Search

High Density Vertically Integrated Photodiodes (HDVIP) MWIR detectors were fabricated in LPE-grown Mercury Cadmium Telluride material. Devices were fabricated with two different acceptor level concentrations. The low doped n-region was held at a single concentration but the dimensions are tailored to simultaneously maintain high quantum efficiency while minimizing dark current and 1/f noise. Since this study target was for operating at high temperatures, detector I-V data was collected between 120 K and 280 K for I-Vs and 180 to 280 K for noise to understand current mechanisms that limit device performance at these elevated temperatures. Noise as a function of frequency has also been collected over the same temperature range. 1/f noise has also been modeled for MWIR detectors as a function of temperature and will be covered.

Improvement of bio-availability of poorly water soluble drugs presents one of the furthermost challenge in drug formulations. One of the most admired and commercially viable formulation approach for this challenge is solid self micro emulsifying drug delivery system (S-SMEDDS). There are many techniques to convert liquid SMEDDS to solid, but an adsorption technique is simple and economic. Hence aim of present study was to develop S-SMEDDS of poorly water soluble drug Telmisartan (TEL) using Aerosil 200 as solid carrier. Liquid SMEDDS was prepared using Acrysol EL 135, Tween 80 and PEG 400 as oil, surfactant and co-surfactant and was converted to S-SMEDDS by adsorbing it on Aerosil 200. Prepared S-SMEDDS was evaluated for flow properties, drug content, reconstitution properties, DSC, SEM, in-vitro drug release and ex-vivo intestinal permeability study. Results showed that prepared S-SMEDDS have good flow property with 99.45 ± 0.02% drug content. Dilution study by visual observation showed that there was spontaneous micro emulsification and no sign of phase separation. Droplet size was found to be 0.34 µm with polydispersity index of 0.25. DSC thermogram showed that crystallization of TEL was inhibited. SEM photograph showed smooth surface of S-SMEDDS with less aggregation. Drug releases from S- SMEDDS were found to be significantly higher as compared with that of plain TEL. Ex-vivo intestinal permeability study revealed that diffusion of drug was significantly higher from S-SMEDDS than that of suspension of plain TEL. Study concluded that S-SMEDDS can effectively formulated by adsorption technique with enhanced dissolution rate and concomitantly bioavailability.DOI: http://dx.doi.org/10.3329/icpj.v1i12.12451 International Current Pharmaceutical Journal 2012, 1(12): 414-419

State-of-the-art large-area photovoltaic (PV) detectors fabricated in HgCdTe grown by molecular beam epitaxy (MBE) have been demonstrated for the Crosstrack Infrared Sounder (CrIS) instrument. Large-area devices (1 mm in diameter) yielded excellent electrical and optical performance operating at 81 K for λc ∼ 15 µm, at 98 K for λc ∼ 9 µm, and λc ∼ 5-µm spectral cutoffs. Fabricated detectors have near-theoretical electrical performance, and Anti Reflection coated quantum efficiency (QE) is greater than 0.70. Measured average RoA at 98 K is 2.0E7 Ωcm2, and near-theoretical QEs greater than 0.90 were obtained on detectors with λc ∼ 5-µm spectral cutoffs. These state-of-the-art large-area PV detector results reflect high-quality HgCdTe grown by MBE on CdZnTe substrates in all three spectral bands of interest.

InAsSb material with a cutoff wavelength in the 5 μm range has been grown on GaAs substrates. The MWIR InAsSb detector arrays were fabricated and hybridized to a ROIC to permit measurement of the electrical and optical properties of detectors. Detector arrays were fabricated in a 1024 x 1024 format on an 18 μm pitch. A fanout was utilized to directly acquire data from a set of selected detectors without an intervening read out integrating circuit (ROIC). Variable temperature Jdark vs Vd measurements have been made with the dark current density ~ 10-5 A/cm 2 at 150 K. The external QE measured using a narrow band filter centered at ~ 4 μm had values in the 65 – 70 % range. Since the detectors were illuminated through a GaAs substrate, which has a reflectance of 29%, the internal QE is greater than 90%. A 1024 x 1024 ROIC on an 18 μm pitch was also designed and fabricated to interface with the barrier detectors. The ROIC operates at 30 Hz frame rate and has a well capacity of 20.7 M electrons. QE at 150 K for a 1024 x 1024 detector array hybridized to a ROIC had a median D* at 150 K under a flux of 1.07 x 1015 ph/(cm 2 /s) was 1.2 x 1011 cm Hz1/2 /W. The NEdT was 44 mK and imagery was obtained at 150 K using an f/2.3 MWIR lens.

In this era Bacteria are mostly considered as pathogenic. Bacteria though are pathogenic but still a few are friendly and essential for human growth and immunity; called as Probiotics. Lactobacillus model moiety is one of such probiotic bacterium which when introduced in sufficient colony serves as new prophylaxis and curing agent. This will increase the innate immunity of humans. Indian market lacks the quality uni-strain product of the probiotics as Nutraceuticals and as Health enhancing drug product. Global market is full of multi-strain microbes dosage form. The best mode to utilize Nutraceutical aspect of probiotics is to convert in dry form. These purified colony; later converted into the solid dry form by spray dry (JISL mini-spray drier) technique. Starch, lactose were used as thermo-protective agent while heat drying technique. Anti-microbial screenings carried out along with In vitro cytotoxicity studies. In vitro cytotoxicity screening evaluated that Lactobacillus powder showings anti-cancer activity nearly same as standard drug with no side effects. Dry powder increased the shelf life of the microbes that resulted in maintenance of viability and activity.

InAsSb material with a cutoff wavelength in the 5 μm range has been grown on GaAs substrates. The MWIR InAsSb detector arrays were fabricated and hybridized to fanouts and ROICs to permit measurement of the electrical and optical properties of detectors. Detector arrays were fabricated in a 1024 x 1024 format on an 18 μm pitch. A fanout was utilized to directly acquire data from a set of selected detectors without an intervening read out integrating circuit (ROIC). Variable temperature Jdark vs Vd measurements have been made with the dark current density ~ 10 -5 A/cm 2 at 150 K. The external QE measured using a narrow band filter centered at ~ 4 μm had values in the 65 - 70 % range. Since the detectors were illuminated through a GaAs substrate which has a reflectance of 29%, the internal QE is greater than 90 %. A 1024 x 1024 ROIC on an 18 μm pitch was also designed and fabricated to interface with the barrier detectors. The ROIC operates at 30 Hz frame rate and has a well capacity of 20.7 M electrons. QE at 150 K for a 1024 x 1024 detector array hybridized to a ROIC had a median D* at 150 K under a flux of 1.07 x 10 15 ph/(cm 2 /s was 1.2 x 10 11 cm Hz 1/2 /W. The NEdT was 44 mK and imagery was obtained at 150 K using an f/2.3 MWIR lens.

Very long wavelength infrared (VLWIR; 15 to 17 µm) detectors are required for remote sensing sounding applications. Infrared sounders provide temperature, pressure and moisture profiles of the atmosphere used in weather prediction models that track storms, predict levels of precipitation etc. Traditionally, photoconductive VLWIR (λc >15 µm) detectors have been used for sounding applications. However, photoconductive detectors suffer from performance issues, such as non-linearity that is 10X – 100X that of photovoltaic detectors. Radiometric calibration for remote sensing interferometry requires detectors with low non-linearity. Photoconductive detectors also suffer from non-uniform spatial optical response. Advances in molecular beam epitaxy (MBE) growth of mercury cadmium telluride (HgCdTe) and detector architectures have resulted in high performance detectors fabricated in the 15 µm to 17 µmm spectral range. Recently, VLWIR (λc ∼ 17 µm at 78 K) photovoltaic large (1000 µm diameter) detectors have been fabricated and measured at flux values targeting remote sensing interferometry applications. The operating temperature is near 78 K, permitting the use of passive radiators in spacecraft to cool the detectors. Detector non-AR coated quantum efficiency >60% was measured in these large detectors. A linear response was measured, while varying the spot size incident on the 1000 µm detectors. This excellent response uniformity, measured as a function of spot size, implies that low frequency spatial response variations are absent. The 1000 µm diameter, λc ∼ 17 µm at 78 K detectors have dark currents ∼160 µA at a −100 mV bias and at 78 K. Interfacing with the low (comparable to the contact and series resistance) junction impedance detectors is not feasible. Therefore a custom pre-amplifier was designed to interface with the large VLWIR detectors operating in reverse bias. A breadboard was fabricated incorporating the custom designed preamplifier interfacing with the 1000 µm diameter VLWIR detectors. Response versus flux measurements were made on the large VLWIR detectors and non-linearity

RTI has demonstrated a novel photodiode technology based on IR-absorbing solution-processed PbS colloidal quantum dots (CQD) that can overcome the high cost, limited spectral response, and challenges in the reduction in pixel size associated with InGaAs focal plane arrays. The most significant advantage of the CQD technology is ease of fabrication. The devices can be fabricated directly onto the ROIC substrate at low temperatures compatible with CMOS, and arrays can be fabricated at wafer scale. Further, device performance is not expected to degrade significantly with reduced pixel size. We present results for upward-looking detectors fabricated on Si substrates with sensitivity from the UV to ~1.7 μm, compare these results to InGaAs detectors, and present measurements of the CQD detectors temperature dependent dark current.

Mid-wavelength infrared (MWIR) InAsSb alloy barrier detectors grown on GaAs substrates were characterized as a function of temperature to evaluate their performance. Detector arrays were fabricated in a 1024 × 1024 format on an 18 μm pitch. A fanout was utilized to directly acquire data from a set of selected detectors without an intervening read out integrating circuit (ROIC). The detectors have a cutoff wavelength equal to ~ 4.9 μm at 150 K. The peak internal quantum efficiency (QE) required a reverse bias voltage of 1 V. The detectors were diffusion-limited at the bias required to attain peak QE. Multiple 18 μm × 18 μm detectors were tied together in parallel by connecting the indium bump of each detector to a single large metal pad on the fanout. The dark current density at -1 V bias for a set of 64 × 64 and 6 × 6 array of detectors, each of which were tied together in parallel was ~ 10-3 A/cm2 at 200 K and 5 × 10-6 A/cm2 at 150 K. The 4096 (64 × 64) and 36 (6 × 6) detectors, both have similar Jdark vs Vd characteristics, demonstrating high operability and uniformity of the detectors in the array. The external QE measured using a narrow band filter centered at ~ 4 μm had values in the 65 – 70 % range. Since the detectors were illuminated through a GaAs substrate which has a reflectance of 29%, the internal QE is greater than 90 %. A 1024 × 1024 ROIC on an 18 μm pitch was also designed and fabricated to interface with the barrier detectors. QE at 150 K for a 1024 × 1024 detector array hybridized to a ROIC matched the QE measured on detectors that were measured directly through a fanout chip. Median D* at 150 K under a flux of 1.07 × 1015 ph/(cm2/s was 1.0 x 1011 cm Hz1/2 /W.

While InGaAs-based focal plane arrays (FPAs) provide excellent detectivity and low noise for SWIR imaging applications, wider scale adoption of systems capable of working in this spectral range is limited by high costs, limited spectral response, and costly integration with Si ROIC devices. RTI has demonstrated a novel photodiode technology based on IR-absorbing solution-processed PbS colloidal quantum dots (CQD) that can overcome these limitations of InGaAs FPAs. The most significant advantage of the CQD technology is ease of fabrication. The devices can be fabricated directly onto the ROIC substrate at low temperatures compatible with CMOS, and arrays can be fabricated at wafer scale. Further, device performance is not expected to degrade significantly with reduced pixel size. We present results for upward-looking detectors fabricated on Si substrates with sensitivity from the UV to ~1.7 µm. We further show devices fabricated with larger size CQDs that exhibit spectral sensitivity that extends from UV to 2 µm.

We describe our recent efforts in developing visible to mid-wave (0.5 µm to 5.0 µm) broadband photon-trap InAsSb-based infrared detectors grown on GaAs substrates operating at high temperature (150-200K) with low dark current and high quantum efficiency. Utilizing an InAsSb absorber on GaAs substrates instead of an HgCdTe absorber will enable low-cost fabrication of large-format, high operating temperature focal plane arrays. We have utilized a novel detector design based-on pyramidal photon trapping InAsSb structures in conjunction with compound barrier-based device architecture to suppress both G-R dark current, as well as diffusion current through absorber volume reduction. Our optical simulation show that our engineered pyramid structures minimize the surface reflection compared to conventional diode structures acting as a broadband anti-reflective coating (AR). In addition, it exhibits > 70-80% absorption over the entire 0.5 µm to 5.0 µm spectral range while providing up to 3× reduction in absorber volume. Lattice-mismatched InAs0.82Sb0.18 with 5.25 µm cutoff at 200K was grown on GaAs substrates. 128×128/60μm and 1024×1024/18μm detector arrays that consist of bulk absorber as well as photon-trap pyramid structures were fabricated to compare the detector performance. The measured dark current density for the diodes with the pyramidal absorber was 3× lower that for the conventional diode with the bulk absorber, which is consistent with the volume reduction due to the creation of the pyramidal absorber topology. We have achieved high D* (< 1.0 x 1010 cm √Hz/W) and maintain very high (< 80 %) internal quantum efficiency over the entire band 0.5 to 5 µm spectral band at 200K.

United States. Defense Advanced Research Projects Agency (DARPA under contract N66604-09-C-3652)

The photocurrent of High Density Vertically Integrated Photodiodes (HDVIP) manufactured in LPE grown SWIR (λc ~ 2.5 μm) HgCdTe material is modeled as a function of incident spot location using a Monte Carlo diffusion calculation in the p-type bulk. The Monte Carlo calculation assumes a 3 x 3 mini-array of detectors surrounded by guard detectors. Carriers generated in the n-regions are always collected. The result is a responsivity map that yields the individual detector "spot scan" profile that is then used to calculate the detector modulation transfer function (MTF). Fourier transforms of detector "spot scan" response profile provided experimental confirmation of MTF that corresponded to the Monte Carlo modeled MTF.

Detectors that have broadband response from the visible (∼ 400 nm) to near infrared (∼ 2.5 μm) have remote sensing hyper spectral applications on a single chip. Cut-off wavelengths in the 2.2 and 2.5 μm range permit detector operation in the 200 K regime. The DRS HDVIP detector technology is a front side illuminated detector technology. Consequently, there is no substrate to absorb the visible photons as in backside-illuminated detectors and these 2.2 and 2.5-μm-cutoff detectors should be well suited to respond to visible light. However, HDVIP detectors are passivated using CdTe that absorbs the visible light photons. CdTe with a direct bandgap ∼ 1.6 eV strongly absorbs photons of wavelength shorter than about 800 nm. Detectors in 320 x 6 arrays with varying thickness of CdTe passivation layers were fabricated to investigate the visible response of the 2.5-μm-cutoff detectors. The SWIR HDVIP detectors have well known high quantum efficiency (QE) in the near infrared region. The focus here was in acquiring array level data in the visible region of the spectrum. The 320 x 6 FPA QE and NEI data were acquired using a 642 nm narrow band filter with 50 % points at 612 nm and 698 nm. The array QE average is ∼ 70 % for the array with CdTe passivation thickness = 44.5 nm. The NEI is ∼ 5 x 10 10 ph/cm 2 /s at a flux Φ = 5.36 x 10 13 ph/cm 2 /s. QE for an array with CdTe passivation thickness = 44.5 nm is ∼ 10 % higher than an array with CdTe passivation thickness = 79.3 nm. In addition, a model that takes into account the complex optical properties of every layer in the HDVIP photodiode architecture was developed to predict the QE of the detectors in the near infrared and visible wavelength regions as a function of CdTe thickness. Measured QE as a function of wavelength is not a good match to the model QE probably due to limitations in the measured QE and knowledge of optical constants that are input into the model.

Intrinsic carriers play a dominant role especially in the long wavelength (8-12 μm cut-off) HgCdTe material near ambient temperatures due to high thermal generation of carriers. This results in low minority carrier lifetimes caused by Auger recombination processes. Consequently, this low lifetime at high temperatures results in high dark currents and subsequently high noise. Cooling is one means of reducing this type of detector noise. However, the challenge is to design photon detectors to achieve background limited performance (BLIP) at the highest possible operating temperature; with the greatest desire being close to ambient temperature operation. We have demonstrated a unique planar device architecture using a novel approach in obtaining low arsenic doping concentrations in HgCdTe. Results indicate Auger suppression in P+/π/N+ devices at 300K and have obtained saturation current densities of the order of 3 milli Amps-cm2 on these devices.

In this work, we develop a mercury-cadmium-telluride linear array detection system that is capable of rapidly capturing (∼1-5 s) a broad spectrum of atomic and molecular laser-induced breakdown spectroscopy (LIBS) emissions in the long-wave infrared (LWIR) region (∼5.6-10 μm). Similar to the conventional UV-Vis LIBS, a broadband emission spectrum of condensed phase samples covering the whole 5.6-10 μm region can be acquired from just a single laser-induced microplasma or averaging a few single laser-induced microplasmas. Atomic and molecular signature emission spectra of solid inorganic and organic tablets and thin liquid films deposited on a rough asphalt surface are observed. This setup is capable of rapidly probing samples "as is" without the need of elaborate sample preparation and also offers the possibility of a simultaneous UV-Vis and LWIR LIBS measurement.

DRS uses LPE-grown SWIR, MWIR and LWIR HgCdTe material to fabricate High-Density Vertically Integrated Photodiode (HDVIP) architecture detectors. 2.5 μm, 5.3 μm and 10.5 μm cutoff detectors have been fabricated into linear arrays as technology demonstrations targeting remote sensing programs. This paper presents 320 x 6 array configuration technology demonstrations' performance of HDVIP HgCdTe detectors and single detector noise data. The single detector data are acquired from within the 320 x 6 array. Within the arrays, the detector size is 40 μm x 50 μm. The MWIR detector array has a mean quantum efficiency of 89.2% with a standard deviation to mean ratio, σ/μ = 1.51%. The integration time for the focal plane array (FPA) measurements is 1.76 ms with a frame rate of 557.7 Hz. Operability values exceeding 99.5% have been obtained. The LWIR arrays measured at 60 K had high operability with only ~ 3% of the detectors having out of family response. Using the best detector select (BDS) feature in the read out integrated circuit (ROIC), a feature that picks out the best detector in every row of six detectors, a 320 x 1 array with 100% operability is obtained. For the 320 x 1 array constituted using the BDS feature, a 100% operable LWIR array with average NEI value of 1.94 x 1011 ph/cm 2/s at a flux of 7.0 x 1014 ph/cm2/s has been demonstrated. Noise was measured at 60 K and 50 mV reverse bias on a column of 320 diodes from a 320 x 6 LWIR array. Integration time for the measurement was 1.76 ms. Output voltage for the detectors was sampled every 100th frame. 32,768 frames of time series data were collected for a total record length of 98 minutes. The frame average for a number of detectors was subtracted from each detector to correct for temperature drift and any common-mode noise. The corrected time series data was Fourier transformed to obtain the noise spectral density as a function of frequency. Since the total time for collecting the 32,768 time data series points is 98.0 minutes, the minimum frequency is 170 μHz. A least squares fit of the form (A/f + B) is made to the noise spectral density data to extract coefficients A and B that relate to the 1/f and white noise of the detector respectively. In addition noise measurements were also acquired on columns of SWIR detectors. Measurements were made under illuminated conditions at 4 mV and 50 mV reverse bias and under dark conditions at 50 mV reverse bias. The total collection time for the SWIR detectors was 47.7 minutes. The detectors are white noise limited down to ~10 mHz under dark conditions and down to ~ 100 mHz under illuminated conditions.

Remote sensing programs require detectors with a variety of wavelengths. One example of remote sensing applications is the GOES-ABI program that requires linear arrays of detectors with cutoff wavelengths ranging from the visible to the VLWIR (λc ~ 15 μm). In order to target the variety of remote sensing applications, an internal task was conducted to develop detectors and linear arrays operating under nominal remote sensing applications. SWIR [λc(295 K) ~ 2.5 μm] test detectors have been measured as a function of temperature between 170 K and 295 K. At 200 K the RoA values are in the 106 ohm-cm2 range. MWIR [λc(60 K) = 5.3 μm] and LWIR [λc(60 K) = 10.5 μm] HgCdTe detectors in a 320 x 6 array format have also been measured at 60 K. Within the arrays, the detector size is 40 μm x 50 μm. The MWIR detector array has a mean quantum efficiency of 89.2 % with a standard deviation to mean ratio, σ/μ = 1.51 %. The integration time for the focal plane array (FPA) measurements is 1.76 ms with a frame rate of 557.7 Hz. Operability values exceeding 99.5 % have been obtained. In addition, test diodes at the edge of the array that did not go through a read out integrated circuit (ROIC) were also measured and had quantum efficiency ~ 86 % that agreed well with the ~ 87 % quantum efficiency measured for detectors in the array that were located near the test detectors. The LWIR arrays, measured at 60K also had high operability with only ~ 3 % of the detectors having out of family response. Using best detector select (BDS) feature in the read out integrated circuit (ROIC), a feature that picks out the best detector in every row of six detectors, a 320 x 1 array with 100 % operability is obtained. For the 320 x1 array constituted using the BDS feature, a 100 % operable LWIR array with average NEI value of 1.94x1011 ph/cm2/s at a flux of 7.0x1014 ph/cm2/s has been demonstrated.

An attempt is made to connect the material parameters of Hg 1-x Cd x Te layer growth to the parameters measured following photovoltaic detector fabrication. We found that the Cd composition X value extracted from spectral response measurements on detectors at 78 K are lower than the X values obtained from the room temperature transmission measurements, or the X value used to fit the measured material minority carrier lifetime versus temperature data. The lateral collection length L c that determines the thermally generated carriers that contribute to the diffusion current and L opt extracted from the "flood-illuminated" to "focused-spot" photocurrent ratio are in excellent agreement. Devices exhibit near theoretical R o A uniformity at 77K for MWIR, LWIR and VLWIR. R o A opt was also found to be uniform throughout the range of detector dimensions measured such as 8 μm diameter circular to 250 μm x 250 μm square. Median R o A opt values are 1266, 66 and 0.75 ohm-cm 2 for the 9.7, 11.3 and 15.4 μm cutoff wavelengths respectively. The uniformity in R o A opt confirms that the detector performance is limited by the bulk properties of the material, and not by surface effects.

Detector characteristics of Au- and Cu-doped High Density Vertically Integrated Photodiode (HDVIP) detectors are presented in this paper. Individual photodiodes in test bars were examined by measuring I-V curves under dark and illuminated conditions at high bias values. Noise as a function of frequency has been measured on Au- and Cu-doped MWIR [λ c (78 K) = 5 μ] HDVIP HgCdTe diodes at several temperatures under dark and illuminated conditions. No excess currents are observed above the photocurrents for reverse bias values out to 500 mV. Both Au- and Cu-doped detectors measured at 85 K, exhibit gain values between 40 and 50 at 8 V reverse bias. Gain values fell in this same range even when the flux incident on each type of detector was varied. The excess noise factor for the Cu-doped detectors ranged from 1.35 to 1.69 depending on the incident flux. Variation is probably due to measurement error. The noise at 8 V reverse bias is white for the Cu-doped detectors. The Au-doped detectors exhibited 1/f noise at 8 V reverse bias. At higher frequencies where the noise spectrum was quasi-white, the excess noise factor for the Au-doped detector was in the 1.0 to 1.5 range.

Cu-doped HDVIP ® detectors with different cut-off wavelengths are routinely manufactured. The DRS HDVIP ® detector technology is a front-side-illuminated detector technology. There is no substrate to absorb the visible photonsas in backside-illuminated detectors and these detectors should be well suited to respond to visible light. However,HDVIP ® detectors are passivated using CdTe that absorbs the visible light photons. CdTe strongly absorbs photons ofwavelength shorter than about 800 nm. Detectors with varying thickness of CdTe passivation layers were fabricated toinvestigate the visible response of the 2.5- µ m-cutoff detectors. A model was developed to predict the quantumefficiency of the detectors in the near infrared and visible wavelength regions as a function of CdTe thickness.Individual photodiodes ( c =2.5µ m) in test bars were examined. Measurements of the quantum efficiency as afunction of wavelength region will be presented and compared to the model predictions.Keywords: infrared, HDVIP

Photon detectors and focal plane arrays (FPAs) are fabricated from HgCdTe and silicon in many varieties. With appropriate choices for bandgap in HgCdTe, detector architecture, dopants, and operating temperature, HgCdTe and silicon can cover the spectral range from ultraviolet to the very-long-wavelength infrared (VLWIR), exhibit high internal gain to allow photon counting over this broad spectral range, and can be made in large array formats for imaging. DRS makes HgCdTe and silicon detectors and FPAs with unique architectures for a variety of applications. Detector characteristics of High Density Vertically Integrated Photodiode (HDVIP) HdCdTe detectors as well as Focal Plane Arrays (FPAs) are presented in this paper. MWIR[λc(78 K) = 5 μm] HDVIP detectors RoA performance was measured to within a factor or two or three of theoretical. In addition, 256 x 256 detector arrays were fabricated. Initial measurements had seven out of ten FPAs having operabilities greater than 99.45% with the best 256 x 256 array having only two inoperable pixels. LWIR [λc(78K)~10 μm] 640 X 480 arrays and a variety of single color linear arrays have also been fabricated. In addition, two-color arrays have been fabricated. DRS has explored HgCdTe avalanche photo diodes (APDs) in the λc = 2.2 μm to 5 μm range. The λc = 5 μm APDs have greater than 200 DC gain values at 8 Volts bias. Large-format to 10242 Arsenic-doped (Si:As, λc ~ 28 μm), Blocked-Impurity-Band (BIB) detectors have been developed for a variety of pixel formats and have been optimized for low, moderate, and high infrared backgrounds. Antimony-doped silicon (Si:Sb) BIB arrays having response to wavelengths > 40 μm have also been demonstrated. Avalanche processes in Si:As at low temperatures (~ 8 K) have led to two unique solid-state photon-counting detectors adapted to infrared and visible wavelengths. The infrared device is the solid-state photomultiplier (SSPM). A related device optimized for the visible spectral region is the visible-light photon counter (VLPC). The VLPC is a nearly ideal device for detection of small bunches of photons with excellent time resolution. Finally, DRS makes imaging arrays of pin-diodes utilizing the intrinsic silicon photoresponse to provide high performance over the 0.4-1.0 μm spectral range operating near room temperature. pin-diode arrays are particularly attractive as an alternative to charge-coupled devices (CCDs) for space applications where radiation hardening is needed. In addition, wire grid micropolarizers have been demonstrated and two color doped silicon detectors using diffractive microlenses are being developed. Precision alignment of sensor chips with respect to a base mounting plate has been demonstrated to be within 2 μm. A similar technique is also utilized to align single large detectors for sounder applications in focal plane arrays (FPAs). FPAs for space applications with the associated cold and warm electronics and packaging/cables have been fabricated.

Detector characteristics of Cu- and Au-doped High Density Vertically Integrated Photodiode (HDVIP) detectors as well as Cu-doped HDVIP Focal Plane Arrays (FPAs) are presented in this paper. Individual photodiodes in test bars were examined by measuring I-V curves and the associated resistance-area (RA) product as a function of temperature. The Au-doped MWIR [λ c (78 K) = 5 μm] HDVIP detectors RoA performance was within a factor of two or three of theoretical. Noise as a function of frequency has been measured on Au-doped MWIR HgCdTe HDVIP diodes at several temperatures under dark and illuminated conditions. Low-frequency noise performance of the Au-doped MWIR diode in the various environments is characterized by the ratio α of the noise current spectral density at 1 Hz to the value of the diode current. For photocurrent at 140 K, α PHOTO = 1.8 x 10 -5 . The value of α PHOTO is the same at both zero bias and 100 mV reverse bias. At 160 K, α PHOTO is slightly lower but still in the low 10 -5 range. Excess low-frequency noise measured at 140 K and 100 mV reverse bias in the dark has α DARK = 1.4 x 10 -5 . At 160 K and 100 mV reverse bias, α DARK is in the mid 10 -5 range. At 140 K,the dark current at 8.2 V reverse bias was equal to the photocurrent at 100 mV reverse bias and close to the photocurrent at zero bias. α DARK = 1.85 x 10 -3 at -8.2 V. This ratio is two orders of magnitude greater than α PHOTO . At 8.2 V reverse bias, the current was amplified by avalanche processes. Similar results were obtained on the Au-doped diode at 160 K. Diffusion current dominates dark current at 100 mV reverse bias at T = 185 K and T = 220 K. The ratio, α DARK approximately α PHOTO in the low to mid 10 -5 range, i.e. dark diffusion current generates excess low frequency noise in the same manner as photocurrent. In addition, 256 x 256 Cu-doped detector arrays were fabricated. Initial measurements had seven out of ten FPAs having operabilities greater than 99.45% with the best 256 x 256 array having only two inoperable pixels.

Multiply damaged sites (MDS) are defined as greater than/equal to two lesions within 10-15 bp and are generated in DNA by ionizing radiation. In vitro repair of closely opposed base damagesor =2 bp apart results in a double strand break (DSB). This work extends the in vitro studies by utilizing clusters of uracil DNA damage as model lesions to determine whether MDS are converted to DSBs in bacteria. Lesions were positioned within the firefly luciferase coding region, transformed into bacteria (wild-type, uracil DNA glycosylase-deficient, ung-, or exonuclease III and endonuclease IV-deficient, xth-nfo-) and luciferase activity measured following repair. DSB formation was expected to decrease activity. Two closely opposed uracils separated byor =7 bp decreased luciferase activity in wild-type and xth-nfo-, but not ung- bacteria. Growth of bacteria to obtain plasmid-containing colonies demonstrated that the plasmid was destroyed following the mis-repair of two uracils positioned 7 bp apart. This study indicates a DSB is formed when uracil DNA glycosylase initiates repair of two closely opposed uracilsor =7 bp apart, even in the absence of the major apurinic endonucleases. This work supports the in vitro studies and demonstrates that DNA repair is not always advantageous to cells.

The effect of radiation on HgCdTe photodiodes is an important parameter to understand when determining the long-term performance limitations for the Cross-track Infrared Sounder (CrIS), a Fourier Transform interferometric sensor that will fly as part of the National Polar-orbiting Operational Environmental Satellite System (NPOESS). The CrIS sensor uses relatively large area photovoltaic detectors, 1 mm in diameter. Each p-on-n HgCdTe photodiode consists of MBE grown, n-type material on lattice matched CdZnTe, with arsenic implantation used to form the junction. A 1mm diameter detector is achieved by using a lateral collection architecture. Solar, and trapped protons are a significant source of radiation in the NPOESS 833 km orbits. We irradiated 22 LWIR detectors with protons at the Harvard Cyclotron Laboratory (HCL) and monitored the I-V performance and dynamic impedance of each detector. Three groups of detectors were irradiated with either 44, 99, or 153-MeV protons, each between 1×1010 - 4×1012 p+/cm2. Several I-V data sets were collected within that fluence range at all three energies. All the detectors were warmed to room temperature for approximately 96 hours following the largest proton dose, re-cooled, and then re-characterized in terms of I-V performance and dynamic impedance. The total noise increase predicted for CrIS after 7-years in orbit is less than 1%.

The National Polar-orbiting Operational Environmental Satellite System (NPOESS) Cross-track Infrared Sounder (CrIS) is a Fourier Transform interferometer-based sensor used to measure earth radiance at high spectral resolution and low spatial resolution. Measured radiance data are analyzed by end users to provide pressure, temperature and moisture profiles of the atmosphere. The CrIS instrument contains Mercury-Cadmium-Telluride (MCT) photovoltaic (PV) detectors with spectral response in the SWIR, MWIR and LWIR ranges. The CrIS instrument requires large area detectors with state-of-the-art detector performance at temperatures attainable with passive cooling. In the case of the LWIR bands noise associated with the detectors limit the instrument performance. In this paper we describe a study of the noise characteristics of a sample of CrIS MCT PV detectors, emphasizing acquisition and validation of 1/f noise measurements for these devices. Interesting aspects of the 1/f noise dependence on bias-voltage and bias-current are noted. The results are analyzed further in a companion paper1 that emphasizes the relationship between leakage current mechanisms in the diodes and 1/f noise observed.

Focal plane arrays used for remote sensing applications are required to operate at high temperatures and are subject to high terrestrial background fluxes. Typical remote sensing applications like cloud/weather imagery, sea-surface temperature measurements, ocean color characterization, and land-surface vegetation indices also require FPA's that operate from the visible through the LWIR portion of the spectrum. This combination of harsh requirements have driven the design of a unique LWIR FPA, that operates at 80K under 300K background conditions, with an operating spectral range from 11.5μm to 12.5μm, and a spectral cutoff of 13.5μm. The FPA consists of 2 side by side arrays of 1×60 HgCdTe, (grown by molecular beam epitaxy) photovoltaic, detector arrays bump bonded to a custom CMOS Si readout. The 2 arrays are completely independent, and can be operated as such. The readout unit cell uses two, current-mode, analog building blocks; a Current Conveyor (CC1) and a dynamic current mirror. The CC1 has input impedance below 300 Ω and an injection efficiency that is independent of the detector characteristics. This combination extracts high performance and excellent sensitivity from detectors whose average RoA values are approximately 1.7 Ω-cm 2 at T=80K. The dynamic current mirror is used to subtract high background photocurrent while preserving excellent dynamic range. In addition to the performance enhancing readout, the detectors are manufactured with integral microlenses and operated in reverse bias to take advantage of their increased dynamic impedance. The dark currents associated with reverse bias operation are subtracted along with the background photocurrents by the dynamic current mirror. Analysis of this unique ROIC architecture will be presented along with modeled performance. Measurements were performed on a LWIR FPA. Expected and measured FPA results are shown in the table below. The expected data are calculated from FPA models and compared to the measured values.

State-of-the-art large area photovoltaic detectors fabricated in HgCdTe grown by Molecular Beam Epitaxy have been demonstrated for the Crosstrack Infrared Sounder instrument. Large area devices (1 mm in diameter) yielded excellent electrical and optical performance operating at 81K for LWIR band and at 98K for MW and SWIR bands. LWIR and MWIR detectors have near-theoretical electrical performance, and AR-coated quantum efficiency is greater than 0.70. Measured average RoA at 98K is 2.0E7 W-cm2 and near-theoretical quantum efficiencies greater than 0.90 were obtained on SWIR detectors. These state-of-the-art large area photovoltaic detector results reflect high quality HgCdTe grown by Molecular Beam Epitaxy on CdZnTe substrates in all three spectral bands of interest.

Focal plane arrays (FPA's), used for remote sensing applications, are required to operate at high temperatures and are subject to high terrestrial background fluxes. Typical remote sensing applications like cloud/weather imagery, sea- surface temperature measurements, ocean color characterization, and land-surface vegetation indices also require FPAs that operate from the visible through the LWIR portion of the spectrum. This combination of harsh requirements have driven the design of a unique LWIR FPA, that operates at 80 K under 300 K background conditions, with an operating spectral range from 11.5 micrometers to 12.5 micrometers , and a spectral cutoff of 13.5 micrometers . The FPA consists of 2 side by side arrays of 1 X 60 HgCdTe, (grown by molecular beam epitaxy) photovoltaic, detector arrays bump bonded to a custom CMOS Si readout. The 2 arrays are completely independent, and can be operated as such. The readout unit cell uses two, current-mode, analog building blocks; a Current Conveyor (CC1) and a dynamic current mirror. The CC1 has input impedance below 300 Ohms and an injection efficiency that is independent of the detector characteristics. This combination extracts high performance and excellent sensitivity from detectors whose average RoA values are approximately 1.7 Ohm-cm2 at T equals 80 K. The dynamic current mirror is used to subtract high background photocurrent while preserving excellent dynamic range. In addition to the performance enhancing readout, the detectors are manufactured with integral microlenses and operated in reverse bias to take advantage of their increased dynamic impedance. The dark currents associated with reverse bias operation are subtracted along with the background photocurrents by the dynamic current mirror. The expected and measured LWIR FPA performance will be presented. Measurements were performed on an LWIR FPA. Expected and measured FPA results are shown in the table below. The expected data are calculated from FPA models and compared to the measured values.

Publisher Summary Significant advances in the areas of mercury cadmium telluride (HgCdTe)-material growth, detector array fabrication, and readout integrated circuit design and fabrication have been accumulated over the past years. These advances have led to the demonstration of high resolution-, low-noise-, and large-format reliable focal plane arrays (FPA). In the 1–3 μm short wavelength infrared region, high-performance, reliable 1024×1024 FPA for astronomy applications have been developed and 2048×2048 arrays are in development. In the 3–5μm middle wavelength infrared spectral region, high-performance 640×480 and 1024×1024 FPA have been developed, while 256×256 FPA are in continuous production to support systems applications. In the 8–12μm- and beyond long-wavelengthinfrared region, high performance, 128×128 FPA have been developed on CdZnTe substrates. The molecular beam epitaxy (MBE) HgCdTe-based technique has emerged as a viable technology for manufacturing high-performance infrared focal plane arrays. Device-quality liquid phase epitaxy, metalorganic chemical vapor deposition, and MBE material are being grown routinely for applications in the 1.5–16.0 μm spectral region. An excellent control of composition, growth rate, layer thickness, doping concentration, dislocation density, and transport characteristics has been demonstrated in FPA.

Very Long Wavelength InfraRed (VLWIR; (lambda) c approximately equals 15 to 17 micrometer at 78 K) photovoltaic detector operating in the 78 K range are needed for remote sensing applications. This temperature range permits the use of passive radiators in spacecraft to cool the detectors. VLWIR ((lambda) c approximately equals 15 to 17 micrometer at 78 K) photovoltaic detectors in a range of sizes (8 micrometer diameter to 1000 micrometer diameter) have been fabricated and their performance measured as a function of temperature. Molecular Beam Epitaxy (MBE) was used to grow n-type VLWIR Hg1-xCdxTe on lattice matched CdZnTe. Arsenic was implanted and the wafer was annealed to provide the p-type regions. All the material was grown with wider bandgap cap layers and consequently the detector architecture is the Double Layer Planar Heterostructure (DLPH) architecture. Id - Vd versus temperature curves for 8 and 1000 micrometer diameter, (lambda) c equals 17 micrometer at 78 K detectors indicate that the 8 micrometer diameter detector is diffusion limited for temperatures greater than 63 K even at a -200 mV bias. There is no appreciable tunneling at T equals 50 K and at -200 mV applied bias. At T equals 40 K tunneling commences at a bias approximately equals -80 mV. Below T equals 30 K, the diode is tunneling limited. The 1000 micrometer diameter detector is diffusion limited at bias values less than -50 mV at 78 K. At zero bias, the detector impedance is comparable to the series/contact resistance. Interfacing with the low (comparable to the contact and series resistance) junction impedance detector is not feasible. Therefore a custom pre- amplifier was designed to interface with the large VLWIR detectors in reverse bias. The detector is dominated by tunneling currents at temperatures less than 78 K. The 1000 micrometer diameter, (lambda) c approximately equals 17 micrometer at 78 K detectors have dark currents approximately equals 160 (mu) A at a -100 mV bias and at 78 K. Detector non-AR coated quantum efficiency > 60% was measured at -100 mV bias in these large detectors and the response was constant across the (lambda) equals 7 micrometer to 15 micrometer spectral band. With AR- coating the quantum efficiency will be > 70%. Response was measured and non-linearity < 0.15% was calculated for the 1000 micrometer detectors. The flux values were in the 1017 ph/cm2/sec range and were changed by varying the blackbody temperature. In addition, a linear response was measured while varying the spot size incident on the 1000 micrometer detectors. This excellent response uniformity measured as a function of spot size implies that, low frequency spatial response variations are absent, for the 1000 micrometer detectors.© (2000) COPYRIGHT SPIE--The International Society for Optical Engineering. Downloading of the abstract is permitted for personal use only.

Significant advances in the areas of mercury cadmium telluride (HgCdTe)material growth, detector array fabrication, and readout integrated circuit (ROIC) design and fabrication have been accumulated over the past 20 years. These advances have led to the demonstration of reliable high-resolution, low-noise and large-format focal plane arrays (FPA). In the 1‑3 μm short wavelength infrared (SWIR) region, high-performance and reliable 1024 × 1024 FPAs for astronomy applications have been developed and 2048 × 2048 arrays are in development. In the 3–5 μm middle wavelength infrared (MWIR) spectral region, high-performance 640 × 480 and 1024 × 1024 FPA have been developed, while 256 × 256 FPA are in continuous production to support systems applications. In the 8–12 μm and beyond long wavelength infrared (LWIR) region, high-performance, 128 × 128 FPA have been developed on CdZnTe substrates. The molecular beam epitaxy (MBE) HgCdTe-based technique has emerged as a viable technology for manufacturing high-performance infrared FPA. Device-quality liquid phase epitaxy (LPE), metal-organic chemical vapor deposition (MOCVD), and MBE material are being grown routinely for applications in the 1.5–16.0 μm spectral region. Excellent control of composition, growth rate, layer thickness, doping concentration, dislocation density, and transport characteristics has been demonstrated. Excellent material quality has made possible high-performance very LWIR 128 × 128 FPAs operating between 40 and 60 K, low-background LWIR detectors operating at 40 K, and MWIR FPA for strategic surveillance applications. The future hopes to see further exploitation of the advances made to further fabricate multicolor FPA and smart FPA with increasing on-chip processing.

Short wavelength, middle wavelength, mid-long wavelength, long wavelength, and very long wavelength focal plane arrays (FPAs) are required for remote sensing applications. Advances in the Molecular Beam Epitaxy (MBE) growth of Mercury Cadmium Telluride (HgCdTe) and detector architectures utilized, have resulted in high performance detectors being fabricated in the 1 micrometers to 16 micrometers spectral range Custom Read Out Integrated Circuits (ROICs) are designed and fabricated to interface the HgCdTe detector arrays. The hybrid focal pane array is made up of the HgCdTe detector array and the CMOS-based ROIC. Hybrid FPAs performance parameters are presented. The HgCdTe detector material is used are grown by MBE on lattice matched CdZnTe substrates. Custom ROICs are fabricated in a commercial CMOS foundry. FPA D* performance values have been obtained for a multitude of spectral ranges and configurations that include; (i) (lambda) c equals 1.8 micrometers , 12 X 256 arrays operating at 295 K with median D* approximately 1.4 X 1012 cm Hz1/2/W, (ii) (lambda) c equals 10.5 micrometers , 256 X 256 arrays operating at 85 K with medina D* equals 3.9 X 1011 cm Hz1/2/W at a background flux (phi) b equals 7.82 X 1015 ph/cm2-2 and (iii) (lambda) c equals 15.8 micrometers at 65K, 128 X 128 array operating at 40K with peak D* of 2.76 X 1011 cm Hz1/2/W at a background flux (phi) b equals 8.0 X 1015 ph/cm2- s. The performance of these FPAs will be presented.

Infrared (IR) remote sensing imaging applications require high-performance Focal Plane Arrays (FPAs) operating in all ranges of the IR spectrum. Short wavelength (SWIR; 1 to 3 micrometer), middle wavelength (MWIR; 3 to 5 micrometer), mid- long wavelength (MLWIR; 6 to 8 micrometer), long wavelength (LWIR; 8 to 14 micrometer), and very long wavelength (VLWIR; greater than 14 micrometer). These diverse spectral bands require high performance detectors and Read Out Integrated Circuits (ROICs) to perform the multi-spectral mission requirements. Significant progress in the design and fabrication of HgCdTe detector arrays and Read Out Integrated Circuits (ROICs) over the past few years has led to the demonstration of high resolution, low noise and large format reliable FPAs. Hybrid FPAs have been measured and their performance parameters are presented. Focal Plane Array D* performance values have been obtained for a multitude of spectral ranges and configurations that include; (1) (lambda) c equals 1.8 micrometer, 12 X 256 arrays operating at 295 K with median D* approximately 1.4 X 1012 cm Hz1/2/W, (2) (lambda) c equals 2.4 micrometer, 12 X 256 arrays operating at 250 K with median D* equals 1.6 X 1012 cm Hz1/2/W, detectors used are grown by MBE on lattice matched CdZnTe, (3) PACE-1 detectors with (lambda) c equals 2.5 micrometer, 1024 X 1024 arrays operating at 115 K with peak D* of 2.3 X 1013 cm Hz1/2/W at a background flux (phi) b equals 1.2 X 1011 ph/cm2- s, (4) MBE HgCdTe on Silicon MWIR detectors have been fabricated and the detector RoA performance for (lambda) co approximately 5.0 micrometer is in the 106 to 107 ohm-cm2 range at 78 K. (5) MBE HgCdTe on CdZnTe detectors, ((lambda) c equals 15.8 micrometer at 65 K), 128 X 128 array operating at 40 K with peak D* of 2.76 X 1011 cm Hz1/2/W at a background flux (phi) b equals 8.0 X 1015 ph/cm2-s. High performance 640 X 480 arrays imaging in the MWIR band have been fabricated on CdZnTe and PACE-1 substrates. The performance of these and additional FPAs will be presented.© (1998) COPYRIGHT SPIE--The International Society for Optical Engineering. Downloading of the abstract is permitted for personal use only.

Remote sensing applications including the National Polar Orbiting Environmental Satellite System (NPOESS) require imaging in a multitude of infrared spectral bands, ranging from the 1.58 micrometer to 1.64 micrometer VSWIR band to the 11.5 micrometer to 12.5 micrometer LWIR band and beyond. These diverse spectral bands require high performance detectors, operating over a range of temperatures; room temperature for the VSWIR band 100 K for MWIR, LWIR and VLWIR, these needs can all be met using molecular beam epitaxy (MBE) to grow HgCdTe. The flexibility inherent in the MBE growth technology is its ability to vary the HgCdTe material's bandgap within a growth run and from growth run to growth run, a capability necessary for remote sensing applications that require imaging in a wide variety of spectral bands. This bandgap engineering flexibility also permits tailoring the device architecture to the various specific system requirements. This paper combines measured detector optical and electrical data, with noise model estimates of ROIC performance to calculate signal to noise ratio (SNR), D* or noise equivalent temperature difference (NE(Delta) T), for each spectral band. The SNR, D* and/or NE(Delta) T are calculated with respect to system focal plane specifications, as required for the meteorological NPOESS.