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Abstract: Analysis of a fuel processor based on methanol steam reforming has been carried out to produce fuel cell grade H2. Six reactor configurations namely FBR1 (fixed bed reactor), MR1 (H2 selective membrane reactor with one reaction tube), MR2 (H2 selective membrane reactor with two reaction tubes), FBR2 (FBR1+preferential CO oxidation (PROX) reactor), MR3 (MR1+PROX), and MR4 (MR2+PROX) are evaluated by simulation to identify the suitable processing scheme. The yield of H2 is significantly affected by H2 selective membrane, residence time, temperature, and pressure conditions at complete methanol conversion. The enhancement in residence time in MR2 by using two identical reaction tubes provides H2 yield of 2.96 with 91.25mol% recovery at steam/methanol ratio of 1.5, pressure of 2bar and 560K temperature. The exit retentate gases from MR2 are further treated in PROX reactor of MR4 to reduce CO concentration to 4.1ppm to ensure the safe discharge to the environment. The risk of carbon deposition on reforming catalyst is highly reduced in MR4, and MR4 reactor configuration generates 7.4NLmin−1 of CO free H2 from 0.12molmin−1 of methanol which can provide 470W PEMFC feedstock requirement. Hence, process scheme in MR4 provides a compact and innovative fuel cell grade H2 generating unit. [Copyright &y& Elsevier]

Abstract: The mathematical modeling of fire growth and smoke movement in any enclosure is a formidable task. Two types of deterministic models are in vogue, zone models and field models (popularly known as CFD technique). CFAST is a popular zone model used for modeling of fires in enclosures. Likewise, CFX is a general purpose CFD code used for various purposes including modeling of fires. In the present paper, a tunnel of length 150m having a rectangular cross-section of 80m2 has been considered for analyzing the temperature and velocity profiles generated by fire, placed at a distance of 20m from one end of portal, by both CFAST and CFX. The simulation by CFAST has been carried out by dividing the tunnel into 1, 2, 5, 8, 10, 12 and 15 compartments of equal size, where these compartments are joined by openings or vents having same cross-section as that of the tunnel. In case of tunnel divided into 15 compartments the fire source position lies at the position of vent; CFAST predicted very high temperatures. The simulations have also been carried out by dividing tunnel into unequal sized compartments such that position of fire was at the center of the compartment. It was found that for accuracy of results, location of fire source inside compartment is an important factor. Computational difficulty was experienced when tunnel was divided into more than 15 compartments. In this paper, a comparative study of temperatures predicted by CFAST and CFX has been done. The CFX and CFAST predictions show that smoke temperature changes with a pattern roughly similar to that of heat release rate. The temperature profiles at selected positions cannot be predicted by CFAST unlike CFX. The detailed features like flame tilt, flow field can only be observed from CFX predictions. [Copyright &y& Elsevier]

The edible and wild cultivars of Dioscorea dumetorum (Kunth) Pax. (Family: Dioscoreaceae) are commonly used as close substitutes in herbal markets due to their edibility and medicinal importance. Comparative study of the cultivars was done using chemical analysis of their methanol tuber extracts and by utilizing the DNA barcode regions, ribulose-1, 5-bisphosphate carboxylase subunits (rbc L) and the non-coding intergenic spacer gene (trn H- psb A) for nucleotide sequences comparison of cultivars. Of the 54 compounds identified from the methanol extract of the edible and wild cultivars using gas chromatography-mass spectrometry (GC-MS), 12 are similar, while 42 are remarkably different. In particular n -hexadecanoic (palmitic) acid had a higher percentage area in the edible cultivar (31.16%) compared to the wild cultivar (0.26%). The cultivars were successfully amplified using the universal primers gene rbc L and trn H- psb A. Their nucleotide sequences showed a slight variation when aligned with CodonCode Aligner V.9.0.1. They were identified by the Basic Local Alignment Search Tool (BLAST) through comparison with Genbank data, which shows close similarities with submitted data. The use of molecular barcoding in identifying the cultivars of Dioscorea dumetorum as well as the chemical composition of their tubers may form an important marker in the compilation of future herbal pharmacopoeia for its proper identification. Image 1 • DNA barcode was useful in identifying cultivars of Dioscorea dumetorum. • GC-MS constituents of D. dumtorum were mainly lipids and terpenoids. • n -hexadecanoic acid provides useful chemical marker in cultivars of D. dumetorum. [ABSTRACT FROM AUTHOR]