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The effects of six ionic liquids with surfactant property (1-hydroxyethyl-3-methyl imidazolium bis(trifluoromethylsulfonyl)imide ([HOEtMIm][NTf2]), 1-hydroxyethyl-3-methyl imidazolium tetrafluoroborate ([HOEtMIm][BF4]), 1-dodecyl-3- methyl imidazolium bromide ([C12MIm]Br), 1-tetradecyl-3- methyl imidazolium bromide ([C14MIm]Br), trioctyl methyl ammonium chloride ([N8,8,8,1])Cl, and tetraethyl ammonium chloride ([N2,2,2,2]Cl)) on the oxidation characteristics and functional groups of coal were studied by means of critical micelle concentration, surface tension, thermogravimetric analysis, temperature-programmed oxidation, and Fourier transform infrared spectroscopy (FTIR) measurements. The lower critical micelle concentration for the ionic liquids except the [N2,2,2,2]Cl suggests the favorable surface activity of these ionic liquids. The surface activities of [N8,8,8,1]Cl, [C14MIm]Br, [C12MIm]Br, and [HOEtMIm][NTf2] were high, while that of [N2,2,2,2]Cl was relatively lower. The thermal stabilities of [HOEtMIm][NTf2] and [HOEtMIm][BF4] were high, while those of [N8,8,8,1]Cl and [N2,2,2,2]Cl were lower. The oxidation activities of ionic liquid-mixed coals were weakened to different degrees except [N8,8,8,1]Cl-mixed coal, because of the poor thermal stability and decomposition of [N8,8,8,1]Cl accelerating the coal oxidation. The other five ionic liquids were suitable for inhibiting coal oxidation, particularly the [HOEtMIm][BF4] and [HOEtMIm][NTf2] with higher inhibition rate, longer inhibition time, and also better thermal stabilities. The activation energy results further confirmed such inhibition effect. The functional group results showed that treatment of ionic liquids on coal can change the contents of hydrogen bonds, aliphatic groups, and aromatic groups in coal. It was inferred that the [HOEtMIm][BF4], [HOEtMIm][NTf2], and [C14MIm]Br were more effectively to affect coal structure and decrease coal oxidation activity. [ABSTRACT FROM AUTHOR]

Fly ash cement is used to solidify marine clay to prepare marine-clay-based cemented paste backfill (MCCPB) to fill the underground goaf of mines, which not only utilizes solid waste such as fly ash and marine clay, but also controls surface subsidence and protects the environment. To simulate the complex underground mine water environment of the filling body, a dry-wet cycle aquatic environment test under different material ratios and curing ages was designed. The water absorption and unconfined compression strength (UCS) of MCCPB with curing ages of 7 and 28 days under the action of 0, 1, 3, and 7 dry-wet cycles were investigated. The results indicate as the number of dry-wet cycles increases, the surface of MCCPB becomes significantly rougher, and the water content and the solid mass decrease accordingly. Different ratios and curing ages of MCCPB in dry-wet cycles of the UCS tend first to increase, then decrease. Meanwhile, the stress-strain curve of the specimen shows that the trend in the elastic modulus is consistent with that of UCS (first increasing, then decreasing), and that, the minimum UCS value of the specimen still meets the early strength requirements of cemented paste backfill in coal mine geothermal utilization. On the one hand, it proves the feasibility of fly ash cement-solidified marine clay for use as cemented paste backfill in coal mines; on the other hand, it also expands the available range of cemented paste backfill materials in coal mines. [ABSTRACT FROM AUTHOR]

Coal gangue-based geopolymer (CGGP) is one of the hot spots existing in the recycling of coal gangue resources due to its good comprehensive mechanical properties. However, the coal gangue structure is stable and reactivity is poor, so the coal gangue needs to be activated before utilization. In this paper, the microstructure changes of activated coal gangue by different mechanical and thermal activation methods, as well as the mechanical properties and microstructure changes of the CGGP specimens were studied by experimental investigation. The results indicated that mechanical activation and thermal activation were two effective methods to change the reactivity of coal gangue, which consisted of destroying the stable kaolinite structure and improving the activity of coal gangue. Conversely, part of the amorphous structure in coal gangue was destroyed when the activation temperature reached 900 °C, which was not conducive to the further enhancement of coal gangue activity. For the CGGP prepared by thermally activated coal gangue and modified sodium silicate alkali solution, the uniaxial compressive strength of the CGGP specimens decreased with thermal activation temperatures of the raw coal gangue materials at 700 °C, 800 °C, and 900 °C. The main reason for this was the lower amount of the active metakaolin structure in coal gangue at 900 °C, which was not conducive to the geopolymerization process. [ABSTRACT FROM AUTHOR]

In underground tunnels, caverns or pillar goaf, the time-dependent deformation or failure of the rock or coal mass is a major safety concern, which affects the mechanical properties and stability of the coal and rock in the underground excavations. However, the damage surrounding rock or coal usually occurs from the time mining starts. This initial damage is rarely considered during the current creep tests used for coal. In the present study, an experimental specimen processing method to identify the initial damage to a coal deposit is suggested. The effect of the strain history on the deformation of coal samples with initial damage during multi-level loading triaxial compression creep tests was studied. The laboratory tests showed that the strain versus creep curve of the coal samples experiences three typical creep stages of deceleration creep in the early stage, constant velocity creep in the medium term and catastrophic accelerated creep in the later stage. With the increase in initial damage, it was observed the gradual decrease in total creep time, deviating stress of creep failure, stress threshold of accelerated creep and starting time of the volume expansion. When the initial damage value increased from 0.0 to 0.50, the deviating stress of creep failure, stress threshold of accelerated creep and starting time of the volume expansion of the coal decreased by 42.3%, 48.5% and 51.4%, respectively. The study is of great significance to conduct researches on the deformation, mechanical characteristics and long-term strength of coal pillar with initial damages under long-term pressure, and also provides insight into the underground excavations and the design of supports to the opneings under such disturbance. [ABSTRACT FROM AUTHOR]