1. Dipolar magnetism in assembled Co nanoparticles on graphene
- Author
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Yin-Ming Chang, Yi-Ying Lu, Chih-Heng Huang, Shih-Yu Wu, C. C. Kuo, Der-Hsin Wei, and Yao-Jui Chan
- Subjects
Materials science ,Spintronics ,Condensed Matter::Other ,Magnetic circular dichroism ,Magnetism ,Graphene ,Physics::Optics ,General Physics and Astronomy ,02 engineering and technology ,Dichroism ,021001 nanoscience & nanotechnology ,01 natural sciences ,law.invention ,Condensed Matter::Materials Science ,Magnetization ,Ferromagnetism ,Chemical physics ,law ,Phase (matter) ,0103 physical sciences ,Physical and Theoretical Chemistry ,010306 general physics ,0210 nano-technology - Abstract
The magnetic properties of the assembled Co nanoparticles on graphene were studied using X-ray magnetic circular dichroism (XMCD), magneto-optical Kerr effects, and a modeling simulation. We demonstrate that the superparamagnetic nanoparticles reveal a ferromagnetic phase when they are assembled on graphene. The moderate increase of the XMCD asymmetry and magnetization with coverage for this assembly indicates a dipolar-mediated magnetism, which is further verified by a model simulation considering the dipolar interaction between neighboring nanoparticles. Furthermore, C K-edge spectra reveal visible dichroism at the π* state of graphene, which indicates the existence of a spin-polarized interface state, while the assembled Co nanoparticles reveal a ferromagnetic phase. These results suggest an efficient route to stabilize the ferromagnetic phase of nanostructures on graphene by tailoring dipolar interactions, which is essential to realize a higher efficiency of spin injection in graphene-based spintronics.
- Published
- 2018
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