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This study was performed to test the combustive properties of Medium Density Fibreboards (MDFs) treated with chemicals of the bis-(dimethylaminomethyl) phosphinic acid (DMDAP), N,N-dimethylethylenediaminomethyl-bis-phosphonic acid (DMDEDAP), piperazinomethyl-bis-phosphonic acid (PIPEABP), and methylpiperazinomethyl-bis-phosphonic acid (MPIPEABP). MDFs were painted in three times with 15 wt% solution of the bis-(dimethylaminomethyl) phosphinic acid and alkylenediaminoalkyl-bis-phosphonic acids at the room temperature, respectively. After drying MDF treated with chemicals, combustive properties and volatile organic compounds (VOCs) contents were examined by the cone calorimeter (ISO 5660-1), test for flame retardant (NEMA Notice No. 2012034), and gas chromatography (KS M ISO 11890-2), respectively. It was indicated that the MDFs treated with chemicals showed the longer time to combustion time (CT) = (442~492) s than that of virgin plate by reducing the burning rate except for CT treated with DMDAP. In adition, the MDFs treated with chemicals showed both of the higher char area (44.33~61.33) kg/kg and char length (10.33~11.67) cm than those of virgin plate. Especially, the MDFs treated with chemicals showed the higher mean volatile organic compounds (VOCs) (0.188~0.333) g/L than that of virgin plate within the prescribed limits. Thus, It is supposed that the combustion-retardation properties were improved by the partial due to the treated chemicals in the virgin MDF.

This study was performed to test combustive properties of medium density fibreboard (MDF) plates treated with piper- azinomethyl-bis-phosphonic acid (PIPEABP), methylpiperazinomethyl-bis-phosphonic acid (MPIPEABP), and N,N-dimethyle- thylenediaminomethyl-bis-phosphonic acid (MDEDAP). MDF specimens were painted three times with 15 wt% solution of the alkylenediaminoalkyl-bis-phosphonic acids at room temperature. After drying specimen treated with chemicals, combustive properties were examined using the cone calorimeter (ISO 5660-1). As a result, combustion-retardation properties increased due to the treatment of bare MDF with alkylenediaminoalkyl-bis-phosphonic acid solution. Especially, the specimens treated with chemicals showed the ignition (TTI) (148 s∼116 s) was retarded and the flameout (Tf) (633 s∼529 s) time increased, while the total heat release rate (THRR) (61.1∼67.0) MJ/m 2 was lowered than those of using virgin plate by reducing the burnig rate. Compared with virgin MDF plate, the specimens treated with the alkylenediaminoalkyl-bis-phosphonic acids showed low combustive properties. However the specimens treated with bis-(dimethylaminomethyl) phosphinic acid (DMDP) showed the higher peak heat release rate (PHRR) (185.08 kW/m 2 ) than that of the virgin plate.

The purpose of this study is to investigate how the ignition spark timing conversion influences the engine performance of LPG/Gasoline Bi-Fuel engine. We propose the control system which can advance the ignition spark timing in LPG fuel mode more than used in gasoline fuel mode. In order to investigate the engine performance during combustion, engine performance are sampled by data acquisition system, for example cylinder pressure, pressure rise rate and heat release rate, while change of the rpm(1500, 2000) and the ignition timing advance(5°,10°,15°,20°) As the result, between 1500rpm and 2000rpm, the cylinder pressure and pressure rise rate was increased when the spark ignition was advanced but pressure rise rate at 20° was smaller value. Also, the heat release rate at 1500rpm was increased but it was lower around 20° at 2000rpm. Key Words : LPG(Liquefied Petroleum Gas), Bi-Fuel Engine, Ignition Timing Advance, Cylinder Pressure, Pressure Rise Rate, Heat Release Rate * 교신저자 : 박명호(parkmh@kangwon.ac.kr)접수일 09년 01월 06일 수정일 (1차 09년 05월 07일, 1차 09년 06월 10일, 3차 09년 07월 16일) 게재확정일 09년 07월 22일

Today every nation faces serious problems of energy supply. Reasonable technologies to make use of coal (including coke) can not only help the mining-related economy which is showing a downward trend but also may fit in with the governmental energy policy. In this research, we aim to supply heating systems in factories, homes, and farms with a substitute fuel by developing coke/waste tire compound fuel with high efficiency for rational use of energy and for recycling of industrial products. A coke/waste boiler was used for this experiment, and different kinds of fuel were experimented including coke, waste tire, coke/waste A and coke/waste B. Four kinds of exhaust gas were also sampled by a gas analyzer, including CO, CO2, NO and NO2 at different temperatures.

This study was to evaluate the feasibility of recycling the solids separated from swine wastewater treatment process as a fuel source for heat production and to provide a data set on the gas emissions and combustion properties. Also, in this study, the heavy metals in ash content were analyzed for its possible use as a fertilizer. Proximate analysis of the solid recovered from the swine wastewater after flocculation with organic polymer showed high calorific (5,330.50 kcal/kg) and low moisture (15.38%) content, indicating that the solid separated from swine wastewater can be used as an alternative fuel source. CO and NOx emissions were found to increase with increasing temperature. Combustion efficiency of the solids was found to be stable (95 to 98%) with varied temperatures. Thermogravimetry (TG) and differential thermal analysis (DTA) showed five thermal effects (four exothermic and one endothermic), and these effects were distinguished in three stages, water evaporation, heterogeneous combustion of hydrocarbons and decomposition reaction. Based on the calorific value and combustion stability results, solid separated from swine manure can be used as an alternative source of fuel, however further research is still warranted regarding regulation of CO and NOx emissions. Furthermore, the heavy metal content in ash was below the legal limits required for its usage as fertilizer.