An edge colouring of a graph G is complete if for any distinct colours c1 and c2 one can find in G adjacent edges coloured with c1 and c2, respectively. The pseudoachromatic index of G is the maximum number of colours in a complete edge colouring of G. Let ψ(n) denote the pseudoachromatic index of Kn. In the paper we proved that if x≥2 is an integer and n∈{4x2-x,⋯,4x2+3x-3}, then ψ(n)≤2x(n-x-1). Let q be an even integer and let ma=(q+1)2-a. If there is a projective plane of order q, a complete edge colouring of Kma with (ma-a)q colours, a∈{-1,0,⋯,q2+1}, is presented. The main result states that if q≥4 is an integer power of 2, then ψ(ma)=(ma-a)q for any a∈{-1,0,⋯,1+4q+92-1}. [ABSTRACT FROM AUTHOR]