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1. Intramolecular Horner-Wadsworth-Emmons Olefination Route to Annulated Carbohydrates

Author

Mikhail S. Ermolenko, Gabor Lukacs, Angela Zampella, Alain Olesker, Muriel Pipelier, Pipelier, M., Ermolenko, M. S., Zampella, Angela, Olesker, A., and Lukacs, G.

Subjects
Chemistry, Intramolecular force, Organic Chemistry, Horner–Wadsworth–Emmons reaction, Medicinal chemistry
Abstract

Depending on the length of the C-alkyl chain, vicinal beta-ketophosphonates of pyranosulosides afforded, under mild basic conditions, cyclopentenone- or cyclohexenone-annulated sugars.

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