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Your search keyword '"Kottas, Gregg S."' showing total 1 results
Start Over Author "Kottas, Gregg S." Topic chirality -- analysis
1 results on '"Kottas, Gregg S."'

1. Coordination-driven face-directed self-assembly of trigonal prisms: face-based conformational chirality

Author

Caskey, Douglas C., Yamamoto, Takuya, Addicott, Chris, Shoemaker, Richard K., Vacek, Jaroslav, Hawkridge, Adam M., Muddiman, David C., Kottas, Gregg S., Michl, Josef, and Stang, Peter J.

Subjects
Chirality -- Analysis, Organometallic compounds -- Chemical properties, Platinum -- Chemical properties, Pyridine -- Chemical properties, Chemistry
Abstract

The coordination-driven self-assembly of four different trigonal prisms from 3 equiv of one of four different tetrapyridyl star connectors and 6 equiv of a platinum linker dication in nitromethane is presented. The use of a conformationally chiral star connector leads to a conformationally chiral prism when connector arm ends attached to a vertex have a strongly correlated twist sense and chirality is communicated across polyhedral faces, edges, and vertices.

Published
2008

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