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This research focuses on synthesis and modification of polyol precursors derived from cis-1,4-polyisoprene (PI). These new polyol precursors can be converted to high value-added polyurethane (PU). The epoxidized hydroxytelechelic PI (EHTPI) prepared by chemical modification from PI was used as starting material for polyol synthesis. 1,3-Dipolar cycloaddition between a terminal alkyne and an azide has rapidly become the most popular click reaction. We applied this reaction to couple azide-functionalized PI and alkyne-functionalized sugar for preparing polyols. For azide functionalization, 1-methyl epoxidized cyclohexane was used as a model molecule, and various conditions for epoxide ring opening of 1-methyl epoxidized cyclohexane and EHTPI were investigated. The cycloaddition of alkyne and azide was carried out in the presence of sodium ascorbate and copper sulfate. The polyol precursors obtained might be used to prepare biodegradable polyol PU.

Natural rubber is a renewable resource with a potential as precursor of a very wide range of novel polymers, including polyisoprene-based surfaces with antifouling (AF) activity. In this work, new ionic and non-ionic coatings were prepared by the photocrosslinking reaction of photosensitive cis -1,4-oligoisoprenes, bearing a variable number of ammonium groups. The photochemical crosslinking was achieved using radical (via acrylate groups) or cationic (via epoxy groups) processes. Surface properties of these coatings were studied by static contact angle measurements and AFM imaging. Assessment of bioactivity demonstrated that most of the resulting coatings showed AF potential against fouling organisms: growth inhibition of marine bacteria ( Pseudoalteromonas elyakovii , Shewanella putrefaciens , Cobetia marina , Polaribacter irgensii , Vibrio aestuarianus ) and fungi ( Halosphaeriopsis mediosetigera , Asteromyces cruciatus , Lulworthia uniseptata , Zalerion sp., Monodictys pelagica ); decreased adhesion of microalgae ( Navicula jeffreyi , Cylindrotheca closterium , Chlorarachnion globosum , Pleurochrysis roscoffensis , Exanthemachrysis gayraliae , Amphora coffeaeformis ); inhibition of attachment and/or germination of spores of Ulva intestinalis . The best AF activity was obtained with the ionic surfaces. These new coatings prepared from precursors obtained from natural rubber are in essence active by contact. As the biocidal functions are fixed covalently to the polymer chain, detectable release of biocidal products in the marine ecosystem is prevented so that a valuable environment-friendly alternative for new AF coatings is hereby proposed.

Metathetic degradation of synthetic cis-1,4-polyisoprene (PI) and styrene–butadiene copolymer (SBR) was performed with cis-1,4-diacetoxy-2-butene (DAB) as chain transfer agent (CTA) using Grubbs II catalyst. Well-defined acetoxy telechelic polyisoprene structures were obtained in a selective manner with a wide range of targeted average molecular weights from 350 g mol −1 to 98,000 g mol −1 , with a polydispersity index of around 2. Starting from SBR, a similar structure control was obtained with a range of M n from 1400 g mol −1 to 65,000 g mol −1 . It was found that precise selection of catalyst concentration and solvent is the major factor to obtain targeted products with high M n control. Moreover, preliminary tests using such a procedure have shown its efficiency starting from waste tyre. This methodology thus suggests the possibility to recycle such rubber waste leading to high value liquid rubber.

The photoinitiated polymerization of epoxidized hydroxytelechelic cis-1,4-polyisoprene and of a dual system (epoxidized/ acrylated) telechelic cis-1,4-polyisoprene in the presence of 2,2-dimethyl-1,2-hydroxyacetophenone or/and hexafluoro-phosphate triar- ylsulfonium salt has been studied by real-time infrared spectroscopy. The synthesis of photosensitives oligoisoprenes was achieved by chemical modifications of hydroxytelechelic cis-1,4-polyisoprene obtained by controlled degradation of high molecular weight cis-1,4- polyisoprene. Then, the effect of light intensity, photoinitiator concentration, addition of reactive diluent and concentration of func- tional groups on the photopolymerization process was evaluated. Concerning the cationic process, the results showed that the kinetic profile improves when photoinitiator concentration and light intensity increase. The optimum concentration of triarylsulfonium salt used as photoinitiator was determined as 5% (w/w) and the optimum light intensity was 50 mW cm � 2 . Reactive diluent (3-ethyl-3- hydroxymethyl oxetane) addition greatly improves the ultimate conversion and the polymerization rate. Subsequently, the photopoly- merization kinetic of a dual epoxidized/acrylated system was studied. The results obtained using different photoinitiator mixtures and different intensity of irradiation showed that the crosslinking of acrylate functions at the chain-end prevents the progression of the cationic process at the oxirane groups along the chain. Thus, the mobility of the cationic reactive centers was restricted by the cross- linking at the high conversion of the acrylate double bonds. V C 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 000: 000-000, 2012

Presently, the disposal of thousands of tons of waste tyres produced every year in the whole world is a major environmental problem. Since tyre rubbers do not decompose easily on account of crosslinking and stabilizers, the processing of the waste tyre rubber constitutes a significant technical challenge. This work describes the use of periodic acid for the controlled one-pot oxidative cleavage of carbonyl telechelic cis -1,4-oligoisoprenes (CTNR) and natural rubber (NR) as model compounds and the application of this method to the degradation of ground waste tyre rubber. Average molecular weight analysis of the degraded material indicates that the reaction time and the periodic acid quantity can be used to control the degree of breakdown; we obtained materials in the average molecular weight range of 700–5000 g mol −1 . The processed material shows ketone and aldehyde groups at the chain ends. Degradation studies of waste tyre rubbers were also carried out using this oxidative cleavage by periodic acid, to achieve carbonyl telechelic oligomers. Well-defined structures were obtained with an average molecular weight from 3000 to 7000 g mol −1 according to the periodic acid/waste tyres rubber ratio used.

Novel flexible polyurethane foams were successfully prepared from a renewable source, hydroxytelechelic natural rubber (HTNR) having different molecular weights (1000–3400 g mol−1) and variation of epoxide contents (EHTNR, 0–35% epoxidation) by a one-shot technique. The chemical and cell structures as well as physico-mechanical, thermal, and acoustic properties were characterized and compared with commercial polyol analogs. The obtained HTNR based foams are open cell structures with cell dimensions between 0.38 and 0.47 mm. The HTNR1000 based foam exhibits better mechanical properties but lower elongation at break than those of commercial polyol analog. However, the HTNR3400 based foam shows the best elastic properties. In a series of EHTNR based foams, the tensile and compressive strengths show a tendency to increase with increasing epoxide content and amount of 1,4-butanediol (BD). The HTNR based foams demonstrate better low temperature flexibility than that of the foam based on commercial polyol. Moreover, the HTNR based polyurethane foams was found to be an excellent absorber of acoustics. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010

New crosslinked ionic polyurethanes and copolyurethanes were yielded by reaction of telechelic cis-1,4-oligoisoprenes, bearing a variable number of ammonium and hydroxy groups, with isocyanurate of isophorone diisocyanate (I-IPDI). Aiming for a comparative study, polyurethane elastomers based on non-ionic telechelic oligomers were also synthesized. Thermo-mechanical behavior and crosslinking density of these three families of materials were investigated by DMTA and swelling test, respectively. Surface properties were examined by static contact angle measurements and AFM imaging. The bactericidal activity of the polymers was investigated by enumerating living Pseudomonas aeruginosa on material surfaces and on water suspensions. The number of attached living bacteria was found to depend on the chemical structure of the material and on the contact time between the microorganisms and the surface. An exclusive bactericidal activity was obtained with the ionic copolyurethane family. Materials with weak crosslinking density were found to release bactericidal moieties. The abilities of the polymers to prevent bacterial growth were examined through zone of inhibition experiments against P. aeruginosa, which shown a bacteriostatical effect for each synthesized material. These experiments were not sufficiently sensitive to detect the leaching of bactericidal moieties from the materials with weak crosslinking density. When the zone of inhibition experiments was performed on more sensitive bacteria, namely Staphylococcus epidermidis, the leaching of bactericidal moieties as well as bacteriostatic effect was detected. This work demonstrates the potentiality for making functional biomaterials from natural rubber, a renewable resource.

International audience; This work describes the influence of silica fillers on the thermomechanical properties of diglycidyl ether of bisphenol A/triethylenetetramine (DGEBA/TETA) epoxy resins during ageing under electron beam irradiation. Whatever be the silica filler (pure micrometric ground and spherical silicas, nanometric silicas and coupling agent treated silicas), the glass transition temperature of the epoxy resins decreases with increasing irradiation dose, meaning that the main effect of the irradiation is chain scission. No influence of the silica fillers has been detected from the changes in the glass transition temperature with the increase in the irradiation dose. The disappearance of the cooperativity of the ? relaxation, the decrease of the a relaxation and the decrease of the elastic modulus at the rubbery plateau observed by dynamic mechanical analyses involve a decrease in the crosslink density of the epoxy resins. The occurrence of chemical reactions between the epoxy resin and the silica surface at high irradiation doses has been shown. Moreover, we show evidence that chemical reactions between the epoxy resin and the silica surface occur at high irradiation dose.

The study of the chemical modifications of model compounds of the diglycidyl ether of bisphenol A/triethylene tetramine (DGEBA/TETA) epoxy resins under electron irradiation is described. The reaction of butylamine and N , N′ -diethylethylene diamine with DGEBA afforded model compounds of the DGEBA/TETA structure. Nanometric silica was used as filler for these model compounds. 1 H and 13 C NMR analyses allowed identification of the chemical structures before and after irradiation. C–O and C–N scissions were observed with the formation of phenolic and methyl-ketone ends and of primary and secondary amines. For the model compounds containing the 1,2-diaminoethylene structure, the scission of the C–N bond is followed by the formation of an enamine end. The mechanisms of the different bond scissions are proposed. The presence of the nanometric silica fillers allows the protection of some C–N bonds. The reaction of the chemical species formed by electron irradiation with the reactive functions at the silica surface is proposed to explain the chemical modifications observed on the irradiated filled model compounds.

Carbonyl telechelic cis-1,4-oligoisoprene (CTPI) obtained from high molecular weight polyisoprene through an oxidative chain cleavage reaction have been chemically modified. Thus, new well defined amino telechelic cis-1,4-oligoisoprenes have been obtained in a mass range of 1600–2300 g/mol according to two different pathways. The first approach involved a standard mesylate displacement by sodium azide followed by smooth reduction using triphenylphosphine. The second pathway implied a reductive amination sequence. Primary or secondary amine functions have thus been selectively obtained at both oligomer chain-ends depending on reaction conditions. Peculiar NMR experiments conducted on these functional oligomers confirmed a precise control of functionality during the chemical modification. Moreover, their abilities to react with toluene diisocyanate or bis(succinimidyl)carbonate have been investigated.

Degradation studies of cis-1,4-polyisoprene were carried out using first and second generation Grubbs catalysts to achieve end-functionalized acetoxy oligomers in both an organic solvent and a latex phase at room temperature. Well-defined acetoxy telechelic polyisoprene structures were obtained in a selective manner with arange of M n from 10 000 to 30 000, with a polydispersity index of around 2.5.

Depolymerization of 20% epoxidized cis-1,4-polybutadiene was carried out through alkenolysis of the butadiene repeat units (B) using 4-octene as depolymerizing agent (DA) and bis(tricyclohexyl phosphine)benzylidene ruthenium (IV) dichloride (1) as catalyst. The average molecular weight of the depolymerization products was determined by NMR, and SEC, and their constituents were identified by GC MS. Cis-4-octene was found more efficient in performing the depolymerization as compared to its trans isomer. Besides dodeca-4,8-diene and hexadeca-4,8,12-triene, 2,3-di[3-heptenyl]-oxirane with a cis oxirane configuration was clearly characterized. Beside the DA to B mole ratio, the catalyst to double bond mole ratio was observed as the major factor controlling the molecular weight of the depolymerization products and the 2,3-di[3-heptenyl]-oxirane yields.

A new automated set-up based on the original Sturm test was developed for determining the biodegradability of proteic mulching films. This method is based on the measurement of released (respiratory metabolism of microorganisms) carbon dioxide to determine film biodegradability. Maintenance of constant aerobic conditions in thermoregulated bioreactors and continuous measurement of released CO2 with an infrared differential gas analyser were the main advantages of this set-up. It was verified with a plasticised proteic film that soil extracts could be used as microbial sources instead of activated sludge that was usually used in laboratory biodegradation tests. To cite this article: S. Lefaux et al., C. R. Chimie 7 (2003).

Telechelic cis-1,4-oligoisoprenes were prepared by the selective cleavage of weak epoxidized units (E) in epoxidized cis-1,4-polyisoprenes (EPIs) and by the random cleavage of isoprenic units (I) in cis-1,4-polyisoprene (PI). In both cases, cleavage by periodic acid (H 5 IO 6 ) in tetrahydrofuran led to aldehydic and ketonic chain ends. Through variations in the E/(I + E) molar percentage (E%) in the cleavage of EPI and through variations in the H 5 IO 6 /I molar percentage (PA%) in the cleavage of PI, a polydispersity index near 2 and a number-average molecular weight of 2 - 20 × 10 3 were obtained. The correlation of the degree of scission with E% and PA%, combined with kinetic, led to the proposal of a two-step mechanism for the H 5 IO 6 cleavage of double bonds.

ROMP of the optical pure monomer of the title compound (1) was performed successfully using the classical WC1 6 /SnMe 4 catalyst. Beside the stereoregularity (σ c = 0.70), the 13 C NMR spectrum of the resulting polymer (P 1 ) evidenced a noticeable directional regularity (B = (HT + TH)/(HH + TT) = 1.6) which can be due to sterically induced regiospecificity in the norbornenyl ring opening during propagation. Significant optical activities were observed for P 1 and for poly(norbornene-2-carboxylic acid) (P 2 ) resulting from LiOH hydrolysis of P 1 is probably due to the homochiral pantolactonyl side chain and the (S) C 2 backbone carbon.

New copolyethers were prepared by chemical modification of polyepichlorohydrin and poly(3,3-bis(chloromethyl)oxetane) with the sodium salt of either 4-hydroxy-4'-nitrostilbene or 4-hydroxy-4'-cyanoazobenzene, employing the concept of having the nitrostilbene or cyanoazobenzene species serve concomitantly as both the nonlinear optical (NLO) chromophore and the mesogenic moiety in the polymer. Their thermal behavior was established by means of differential scanning calorimetry (DSC) and optical microscopy. The NLO properties of two nematic copolyethers were studied. The NLO mesogenic groups were oriented by the standard corona poling technique and the degree of axial ordering was determined as a function of poling conditions. The second harmonic coefficients d 31 and d 33 were measured. The results showed that liquid crystallinity enhances field-induced polar ordering. The ratio d 33 /d 31 was found to be much larger than 3, in agreement with the theoretical models for electric field poling of liquid crystals. We were able to obtain d 33 values up to 130 pm/V at λ = 1,064 μm, thus exceeding many values previously reported for second harmonic generation measurements on isotropic polymers containing similar side chain chromophores.

Optimal conditions for distannoxane catalyzed transesterification of methyl esters with benzylic alcohols were established by studying the polycondensation of hex-3-ene-1,6-bis(methyl oate) (1) with 1,4-bis(hydroxymethyl)benzene (2). α,ω-Dicarbomethoxy-1,4-oligobutadiene (3) was obtained by cross metathesis between cycloocta-1,5-diene and 1. The synthesis of 1,4-bis[4-(hydroxymethyl)cinnamoyl]-benzene (4) were conducted starting from 4-(diethoxymethyl)benzaldehyde (5) and 1,4-diacetylbenzene. Finally the organosoluble polyester (PE3/4) were synthesized by reacting 3 with 4 and the occurrence of crosslinkings by UV irradiation was checked.

A chain cleavage reaction allowing the transformation of high molecular weight polymers in well-defined oligomers can be considered as a step in a synthetic scheme. The control of oligomers with respect to their average molecular weights, their molecular weights distributions and their chain-end microstructures implies the control of the cleavage reaction with respect to its yield, its regiospecificity and its chemiospecificity. Among several examples of efficient uses of this principle for the preparation of liquid oligomers from unsaturated polymers, attention is focused (I) on controlled oxidative degradation of rubber and (II) on metathetical controlled degradation of 1,4-polydienes and polyakenamers. (I.a) The mechanism of the phenylhydrazine accelerated oxidation of rubber in the latex phase is described according to accurate structural studies on molecular model molecules. (I.b) The epoxidation of rubber and periodic acid cleavages of epoxides in the latex phase are interpretated referring to the innuence of the biphasic medium. The results are in agreement with interfacial blocky epoxidation by the water-soluble reagent and interfacial arrangement of the epoxidized block to be cleaved. Finally the metathetical degradations resulting from back-bitting cyclisation and cross metathesis with acyclic alkenes are presented as preparative methods to get (II.a) well-defined cyclic oligomers and (II.b) telechelic oligomers (i.e. terminally functionalized oligomers).

Low-molecular-weight organosilane polymers were prepared by sodium and potassium/sodium coupling of dichloromethylphenylsilane (1) with chlorotrimethylsilane (2). Size exclusion chromatography (SEC), IR, UV and NMR (1H, 13C and 29SI) analysis of the crude α,ω-bis(trimethylsilyl) oligo(methylphenylsilane) (3) were performed and compared with those of the isolated shortest oligomers. According to an anionic mechanism, the solvent and alkali-metal effects on the yield and the oligomer distribution (SEC-resolved) allow an optimisation for the synthesis of the shortest oligomers (trisilane and tetrasilane).

The coupling of dichloromethylphenylsilane (1) with chlorotrimethylsilane (2) by lithium is considered for the synthesis of low-molecular-weight organosilane polymers 3 and for the preparation of heptamethylphenyl-2-trisilane (3a) and octamethyldiphenyl-2,3-tetrasilane (3b). Size-exclusion chromatography, ultraviolet and infrared spectroscopies and nuclear magnetic resonance (1H, 13C and 29Si NMR) analyses of the crude product 3 were performed and compared with those of 3a and 3b. According to the spectroscopic characteristics of heptamethyltetrakis(trimethylsilyl)-3,4,5,6-cyclohex-1-enyl-2-trisilane (4), and the observed silylation of the trisilane 3a when it is submitted to the action of a (CH3)3SiCl/Li/tetrahydrofuran system, the silylation of the phenyl ring during the reductive condensation of the chlorosilanes is supported by NMR identification of 4-like structures.

Low-molecular-weight organosilane polymers were prepared by sodium coupling of dichloro-methylphenylsilane (1) with chlorotrimethylsilane (2). Gel permeation chromatography (GPC), IR and NMR (1H, 13C and 29Si) analysis of the crude product (3) were performed and compared with those of the isolated first oligomers, trisilane (3a) and tetrasilane (3b). The GPC characteristics, especially high resolution ones, in accordance with the α,ω-bis(trimethylsilyl)-oligo(methylphenylsilane) structure are compared with those of hydrocarbon polymers. The relations of the NMR characteristics of the methylphenylsilanediyl unit with the position along the chain and the configuration of the diads are approached. Some spectroscopic indications of the secondary structure are discussed.

Telechelic oligoisoprenes were successfully prepared by the selective controlled degradation of natural rubber, a renewable source, via epoxidation and cleavage reactions. The molar mass of the oligoisoprene product obtained depends on the degree of epoxidation of the starting materials. The chemically modified structures obtained via epoxidation, hydrogenation, and ring opening of epoxide groups were also studied, and the chemical structures and thermal properties of the oligoisoprene products were determined. Moreover, the preliminary study of preparation of hydroxytelechelic natural rubber (HTNR)-based polyurethane foam was performed. A novel HTNR-based polyurethane foam was successfully prepared and its thermal properties were investigated and the results indicated that the HTNR-based polyurethane foam has a good low temperature flexibility. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010

The first [4 + 2] inverse electrodemand heterocycloaddition between hydroxytelechelic oligoisoprenes and the benzylidene pyruvic methyl ester promoted by tin tetrachloride is described. A partial hydrogenation of hydroxytelechelic oligoisoprenes was necessary to selectively promote the cycloaddition.

The results of studies of co-metathesis reactions of 1,5-cyclooctadiene (1) with dimethyl 3-hexenedioate (2a) and for comparison, with 4-octene (2b) and 1,5-hexadiene (2c) are analyzed in order to approximate the relative reactivities of the carbene species and of the different types of double bonds. To this end, the experimental distributions of the first telomers are compared with theoretical ones calculated on the one hand allowing equal probability of arrangement of alkylidene groups and on the other hand allowing a kinetic control of propagation and transfer reactions. In other respects, the possibilities of mass control of the products obtained by the same co-metathesis or by degradation of 1,4-polybutadiene are studied. The results show that the reactivity of the 1,5-cyclooctadiene double bonds is higher than that of the other types of double bonds, this being in agreement with the hypothesis of stabilization of the β-carbomethoxycarbene species by carbene/ester complexation. This stabilization allows us to explain the distribution of α,β-difunctional oligomers in agreement with the hypothesis of kinetic control. The distribution of non-functional oligomers agrees with a random combination of alkylidene groups. This stabilization is compatible with the controlling method of molecular weights in the products obtained by polymerization of cyclooctadiene and also by degradation of 1,4-polybutadiene in the presence of 2a.

New segmented polyurethanes (thermoplastic-elastomers) based on previously described hydroxytelechelic cis-1,4-polyisoprene (HTPI), miscellaneous isocyanates and chain extenders at various equivalent ratios were prepared by the classical one-shot method. The influence of the nature of isocyanate and chain extender, as well as their equivalent ratios, on the mechanical and thermal materials behavior was investigated. Thus, a comparative assessment of material properties was performed. Microphase separation of hard and soft segments was observed by DMTA, DSC and AFM. Moreover, according to Thermogravimetric Analysis (TGA), linear relationships depending on the isocyanate and chain extender nature were found between the weight loss (%) and the percentages of hard segments. A classification of thermal stability in terms of weight loss was established. With the aim of a thermo-mechanical comparative study, polyurethane elastomers based on HTPI and isocyanates without chain extender, were also synthesized.

New telechelic cis -1,4-polyisoprene oligomers bearing an hydroxyl group at the end of the polyisoprene backbone and possessing controlled molecular weights were used as soft segments in the elaboration of polyurethane elastomers. Besides, the well defined hydroxytelechelic cis -1,4-polyisoprene (HTPI) structure obtained through a controlled methodology, was chemically modified leading to hydrogenated and epoxidized oligomers based polyurethanes. The influence of the structural changes of these precursors on the polyurethanes properties have been studied. Thus, mechanical parameters as well as glass transition and mechanical transition temperature measurements indicated an increase in PUs hardness when the length of soft segment decreases and when the degree of epoxidized and hydrogenated isoprenic moieties increases. Moreover, based on thermogravimetric analysis (TGA), a linear relationship was established between the weight loss in the urethane stage degradation and the amount of hard segments in the PUs. Otherwise, the hydrogenated soft segments were found more thermally stable than the epoxidized and the non modified ones. By comparison with similar investigations developed from commercial oligodienes (PBHT R20 LM ® and EPOL ® ), this study mainly showed that the PUs based on hydrogenated hydroxytelechelic cis -1,4-polyisoprenes were more thermally stable and softer than the EPOL ® based analogues.

ROMP and retro-acyclic diene metathesis (ADMET) were used for the synthesis of new functional polymers and functional oligomers, respectively. Purely exo and enantiomerically pure norbornene and 7-oxanorbornene derivatives were prepared using stereospecific synthesis, effective fractionation and high yield condensation reactions. Successful ROMPs of those monomers were performed using either the new carbenic Schrock’s or Grubb’s catalysts or in some cases a classical bicomponent catalyst. New functional polymers such as optically active poly(norbornene-2-carboxylic acid), reactive poly(norbornene-2-azlactone), and side-chain liquid crystal polyoxanorbornenes were fully characterized. On the other hand, successful depolymerizations of 1,4-polyisoprene and of epoxidized 1,4-polybutadiene via cross-metathesis with 4-octene were performed using a stabilized bicomponent catalyst and the Grubb’s catalyst, respectively. Conditions for the controlled synthesis of epoxidized oligobutadienes and of epoxydienic monomers via retro-ADMET were clearly defined. © 2002 Elsevier Science B.V. All rights reserved.

Resume Les meilleures conditions (proportion de catalyseur, temperature et duree de reaction) pour obtenir la metathese croisee du cyclopentene (CP) avec l'octene-4 ( 1a ) et l'hexene-3 dioate de dimethyle ( 1b ) par utilisation du catalyseur WCl 6 /Sn(CH 3 ) 4 , ont ete recherchees. Les oligopentenameres dieniques et trieniques sont isoles et des produits secondaires identifies. L'application des conditions requises pour la metathese croisee de 1b avec CP, a CP seul provoque l'oligomerisation cationique de CP et l'alkylation du solvant. Les resultats sont en accord avec l'hypothese de stabilisation des especes actives en metathese par les fonctions esters.

In order to identify phenylhydrazone structures in the reaction products of oxidized polyisoprene or its models with phenylhydrazine, the UV, 1H NMR, 13C NMR and MS spectra as well as the steric exclusion chromatography parameters were determined for phenylhydrazones derived from aldehydes and ketones, selected as models of conjugated carbonyl structures, which could result from the oxidation of polyisoprene units. By comparison with possible coexistent structures, inclusively phenylhydrazones of non-conjugated carbonyl derivatives, oxidized polyisoprene structures can be identified.

Some constituents and structures in the mixtures obtained by reaction of oxygen with model compounds of 1,4-polyisoprene in the presence of phenylhydrazine (1) could be identified. Accelerated oxidation of monomeric units 2 of 1,4-polyisoprene by phenyl radical generation (reaction of 1 with oxygen) and in situ decomposition of hydroperoxides, allow to explain the formation of epoxidized and hydroxylated units which were identified. Identification of phenylsubstituted alcohols and phenyl ketones leads to the proposition of a chain cleavage process involving the addition of phenyl radicals to the double bonds of 2. No more carbonyl compounds or structures resulting from peroxide decompositions by carbon-carbon bond cleavage could be detected. The hypothesis of their transformation into phenylhydrazones, followed by oxidation and decompositions, is supported by indications of phenylazo structures, but has to be confirmed.

Studies of metathetic degradation of polybutadienes containing 70 to 80% of 2-butene-1,4-diyl units (1) in presence of dimethyl 3-hexenedioate (2) were carried out applying WCl6/Me4Sn as catalyst and r = [2]/[1] values varying between 0,4 and 0,01. The degradation was followed by steric exclusion chromatography, and the structural composition of degraded products was determined by 1H NMR. For r = 0,2, the degradation by cross metathesis between 1 and 2, leading to α,ω-bifunctionalized “prepolymers”, is superimposed by degradation via intramolecular metathesis and cationic cyclization of 1 units. Cationic side reactions (cyclization) are minimized by addition of ethyl acetate to the catalytic system.

With regard to the postulated intervention of phenylhydrazone structures during the degradation of 1,4-polyisoprenes by the phenylhydrazine (1)/oxygen system, UV, 1H NMR, 13C NMR and mass spectroscopy as well as steric exclusion chromatography were applied for the characterization of model phenylhydrazones deriving from non conjugated carbonyl derivatives. Comparison of the results with some possible coexistent structural parameters gave some indications on the validity of these analytical tools for the identification of phenylhydrazone structures in oxidized polyisoprene.