elsevier]
- Published
- 2012
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