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The two title crystalline compounds, viz. meso-bis{η5-1-[1-(dimethylamino)ethenyl]-3-(trimethylsilyl)cyclopentadienyl}iron(II), [Fe(C12H20NSi)2], (II), and meso-bis{η5-1-[1-(dimethylamino)ethenyl]-3-(trimethylsilyl)cyclopentadienyl}cobalt(II), [Co(C12H20NSi)2], (III), were obtained by the reaction of lithium 1-[1-(dimethylamino)ethenyl]-3-(trimethylsilyl)cyclopentadienide with FeCl2 and CoCl2, respectively. For (II), the trimethylsilyl- and dimethylaminoethenyl-substituted cyclopentadienyl (Cp) rings present a nearly eclipsed conformation, and the two pairs of trimethylsilyl and dimethylaminoethenyl substituents on the Cp rings are arranged in an interlocked fashion. In the case of (III), the same substituted Cp rings are perfectly staggered leading to a crystallographically centrosymmetric molecular structure, and the two trimethylsilyl and two dimethylaminoethenyl substituents are oriented in opposite directions, respectively, with the trimethylsilyl group of one Cp ring and the dimethylaminoethenyl group of the other Cp ring arranged more closely than in (II). [ABSTRACT FROM AUTHOR]

The title compound, C20H17N5, has two mol­ecules in the asymmetric unit with comparable conformations. In each mol­ecule, the isoindoline group and one methyl­pyridyl ring are coplanar, while the other methyl­pyridyl rings form angles with respect to these planes of 43.2 (2) and 37.6 (2)°. [ABSTRACT FROM AUTHOR]