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1. An unprecedented twofold interpenetrating (3,4)-connected 3-D metal–organic frameworkElectronic supplementary information (ESI) available: Synthesis of ligand and MOF, simplified view of network, crystal information, hydrogen-bonding table, and XRD pattern. See DOI: 10.1039/b702216f

Author

Seunghee HongThe first and the second authors contributed equally to this paper., Yang Zou, Dohyun Moon, and Myoung Soo Lah

Subjects
*ORGANOMETALLIC chemistry, *ORGANOCOPPER compounds, *CHEMICAL structure, *CHEMICAL reactions, *SOLVENTS, *HYDROGEN bonding
Abstract

An unprecedented twofold interpenetrating (3,4)-connected topology of the Cu3L4-type metal–organic framework was prepared using N,N′,N″-tris(4-pyridinyl)-1,3,5-benzenetricarboxamide (L) as a trigonal three-connection node and the copper(ii) ion as a square planar four-connection node, where the framework contains remarkably large 1-D solvent channels. [ABSTRACT FROM AUTHOR]

Published
2007
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