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Growth of helium bubbles near the surface of metals leads to various morphology changes when sufficient helium ions are continuously implanted on the surface. In this study, low energy (< 100 eV) helium plasma irradiations to various noble metals were conducted, and consequent surface morphology changes were analyzed. It was found that fiberform nanostructures were formed by the helium plasma irradiation on rhodium and ruthenium thin films, which were deposited by magnetron sputtering, and on platinum and iridium wires. Growth of fiberform structures were not identified on gold, silver, and palladium samples exposed to helium plasmas even though the irradiations were conducted at various surface temperatures, though pinholes were observed on palladium surface. We discussed the relation between the morphology changes and material properties., ファイル公開：2020-04-25

This overview presents recent results regarding hydrogen isotope absorption and emission dynamics in neutron-irradiated tungsten (W) using our recently developed Compact Diverter Plasma Simulator (CDPS), a linear plasma device in a radiation-controlled area. Neutron irradiation to 0.016 - 0.06 displacement per atom resulted in a significant increase in deuterium (D) retention due to trapping effects of radiation-induced defects. We analyzed the dependency of D retention on the D plasma fluence by exposing neutron-irradiated pure W to D plasma at 563 K over a range of D fluence values. The total retention was revealed to be proportional to the square root of D fluence, indicating that the implanted D atoms first occupy the defects caused by neutron-irradiation near the surface and then the defects located in deeper regions. We further investigated the effects of post-plasma annealing on D emission; neutron-irradiated pure W was exposed to D plasma at 573 K and was then annealed at the same temperature for 30 hours. Approximately 10% of the absorbed D was released by annealing, suggesting that a heat treatment of the plasma-facing component of a fusion reactor at moderately elevated temperatures could contribute to the removal of accumulated hydrogen isotopes. The experimental results obtained in this study were only available by investigating neutron-irradiated specimens with the CDPS system, which will be essential for future studies of material behavior and plasma-wall interactions in the fusion reactor environment.

The Large Helical Device (LHD) started the deuterium plasma experiment on March 7, 2017. Approximately 6.4 GBq of tritium was produced in the first deuterium plasma experiment campaign and were utilized as tracers for the investigation of release behavior and the balance of tritium in the LHD vacuum vessel. To determine the tritium balance in LHD, the tritium release from the vacuum vessel was continually observed during the plasma experiment period and the vacuum vessel maintenance activities. The tritium exhaust rate was approximately 32.8% at the end of the plasma experiment. After the plasma experiment, the vacuum vessel was ventilated by room air for the maintenance activity and the tritium release from the in-vessel components was observed. The tritium release rate gradually decreased and became constant after four-month in spite of water vapor concentration. It is suggested that the tritium release mechanism from the vacuum vessel is a diffusion-limited process from the bulk. The tritium release amount during the maintenance activity for one year was approximately 5.0%. Considering the decrease of tritium decay for 1.5 years, tritium inventory in LHD was estimated to be approximately 3.66 GBq (57.2%) at the end of maintenance activity.

A tungsten (W) deposition layer is formed while a sample is exposed to a helium (He) plasma at the surface temperature of 473 or 573 K. The formed He-W co-deposition layer was composed of fine grains, the size of which increased with the surface temperature. The samples with the co-deposition layer was exposed to a deuterium (D2) plasma, and the D retention was investigated using thermal desorption spectroscopy. It was found that the co-deposition layer has quite different D retention characteristics compared with bulk W.

We have developed a compact divertor plasma simulator (CDPS) that can produce steady-state deuterium and/or helium plasmas with densities above ∼ 1018 m−3 for Plasma-Wall Interaction (PWI) studies of neutron-irradiated materials. The maximum particle flux is about 1022 m−2s−1. The CDPS was installed and is being operated in the radiation-controlled area of the International Research Center for Nuclear Materials Science, Institute for Materials Research, Tohoku University. We are able to control sample temperature within uncertainty of 5 °C during plasma exposure by adjusting the cooling air flow rate to the sample holder. The CDPS has a sample-carrier system, which makes it possible to transfer a plasma-irradiated sample from the sample holder to an infrared heater for analysis using thermal desorption spectroscopy (TDS) without exposing it to the air. This avoids the oxidation of the sample and minimizes the time between the end of plasma exposure and TDS analysis. An ITER-like tungsten (W) sample (A.L.M.T. Corp.), which has been irradiated by neutrons to 0.06 dpa in a fission reactor, was exposed to a deuterium plasma in the CDPS. The experimental results clearly show that the total deuterium retention in the neutron-irradiated W sample increases significantly in comparison with a pristine W, as demonstrated by broadening of the TDS spectrum at high temperatures.

As the finalization of a hydrogen experiment towards the deuterium phase, the exploration of the best performance of hydrogen plasma was intensively performed in the large helical device. High ion and electron temperatures, Ti and Te, of more than 6 keV were simultaneously achieved by superimposing high-power electron cyclotron resonance heating onneutral beam injection (NBI) heated plasma. Although flattening of the ion temperature profile in the core region was observed during the discharges, one could avoid degradation by increasing the electron density. Another key parameter to present plasma performance is an averaged beta value $\left\langle \beta \right\rangle $ . The high $\left\langle \beta \right\rangle $ regime around 4% was extended to an order of magnitude lower than the earlier collisional regime. Impurity behaviour in hydrogen discharges with NBI heating was also classified with a wide range of edge plasma parameters. The existence of a no impurity accumulation regime, where the high performance plasma is maintained with high power heating >10 MW, was identified. Wide parameter scan experiments suggest that the toroidal rotation and the turbulence are the candidates for expelling impurities from the core region.

A fiberform nanostructured layer is formed on a tungsten (W) surface using helium (He) plasma irradiation. The behavior of the nanostructures and He bubbles were observed during annealing via in situ transmission electron microscopy. Notable changes in the nanostructures occurred at 1223 K. A collapse of the nanostructures was observed along with a collapse of the He bubbles during annealing.

Nanostructured tungsten formed by the exposure to helium plasma in a linear plasma device was installed in the large helical device (LHD). After the exposure in a series of experiments in the 2012 fiscal year campaign in LHD, the samples were analyzed by scanning electron microscope (SEM), transmission electron microscope (TEM), and energy dispersion x-ray spectroscopy (EDX). It was found that part of the nanostructures was totally covered with carbon based material probably from divertor, while some other parts were eroded by sputtering. On the erosion dominant region, it was revealed that the head part of nanostructures was sputtered and the surface became rounded, but the nanostructures still remained near the surface. Optical reflectance of the material was measured, and it was found that the morphology changes increased the optical reflectivity up to ∼10% from typically less than 1%. The possibility and limitation of the nanostructured tungsten as a light absorber (viewing dump) are discussed.