1. Coordination polymers based on trans, trans-muconic acid: synthesis, structure, adsorption and thermal properties
- Author
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Nadezhda N. Dremova, Rose K. Baimuratova, N. D. Golubeva, Gulzhian I. Dzhardimalieva, and Andrey V. Ivanov
- Subjects
chemistry.chemical_classification ,Muconic acid ,010405 organic chemistry ,Chemistry ,General Chemical Engineering ,General Chemistry ,Polymer ,010402 general chemistry ,01 natural sciences ,0104 chemical sciences ,chemistry.chemical_compound ,Adsorption ,Thermal ,Organic chemistry - Abstract
Metal-organic frameworks (MOFs) are promising sacrificial templates for synthesis of carbon functional materials with a relatively high concentration of stabilized metallic species. In this work coordination polymers based on trans,trans-muconic acid and transition metals (Cu, Zn, Ni, Co) were prepared and selected as the precursors for supramolecular organization of nanocomposites. The coordination polymers and metal-containing thermolysis products obtained were characterized using a number of analytical techniques including powder X-ray diffraction, elemental analysis, thermal gravimetric analysis, scanning electron microscopy and volumetric nitrogen adsorption/desorption. This study extends the application of coordination polymers as precursors for designing of carbon materials incorporating metal nanoparticles. It is shown that appropriate choice of metal-organic precursors in solid-phase thermolysis allowed to get materials with determined morphologies.
- Published
- 2020