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Smart control systems and new technologies are necessary to reduce the energy consumption in buildings while achieving thermal comfort. In this work, we monitor the thermal evolution inside a scale reduced closed space whose exterior and/ or interior wall faces have been painted with a coating solution. Based on the experimental data obtained under different environmental conditions, a simulator was developed and tuned to reproduce the thermodynamic behavior inside the spaces, with a relative error of less than 3.5%. This simulator lets us also estimate energy savings, temperature, and flux behavior under other conditions. [ABSTRACT FROM AUTHOR]