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1. Direct incorporation of a ferric ion in the porphyrinogen core: Tetrakis(cyclohexyl)iron porphyrinogen anion with different conformers and its reaction with iodine

3. N[O.sub.2]-mediated meso-hydroxylation of iron(III) porphyrin

4. Formation of superoxide anion on aerial oxidation of Cu(II)-porphyrinogen in the synthesis of tetrakis(cyclohexyl)porphyrinogenCu(III) anion

5. Reversible penta- and hexacoordination motifs in [Co(TMPP)] resulting in interchange of 1D and 2D supramolecular designs

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