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The suppression of superconductivity in disordered systems is a fundamental problem of condensed matter physics. Here we investigate the superconducting niobium-titanium-nitride (Nb_{1-x}Ti_{x}N) thin films grown by atomic layer deposition (ALD) where disorder is controlled by the slight tuning of the ALD process parameters. We observe the smooth crossover from the disorder-driven superconductor-normal metal transition (often reffered to as fermionic mechanism) to the case where bosonic mechanism dominates and increasing disorder leads to formation of metal with Cooper pairing. We show that, in moderately disordered films, the transition to zero-resistance state occurs in a full agreement with the conventional theories of superconducting fluctuations and Berezinskii-Kosterlitz-Thouless transition. However, the critically disordered films violate this accord showing low-temperature features possibly indicating the Bose metal phase. We show that it is the interrelation between film's sheet resistance in the maximum, R_{max}, of the resistive curve R(T) and R_q = h/4e^2 that distinguishes between these two behaviors. We reveal the characteristic features in magnetoresistance of the critically disordered films with R_{max} > R_q, Comment: 8 pages, 3 figures

Point contact tunneling (PCT) spectroscopy measurements are reported over wide areas of cm-sized cut outs from niobium superconducting RF cavities. A comparison is made between a high-quality, conventionally processed (CP) cavity with a high field Q drop for acceleration field E $>$ 20 MV/m and a nitrogen doped (N-doped) cavity that exhibits an increasing Q up to fields approaching 15 MV/m. The CP cavity displays hot spot regions at high RF fields where Q-drop occurs as well as unaffected regions (cold spots). PCT data on cold spots reveals a near ideal BCS density of states (DOS) with gap parameters, $\Delta$ as high as 1.62 meV, that are among the highest values ever reported for Nb. Hot spot regions exhibit a wide distribution of gap values down to $\Delta \sim$ 1.0 meV and DOS broadening characterized by a relatively large value of pair-breaking rate, $\Gamma$, indicating surface regions of significantly reduced superconductivity. In addition, hot spots commonly exhibit Kondo tunneling peaks indicative of surface magnetic moments attributed to a defective oxide. N-doped cavities reveal a more homoegeneous gap distribution centered at $\Delta \sim$ 1.5 meV and relatively small values of $\Gamma/\Delta$. The absence of regions of significantly reduced superconductivity indicates that the N interstitials are playing an important role in preventing the formation of hydride phases and other macroscopic defects which might otherwise severely affect the local, surface superconductivity that lead to hot spot formation. The N-doped cavities also display a significantly improved surface oxide, i.e., increased thickness and tunnel barrier height, compared to CP cavities. These results help explain the improved performance of N-doped cavities and give insights into the origin of the initial increasing Q with RF amplitude.

Point contact tunneling (PCT) and low energy muon spin rotation (LE-muSR) are used to probe, on the same samples, the surface superconducting properties of micrometer thick niobium films deposited onto copper substrates using different sputtereing techniques: diode, dc magnetron (dcMS) and HIPIMS. The combined results are compared to radio-frequency tests performances of RF cavities made with the same processes. Degraded surface superconducting properties are found to yield lower quality factors and stronger Q slope. In addition, both techniques find evidence for surface paramagnetism on all samples and particularly on Nb films prepared by HIPIMS.

High purity niobium (Nb), subjected to the processing methods used in the fabrication of superconducting RF cavities, displays micron-sized surface patches containing excess carbon. High-resolution transmission electron microscopy and electron energy-loss spectroscopy measurements are presented which reveal the presence of nanoscale NbC coherent precipitates in such regions. Raman backscatter spectroscopy on similar surface regions exhibit spectra consistent with the literature results on bulk NbC but with significantly enhanced two-phonon scattering. The unprecedented strength and sharpness of the two-phonon signal has prompted a theoretical analysis, using density functional theory (DFT), of phonon modes in NbC for two different interface models of the coherent precipitate. One model leads to overall compressive strain and a comparison to ab-initio calculations of phonon dispersion curves under uniform compression of the NbC shows that the measured two-phonon peaks are linked directly to phonon anomalies arising from strong electron-phonon interaction. Another model of the extended interface between Nb and NbC, studied by DFT, gives insight into the frequency shifts of the acoustic and optical mode density of states measured by first order Raman. The exact origin of the stronger two-phonon response is not known at present but it suggests the possibility of enhanced electron-phonon coupling in transition metal carbides under strain found either in the bulk NbC inclusions or at their interfaces with Nb metal. Preliminary tunneling studies using a point contact method show some energy gaps larger than expected for bulk NbC., Comment: Phys. Rev. B, accepted

Large-grain Nb has become a viable alternative to fine-grain Nb for the fabrication of superconducting radio-frequency cavities. In this contribution we report the results from a heat treatment study of a large-grain 1.5 GHz single-cell cavity made of "medium purity" Nb. The baseline surface preparation prior to heat treatment consisted of standard buffered chemical polishing. The heat treatment in the range 800 - 1400 C was done in a newly designed vacuum induction furnace. Q0 values of the order of 2x1010 at 2.0 K and peak surface magnetic field (Bp) of 90 mT were achieved reproducibly. A Q0-value of (5+-1)1010 at 2.0 K and Bp = 90 mT was obtained after heat treatment at 1400 C. This is the highest value ever reported at this temperature, frequency and field. Samples heat treated with the cavity at 1400 C were analyzed by secondary ion mass spectrometry, secondary electron microscopy, energy dispersive X-ray, point contact tunneling and X-ray diffraction and revealed a complex surface composition which includes titanium oxide, increased carbon and nitrogen content but reduced hydrogen concentration compared to a non heat-treated sample.

In our article [1], we found that with increasing dissipation there is a clear, systematic shift and sharpening of the conductance peak along with the disappearance of the higher-bias dip/hump features (DHF), for a stack of intrinsic Josephson junctions (IJJs) of intercalated Bi2Sr2CaCu2O8+{\delta} (Bi2212). Our work agrees with Zhu et al [2] on unintercalated, pristine Bi2212, as both studies show the same systematic changes with dissipation. The broader peaks found with reduced dissipation [1,2] are consistent with broad peaks in the density-of-states (DOS) found among scanning tunneling spectroscopy [3] (STS), mechanical contact tunneling [4] (MCT) and inferred from angle (momentum) resolved photoemission spectroscopy [5] (ARPES); results that could not be ignored. Thus, sharp peaks are extrinsic and cannot correspond to the superconducting DOS. We suggested that the commonality of the sharp peaks in our conductance data, which is demonstrably shown to be heating-dominated, and the peaks of previous intrinsic tunneling spectroscopy (ITS) data implies that these ITS reports might need reinterpretation., Comment: Rebuttal to Comment of Krasnov arXiv:1007.4510

Anomalously high and sharp peaks in the conductance of intrinsic Josephson junctions in Bi$_{2}$Sr$_{2}$CaCu$_{2}$O$_{8+\delta}$ (Bi2212) mesas have been universally interpreted as superconducting energy gaps, but here we show they are a result of heating. This interpretation follows from a direct comparison to the equilibrium gap, $\mathit \Delta$, measured in break junctions on similar Bi2212 crystals. As the dissipated power increases with a greater number of junctions in the mesa, the conductance peak abruptly sharpens and its voltage decreases to well below 2$\mathit \Delta$. This sharpening, found in our experimental data, defies conventional intuition of heating effects on tunneling spectra, but it can be understood as an instability into a nonequilibrium two-phase coexistent state. The measured peak positions occur accurately within the voltage range that an S-shaped backbending is found in the {\it calculated} current-voltage curves for spatially {\it uniform} self-heating and that S-shape implies the potential for the uniform state to be unstable., Comment: 10 pages, 7 figures

A method to treat the surface of Nb is described which potentially can improve the performance of superconducting RF cavities. We present tunneling and x-ray photoemission spectroscopy (XPS) measurements at the surface of cavity-grade niobium samples coated with a 3 nm alumina overlayer deposited by Atomic Layer Deposition (ALD). The coated samples baked in ultra high vacuum (UHV) at low temperature reveal at first degraded superconducting surface. However, at temperatures above 450C, the tunneling conductance curves show significant improvements of the superconducting density of states (DOS) compared with untreated surfaces., Comment: 3 pages, 2 figures

Tunneling spectroscopy was performed on Nb pieces prepared by the same processes used to etch and clean superconducting radio frequency (SRF) cavities. Air exposed, electropolished Nb exhibited a surface superconducting gap delta=1.55 meV, characteristic of clean, bulk Nb. However the tunneling density of states (DOS) was broadened significantly. The Nb pieces treated with the same mild baking used to improve the Q-slope in SRF cavities, reveal a sharper DOS. Good fits to the DOS were obtained using Shiba theory, suggesting that magnetic scattering of quasiparticles is the origin of the gapless surface superconductivity and a heretofore unrecognized contributor to the Q-slope problem of Nb SRF cavities., Comment: 3 pages, 3 figures

We report a simple method for the fabrication of Niobium superconducting (SC) tips for scanning tunnelling microscopy which allow atomic resolution. The tips, formed in-situ by the mechanical breaking of a niobium wire, reveal a clear SC gap of 1.5 meV and a critical temperature Tc=9.2+-0.3 K as deduced from Superconductor Insulator Normal metal (NIS) and Superconductor Insulator Superconductor (SIS) spectra. These match the values of bulk Nb samples. We systematically find an enhanced value of the critical magnetic field in which superconductivity in the tip is destroyed (around 1 T for some tips) up to five times larger than the critical field of bulk Nb (0.21 T). Such enhancement is attributed to a size effect at the tip apex, Comment: to appear in Physica C