Search

Cofiring of coal slime in existing utility boilers is a promising approach to the disposal of coal slime. However, reports about cofiring coal slime with anthracite in the down-fired utility boiler are still few. This work presents a comprehensive study on the combustion characteristics, slagging potential, and NOx emissions of cofiring coal slime and anthracite through lab-scale experiments, numerical simulations, and full-scale industrial measurements in a 600MW down-fired utility boiler. The lab-scale experiments show combustion interactions between anthracite and coal slime, which have both a promotive effect on the ignition of anthracite and inhibitive effect on the combustion and burnout of anthracite. Especially, the inhibitive effect is greater than the promotive effect when the blending ratio of coal slime is above 5%. The addition of coal slime can effectively improve the ash fusion temperature of blended samples. In addition, simulations and full-scale industrial measurements of anthracite cofiring with coal slime are performed in a down-fired utility boiler. The results show that as the blending ratio of coal slime increases, the carbon content in fly ash increases and the boiler efficiency and NOx emissions decrease. A 5% ratio is validated to be a reasonable cofiring ratio of coal slime in the actual operation without no slagging phenomenon. These results provide more insights into the cofiring behavior of coal slime and anthracite and guide the application of blending coal slime in a down-fired boiler. [ABSTRACT FROM AUTHOR]

Coal combustion is the major contributor to global toxic selenium (Se) emissions. Inorganic elements in coals significantly affect Se partitioning during combustion. This work confirmed that the calcium (Ca) in ash had a stronger relationship with Se retention at 1300 °C than other major elements. Ca oxide chemically reacted with gaseous Se, and its sintering densification slightly affected Se adsorption capacities (44.45 −1840.71→35.17 −1540.15 mg/kg) at 300 − 1300 °C. Therefore, Ca in coals was identified as having potential for hindering gaseous Se emissions, and coals with increased Ca contents (2.74→5.19 wt%) were used in a 350 MW unit. The decreased Se mass distribution (3.54%→2.63%) in flue gas at air preheater inlet (320 −362 °C) confirmed the effectiveness of increased Ca content on gaseous Se emission reduction. More gaseous Se further condensed and was chemically adsorbed by fly ash when passed through an electrostatic precipitator, resulting in a significant increase in the Se content of fly ash. Additionally, the corresponding Se leaching ratio decreased from 4.88 − 35.74% to 1.87 − 26.31%, indicating enhanced stability of Se enriched in fly ash. This research confirmed the feasibility and environmental safety of sequestration of gaseous Se from flue gas to fly ash by increasing the Ca content in coals. [Display omitted] ● Se retention at 1300 °C is associated with Ca content in ash. ● Ca oxide removes more gaseous Se via chemical reaction during flue gas cooling. ● Coals with higher Ca contents will release less gaseous Se into flue gas. ● A higher Ca content in fly ash can enhance the stability of Se within. ● Electrostatic precipitator induces Se emission reduction with increased Ca content. [ABSTRACT FROM AUTHOR]