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Helium implantation in epitaxial thin films is a way to control the out-of-plane deformation independently from the in-plane strain controlled by epitaxy. In particular, implantation by means of a helium microscope allows for local implantation and patterning down to the nanometer resolution, which is of interest for device applications. We present here a study of bismuth ferrite (BiFeO3) films where strain was patterned locally by helium implantation. Our combined Raman, XRD and TEM study shows that the implantation causes an elongation of the BiFeO3 unit cell and ultimately a transition towards the so-called super-tetragonal polymorph via states with mixed phases. In addition, TEM reveals the onset of amorphization at a threshold dose that does not seem to impede the overall increase in tetragonality. The phase transition from the R-like to T-like BiFeO3 appears as first-order in character, with regions of phase coexistence and abrupt changes in lattice parameters.

While ferromagnets are at the heart of daily life applications, their large magnetization and resulting energy cost for switching bring into question their suitability for reliable low-power spintronic devices. Non-collinear antiferromagnetic systems do not suffer from this problem and often possess remarkable extra functionalities: non-collinear spin order may break space-inversion symmetry and thus allow electric-field control of magnetism, or produce emergent spin-orbit effects, which enable efficient spin-charge interconversion. To harness these unique traits for next-generation spintronics, the nanoscale control and imaging capabilities that are now routine for ferromagnets must be developed for antiferromagnetic systems. Here, using a non-invasive scanning nanomagnetometer based on a single nitrogen-vacancy (NV) defect in diamond, we demonstrate the first real-space visualization of non-collinear antiferromagnetic order in a magnetic thin film, at room temperature. We image the spin cycloid of a multiferroic BiFeO$_3$ thin film and extract a period of $\sim70$ nm, consistent with values determined by macroscopic diffraction. In addition, we take advantage of the magnetoelectric coupling present in BiFeO$_3$ to manipulate the cycloid propagation direction by an electric field. Besides highlighting the unique potential of NV magnetometry for imaging complex antiferromagnetic orders at the nanoscale, these results demonstrate how BiFeO$_3$ can be used as a versatile platform for the design of reconfigurable nanoscale spin textures.

Antiferromagnetic thin films are currently generating considerable excitement for low dissipation magnonics and spintronics. However, while tuneable antiferromagnetic textures form the backbone of functional devices, they are virtually unknown at the submicron scale. Here we image a wide variety of antiferromagnetic spin textures in multiferroic BiFeO3 thin films that can be tuned by strain and manipulated by electric fields through room temperature magnetoelectric coupling. Using piezoresponse force microscopy and scanning NV magnetometry in self-organized ferroelectric patterns of BiFeO3, we reveal how strain stabilizes different types of non-collinear antiferromagnetic states (bulk-like and exotic spin cycloids) as well as collinear antiferromagnetic textures. Beyond these local-scale observations, resonant elastic X-ray scattering confirms the existence of both types of spin cycloids. Finally, we show that electric-field control of the ferroelectric landscape induces transitions either between collinear and non-collinear states or between different cycloids, offering perspectives for the design of reconfigurable antiferromagnetic spin textures on demand.

We report the experimental design of a 1D stealth acoustic material, namely a material that suppresses the acoustic scattering for a given set of incident wave vectors. The material consists of multiple scatterers, rigid diaphragms, located in an air-filled acoustic waveguide. The position of the scatterers has been chosen such that in the Born approximation a suppression of the scattering for a broad range of frequencies is achieved and thus a broadband transparency. Experimental results are found in excellent agreement with the theory despite the presence of losses and the finite size of the material, features that are not captured in the theory. This robustness as well as the generality of the results motivates realistic potential applications for the design of transparent materials in acoustics and other fields of wave physics.

The electric field control of functional properties is a crucial goal in oxide-based electronics. Non-volatile switching between different resistivity or magnetic states in an oxide channel can be achieved through charge accumulation or depletion from an adjacent ferroelectric. However, the way in which charge distributes near the interface between the ferroelectric and the oxide remains poorly known, which limits our understanding of such switching effects. Here we use a first-of-a-kind combination of scanning transmission electron microscopy with electron energy loss spectroscopy, near-total-reflection hard X-ray photoemission spectroscopy, and ab-initio theory to address this issue. We achieve a direct, quantitative, atomic-scale characterization of the polarization-induced charge density changes at the interface between the ferroelectric BiFeO3 and the doped Mott insulator Ca1-xCexMnO3, thus providing insight on how interface-engineering can enhance these switching effects., Comment: Work supported by ERC Consolidator grant MINT (Contract No. 615759)

The control of optical fields is usually achieved through the electro-optic or acousto-optic effect in single-crystal ferroelectric or polar compounds such as LiNbO3 or quartz. In recent years, tremendous progress has been made in ferroelectric oxide thin film technology - a field which is now a strong driving force in areas such as electronics, spintronics and photovoltaics. Here, we apply epitaxial strain engineering to tune the optical response of BiFeO3 thin films, and find a very large variation of the optical index with strain, corresponding to an effective elasto-optic coefficient larger than that of quartz. We observe a concomitant strain-driven variation in light absorption - reminiscent of piezochromism - which we show can be manipulated by an electric field. This constitutes an electrochromic effect that is reversible, remanent and not driven by defects. These findings broaden the potential of multiferroics towards photonics and thin film acousto-optic devices, and suggest exciting device opportunities arising from the coupling of ferroic, piezoelectric and optical responses., Comment: Work supported by ERC Consolidator grant MINT (Contract No. 615759)

In tunnel junctions with ferroelectric barriers, switching the polarization direction modifies the electrostatic potential profile and the associated average tunnel barrier height. This results in strong changes of the tunnel transmission and associated resistance. The information readout in ferroelectric tunnel junctions (FTJs) is thus resistive and non-destructive, which is an advantage compared to the case of conventional ferroelectric memories (FeRAMs). Initially, endurance limitation (i.e. fatigue) was the main factor hampering the industrialization of FeRAMs. Systematic investigations of switching dynamics for various ferroelectric and electrode materials have resolved this issue, with endurance now reaching $10^{14}$ cycles. Here we investigate data retention and endurance in fully patterned submicron Co/BiFeO$_3$/Ca$_{0.96}$Ce$_{0.04}$MnO$_3$ FTJs. We report good reproducibility with high resistance contrasts and extend the maximum reported endurance of FTJs by three orders of magnitude ($4\times10^6$ cycles). Our results indicate that here fatigue is not limited by a decrease of the polarization or an increase of the leakage but rather by domain wall pinning. We propose directions to access extreme and intermediate resistance states more reliably and further strengthen the potential of FTJs for non-volatile memory applications.

We report Bessel-like beam formation of acoustic waves by means of an axisymmetric grating of rigid tori. The results show that the generated beam pattern is similar to that of Bessel beams, characterized by elongated non-diffracting focal spots. A multiple foci structure is observed, due to the finite size of the lens. The dependence of the focal distance on the frequency is also discussed, on the basis of an extended grating theory. Experimental validation of acoustic Bessel-like beam formation is also reported for sound waves. The results can be generalized to wave beams of different nature, as optical or matter waves.

We investigate the sound propagation in an air-filled tube periodically loaded with Helmholtz resonators. By tuning the Helmholtz with the Bragg resonance, we study the efficiency of slow sound propagation in the presence of the intrinsic viscothermal losses of the system. While in the lossless case the overlapping of the resonances results in slow sound induced transparency of a narrow frequency band surrounded by a strong and broadband gap, the inclusion of the unavoidable losses imposes limits to the slowdown factor and the maximum transmission. Experiments, theory and finite element simulations have been used for the characterization of acoustic wave propagation. Experiments, in good agreement with the lossy theory, reveal the possibility of slowing sound at low frequencies by 20 times. A trade-off among the relevant parameters (delay time, maximum transmission, bandwidth) as a function of the tuning between Bragg and Helmholtz resonance frequency is also presented.

We present the design of a structured material supporting complete absorption of sound with a broadband response and functional for any direction of incident radiation. The structure which is fabricated out of porous lamellas is arranged into a low-density crystal and backed by a reflecting support. Experimental measurements show that strong all-angle sound absorption with almost zero reflectance takes place for a frequency range exceeding two octaves. We demonstrate that lowering the crystal filling fraction increases the wave interaction time and is responsible for the enhancement of intrinsic material dissipation, making the system more absorptive with less material.

The symmetry matching between the source and the lens results of fundamental interest for lensing applications. In this work we have modeled an axisymmetric gradient index (GRIN) lens made of rigid toroidal scatterers embedded in air considering this symmetry matching with radially symmetric sources. The sound amplification obtained in the focal spot of the reported lens (8.24 dB experimentally) shows the efficiency of the axisymmetric lenses with respect to the previous Cartesian acoustic GRIN lenses. The axisymmetric design opens new possibilities in lensing applications in different branches of science and technology.

We propose and experimentally demonstrate a novel mechanism of sound wave concentration based on soft reflections in chirped sonic crystals. The reported controlled field enhancement occurs at around particular (bright) planes in the crystal, and is related to a progressive slowing down of the sound wave as it propagates along the material. At these bright planes, a substantial concentration of the energy (with a local increase up to 20 times) was obtained for a linear chirp and for frequencies around the first band gap. A simple couple mode theory is proposed, that interprets and estimates the observed effects. The results are obtained for the case of sound waves and sonic crystals, however they are extendable to other type of waves in modulated host matter.

A theoretical and experimental study of the propagation of sound beams in- and behind three-dimensional sonic crystals at frequencies close to the band edges is presented. An efficient collimation of the beam behind the crystal is predicted and experimentally demonstrated. This effect could allow the design of sources of high spatial quality sound beams.

The effect of the presence of a finite impedance surface on the wave propagation properties of a two-dimensional periodic array of rigid cylinders with their axes perpendicular to the surface is both numerically and experimentally analyzed in this work. In this realistic situation both the incident and the scattered waves interact with these two elements, the surface and the array. The interaction between the excess attenuation effect, due to the destructive interference produced by the superposition of the incident wave and the reflected one by the surface, and the bandgap, due to the periodicity of the array, is fundamental for the design of devices to control the transmission of waves based on periodic arrays. The most obvious application is perhaps the design of Sonic Crystals Noise Barriers. Two different finite impedance surfaces have been analyzed in the work in order to observe the dependence of the wave propagation properties on the impedance of the surface.

Complex Band Structures and Multiple Scattering Theory have been used in this paper to analyze the overlapping of the evanescent waves localized in point defects in Sonic Crystals. The Extended Plane Wave Expansion (EPWE) with supercell approximation gives the imaginary part of the Bloch vectors that produces the decay of the localized modes inside the periodic system. Double-cavities can present a coupling between the evanescent modes localized in the defect, showing a symmetric or antisymmetric modes. When point defects are close, the complex band structures reveal a splitting of the frequencies of the localized modes. Both the real part and the imaginary values of wave vector of the localized modes in the cavities present different values for each localized mode, which gives different properties for each mode. Novel measurements, in very good agreement with analytical data, show the experimental evidences of the symmetric and antisymmetric localized modes for a double-point defect in Sonic Crystals (SC). The investigation on the localization phenomena and the coupling between defects in periodic systems has a fundamental importance both in pure and in applied physics.

The complex band structures calculated using the Extended Plane Wave Expansion (EPWE) reveal the presence of evanescent modes in periodic systems, never predicted by the classical \omega(\vec{k}) methods, providing novel interpretations of several phenomena as well as a complete picture of the system. In this work we theoretically and experimentally observe that in the ranges of frequencies where a deaf band is traditionally predicted, an evanescent mode with the excitable symmetry appears changing drastically the interpretation of the transmission properties. On the other hand, the simplicity of the sonic crystals in which only the longitudinal polarization can be excited, is used to interpret, without loss of generality, the level repulsion between symmetric and antisymmetric bands in sonic crystals as the presence of an evanescent mode connecting both repelled bands. These evanescent modes, obtained using EPWE, explain both the attenuation produced in this range of frequencies and the transfer of symmetry from one band to the other in good agreement with both experimental results and multiple scattering predictions. Thus, the evanescent properties of the periodic system have been revealed necessary for the design of new acoustic and electromagnetic applications based on periodicity.

This work theoretically and experimentally reports the evanescent connections between propagating bands in periodic acoustic materials. The complex band structures obtained by solving for the $k(\omega)$ problem reveal a complete interpretation of the propagation properties of these systems. The prediction of evanescent modes, non predicted by classical $\omega(\vec{k})$ methods, is of interest for the understanding of these propagation properties. Complex band structures provide an interpretation of the evanescent coupling and the level repulsion states showing the possibility to control of evanescent waves in periodic materials.

An acoustic metamaterial made of a two-dimensional (2D) periodic array of multi-resonant acoustic scatterers is analysed in this paper. The building blocks consist of a combination of elastic beams of Low-Density Polyethylene Foam (LDPF) with cavities of known volume. Sound inside the structure can excite elastic resonances of the material as well as acoustic resonances in the cavities producing several attenuation peaks in the low-frequency range. Due to this behaviour at the subwavelength regime we can define this periodic array as a Locally Multi-Resonant Acoustic Metamaterial (LMRAM) presenting strong dispersive characteristics of the effective properties with subwavelength multi-resonant structural units. The results shown in this paper could be use to design effective Sonic Crystal Acoustic Barriers with wide tunable attenuation bands in the low-frequency range.

The physical properties of a periodic distribution of absorbent resonators is used in this work to design a tunable wideband bandstop acoustic filter. Analytical and numerical simulations as well as experimental validations show that the control of the resonances and the absorption of the scatterers along with their periodic arrangement in air introduces high technological possibilities to control noise. Sound manipulation is perhaps the most obvious application of the structures presented in this work. We apply this methodology to develop a device as an alternative to the conventional acoustic barriers with several properties from the acoustical point of view but also with additional aesthetic and constructive characteristics.

The use of Sonic Crystals as environmental noise barriers has certain advantages from the acoustical and the constructive point of view with regard to conventional ones. One aspect do not studied yet is the acoustic interaction between the Sonic Crystals and the ground due to, up to now, this latter is not included in the analytical models used to characterize these Sonic Crystals. We present here an analytical model, based on multiple scattering theory, to study this interaction considering the ground as a finite impedance surface. Using this model we have obtained interesting conclusions that allow to design more effectively noise screens based on Sonic Crystals. The obtained results have been compared with experimental and numerical, finding a good agreement between them.

Research into properties of heterogeneous artificial materials, consisting of arrangements of rigid scatterers embedded in a medium with different elastic properties, has been intense throughout last two decades. The capability to prevent the transmission of waves in predetermined bands of frequencies -called bandgaps- becomes one of the most interesting properties of these systems, and leads to the possibility of designing devices to control wave propagation. The underlying physical mechanism is destructive Bragg interference. Here we show a technique that enables the creation of a wide bandgap in these materials, based on fractal geometries. We have focused our work in the acoustic case where these materials are called Phononic/Sonic Crystals (SC) but, the technique could be applied any types of crystals and wave types in ranges of frequencies where the physics of the process is linear.

Evanescent modes in complete sonic crystals (SC) and SC with point defects are reported both theoretically and experimentally in this paper. Plane wave expansion (PWE) and, in general, $\omega(k)$ methods have been used to calculate band structures showing gaps that have been interpreted as ranges of frequencies where no real $k$ exists. In this work, we extend PWE to solve the complex $k(\omega)$ problem applied to SC, introducing the supercell approximation for studying one vacancy. Explicit matrix formulation of the equations is given. This $k(\omega)$ method enables the calculation of complex band structures, as well as enabling an analysis of the propagating modes related with real values of the function $k(\omega)$, and the evanescent modes related with imaginary values of $k(\omega)$. This paper shows theoretical results and experimental evidences of the evanescent behavior of modes inside the SC band gap. Experimental data and numerical results using the finite elements method are in very good agreement with the predictions obtained using the $k(\omega)$ method., Comment: 15 pages, 3 figures

Using a low-temperature conductive-tip atomic force microscope in cross-section geometry we have characterized the local transport properties of the metallic electron gas that forms at the interface between LaAlO3 and SrTiO3. At low temperature, we find that the carriers do not spread away from the interface but are confined within ~10 nm, just like at room temperature. Simulations taking into account both the large temperature and electric-field dependence of the permittivity of SrTiO3 predict a confinement over a few nm for sheet carrier densities larger than ~6 10^13 cm-2. We discuss the experimental and simulations results in terms of a multi-band carrier system. Remarkably, the Fermi wavelength estimated from Hall measurements is ~16 nm, indicating that the electron gas in on the verge of two-dimensionality., Comment: Accepted for publication in Physical Review Letters

The alpha-beta magneto-structural phase transition in MnAs/GaAs(111) epilayers is investigated by elastic neutron scattering. The in-plane parameter of MnAs remains almost constant with temperature from 100 K to 420 K, following the thermal evolution of the GaAs substrate. This induces a temperature dependent biaxial strain that is responsible for an alpha-beta phase coexistence and, more important, for the stabilization of the ferromagnetic alpha-phase at higher temperature than in bulk. We explain the premature appearance of the beta-phase at 275 K and the persistence of the ferromagnetic alpha-phase up to 350 K with thermodynamical arguments based on the MnAs phase diagram. It results that the biaxial strain in the hexagonal plane is the key parameter to extend the ferromagnetic phase well over room temperature., Comment: 4 pages, 3 figures, accepted for publication in Physical Review Letters

We report on the appearance of magnetic stripes in MnAs/GaAs(100) epilayers at temperatures well below the ferromagnetic transition of the system. The study has been performed by ferromagnetic resonance experiments (FMR) on MnAs epilayers grown on (100) and (111) GaAs substrates. The FMR spectra of the MnAs/GaAs(100) samples at 180 K reveal the appearance of zones of different magnetic behavior with respect to the low-temperature homogeneous ferromagnetic phase. The angular and the temperature dependence of the spectra serve us to detect the inter-growth of the non-magnetic phase into the ferromagnetic phase at a very early stage of the process. The experimental data show that the new phase nucleates in a self-arranged array of stripes in MnAs/GaAs(100) thin films while it grows randomly in the same films grown on GaAs(111)., Comment: 8 pages, 5 figures

The magnetic properties of MnAs epilayers have been investigated for two different substrate orientations: GaAs(100) and GaAs(111). We have analyzed the magnetization reversal under magnetic field at low temperatures, determining the anisotropy of the films. The results, based on the shape of the magnetization loops, suggest a domain movement mechanism for both types of samples. The temperature dependence of the coercivity of the films has been also examined, displaying a generic anomalous reentrant behavior at T$>$200 K. This feature is independent of the substrate orientation and films thickness and may be associated to the appearance of new pinning centers due to the nucleation of the $\beta$-phase at high temperatures., Comment: 9 pages, 7 figures

We report on the use of the LaAlO3 (LAO) high-k dielectric as a tunnel barrier in magnetic tunnel junctions. From tunnel magnetoresistance (TMR) measurements on epitaxial La2/3Sr1/3MnO3/LAO/La2/3Sr1/3MnO3 junctions, we estimate a spin polarization of 77% at low temperature for the La2/3Sr1/3MnO3/LAO interface. Remarkably, the TMR of La2/3Sr1/3MnO3/LAO/Co junctions at low bias is negative, evidencing a negative spin polarization of Co at the interface with LAO, and its bias dependence is very similar to that of La2/3Sr1/3MnO3/STO/Co junctions. We discuss possible reasons for this behaviour., Comment: 14 pages, 3 figures

We have obtained bulk samples of the graphite intercalation compound, CaC6, by a novel method of synthesis from highly oriented pyrolytic graphite. The crystal structure has been completely determined showing that it is the only member of the MC6, metal-graphite compounds, which has rhombohedral symmetry. We have clearly shown the occurrence of superconductivity in the bulk sample at 11.5K, using magnetization measurements., Comment: 8 pages of text + 4 figures = 12 pages