1. Anti-correlation between excitations and locally-favored structures in glass-forming systems
- Author
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Lang, Danqi, Scalliet, Camille, and Royall, C. Patrick
- Subjects
Condensed Matter - Soft Condensed Matter ,Physics - Applied Physics ,Physics - Computational Physics - Abstract
Dynamics that are microscopic in space and time, so-called excitations, are considered the elementary unit of relaxation in the Dynamic Facilitation (DF) theory of the glass transition. Meanwhile, geometric motifs known as locally favored structures (LFS) are associated with vitrification in many glassformers. Recent work indicates that the probability of particles both found in locally favored structures (LFS) and excitations decreases significantly upon supercooling suggesting that there is an anti-correlation between them. [Ortlieb et al, Nature Commun. 14, 2621 (2023)]. However, the spatial relationship between excitations and LFS remains unclear. By employing state-of-the-art GPU computer simulations and colloid experiments, we analyze this relationship between LFS and excitations in model glassformers. We demonstrate that there is a spatial separation between the two in deeply supercooled liquids. This may be due to the fact that LFS are well-packed, thus they are solid and stable.
- Published
- 2024