1. Post-modification of Cellulose Nanocrystal Aerogels with Thiol-Ene Click Chemistry.
- Author
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Aalbers GJW, Boott CE, D'Acierno F, Lewis L, Ho J, Michal CA, Hamad WY, and MacLachlan MJ
- Subjects
- Hydrophobic and Hydrophilic Interactions drug effects, Porosity, Sulfhydryl Compounds chemistry, Cellulose chemistry, Click Chemistry, Gels chemistry, Nanoparticles chemistry
- Abstract
The functionalization of cellulose nanocrystal (CNC) aerogels was achieved through a two-step synthetic procedure. CNC aerogels were prepared under hydrothermal conditions, followed by solvent exchange and critical point drying. The CNC aerogels were functionalized with a methacrylate group and then underwent thiol-ene click chemistry to impart a range of functionalities onto the surface of the CNC aerogel. The use of the functionalized aerogels as oil absorbents was then investigated, with the most hydrophobic CNC aerogel, 1 H,1 H,2 H,2 H-perfluorodecanethiol-functionalized CNC aerogel, exhibiting the highest absorption of xylenes at 2.9 mL g
-1 .- Published
- 2019
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