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To each finite subset of $\mathbb{Z}^2$ (a diagram), one can associate a subvariety of a complex Grassmannian (a diagram variety), and a representation of a symmetric group (a Specht module). Liu has conjectured that the cohomology class of a diagram variety is represented by the Frobenius characteristic of the corresponding Specht module. We give a counterexample to this conjecture. However, we show that for the diagram variety of a permutation diagram, Liu's conjectured cohomology class $\sigma$ is at least an upper bound on the actual class $\tau$, in the sense that $\sigma - \tau$ is a nonnegative linear combination of Schubert classes. To do this, we exhibit the appropriate diagram variety as a component in a degeneration of one of Knutson's interval positroid varieties (up to Grassmann duality). A priori, the cohomology classes of these interval positroid varieties are represented by affine Stanley symmetric functions. We give a different formula for these classes as ordinary Stanley symmetric functions, one with the advantage of being Schur-positive and compatible with inclusions between Grassmannians., Comment: 15 pages