1. CO2-responsive graphene oxide nanofiltration membranes for switchable rejection to cations and anions.
- Author
-
Yin, Congcong, Dong, Liangliang, Wang, Zhaogen, Chen, Mingqing, Wang, Yong, and Zhao, Yue
- Subjects
- *
GRAPHENE oxide , *NANOFILTRATION , *METHACRYLATES , *COMPOSITE membranes (Chemistry) , *POLYETHERSULFONE , *ION transport (Biology) , *WATER purification , *BIOLOGICAL membranes - Abstract
Inspired by biological membranes with charge-gated channels that allow the transport of water and ions but restrict the undesired substances, various regulated nanofiltration (NF) membranes containing charge-gated channels have been developed for water purification. However, most of these membranes are mono-charged (positively or negatively) that show high rejection only to the corresponding co-ions but low rejection to the counter-ions, which limits their wider applications. Herein, we report NF membranes with gas-tunable charge-gated channels and high rejection to different salts on demand. The membranes are prepared by assembling a CO 2 -responsive polymer, poly(N,N-dimethylaminoethyl methacrylate), on the surface of graphene oxide (GO). As a result of CO 2 -induced reversal of the charge sign, the membranes exhibit "self-regulation" of their surface charges. Upon bubbling CO 2 into water, the membranes are positively charged, which shows high rejection to MgCl 2. After bubbling Ar to remove CO 2 , the membranes gradually transform to negatively charged, and high rejection to Na 2 SO 4 is obtained. This study demonstrates the gas-tunable charge-gated ion transport behavior of the CO 2 -responsive NF membranes, and opens up new avenues for the design of on-demand NF membranes. New nanofiltration membranes exhibit on-demand switchable rejections toward cations and anions with the participation and departure of CO 2. Image 1 • New nanofiltration membrane was built with graphene oxide and CO 2 -responsive polymer. • The surface of nanopores can be reversibly switched between opposite charged state. • Charge sign can easily be reversed in a robust and contamination-free manner. • Ion transport behavior was dominated with the participation and departure of CO 2. [ABSTRACT FROM AUTHOR]
- Published
- 2019
- Full Text
- View/download PDF