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Increasing the field development efficiency of fractured reservoirs is a contemporary issue. This paper presents fundamental and exploratory research results in this field using modern high-tech experimental equipment from the "Arctic" Scientific Centre at the Saint Petersburg Mining University. Oil reserves in fractured reservoirs are enormous; however, they are classified as hard-to-recover. The before-mentioned reservoirs require a specific approach when selecting technologies to improve the efficiency of their development. In this paper, as a solution to the problem under discussion, we propose the use of a physicochemical method of developing fractured reservoirs based on the injection of a water shut-off agent to exclude highly permeable water-conducting fractures from the drainage process. This technology makes it possible to effectively include and develop previously undrained reservoir areas by directly controlling their filtration properties with the use of new highly efficient and ecologically safe chemical reagents and process fluids. [ABSTRACT FROM AUTHOR]