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Bringing solid-state lithium batteries to market is a challenge; in part because their fabrication requires a technically difficult step of solid-electrolyte separator assembly, and because thus far, solid-state cells have only cycled under high pressure. Here, we address both these bottlenecks by assembling lithium-ion batteries based on the argyrodite Li 6 PS 5 Cl as the electrolyte using standard coating processes. Moreover, we upscaled to 10 cm2 pouch cells in a dry room by a double casting technique, thanks to the use of fluorine-free polyisobutene as the binder and nanosilicon and LiNi 0.6 Mn 0.2 Co 0.2 O 2 (NMC622) respectively as the anode and cathode active materials. Electrode casting is shown to significantly improve the cycling stability when compared to the conventional pelletizing process. The all-coated pouch cells, cycled at a pressure as low as 1 MPa over 160 cycles, show a better capacity retention than the pelletized cells cycling under >100 MPa. The higher performance of the sheet-type cell is thought to originate in the better densification and homogeneity of the cell, attested by its low resistance. [Display omitted] • Si-NMC pouch cells with Li 6 PS 5 Cl solid electrolyte. • Both electrodes and separator casted via conventional ink coating process. • Cell scaled up from 0.4 cm2 (pelletized cell) to 10 cm2 (all-coated pouch cell). • The coating process improved long-term stability. • Pouch cells cycled under 1 MPa perform better than pelletized cells at 127 MPa. [ABSTRACT FROM AUTHOR]