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Start Over Author "Dubois, Lionel" Topic conformational analysis
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1. Water soluble cryptophanes showing unprecedented affinity for xenon: Candidates as NMR-based biosensors

Author

Huber, Gaspard, Brotin, Thierry, Dubois, Lionel, Desvaux, Harve, Dutasta, Jean-Pierre, and Berthault, Patrick

Subjects
Aqueous solution reactions -- Analysis, Xenon -- Chemical properties, Nuclear magnetic resonance spectroscopy -- Usage, Conformational analysis, Chemistry
Abstract

The structural and dynamical behaviors of the cryptophanes bearing molecules as well as their interaction with xenon are studied by using [.sup.1.H] and [.sup.128.Xe] NMR. The host molecules are shown to exist in aqueous solution under different conformations in very slow exchange whereas the cryptophanes in such conformation are unable to complex xenon.

Published
2006

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