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Aiming at the problem of chemical-mechanics-hydro (C-M-H) action encountered by rocks in underground engineering, chemical damage variables, water damage variables, and force damage variables are introduced to define the degree of degradation of rock materials. Stone is selected as the sample for acid corrosion treatment at pH 3, 4, and 7, and a chemical damage factor is defined that coupled the pH value and duration of exposure. Then based on the spatial mobilized plane (SMP) criterion and the Lemaitre strain equivalence hypothesis, this research develops a constitutive model considering rock chemical corrosion-water-confining pressure damage. The proposed damage constitutive model employs the extremum method to ascertain the two Weibull distribution parameters (m and F0) by theoretical derivation and exhibits satisfactory conformity between the theoretical and experimental curves. The damage constitutive model can be consistent in the stress–strain characteristics of the rock triaxial compression process, which verifies the rationality and reliability of the model parameters. The model effectively represents the mechanical properties and damage characteristics of rocks when subjected to the combined influence of water chemistry and confinement. The presented model contributes to a better understanding of tangible rock-engineered structures subjected to chemical corrosion in underwater environments. [ABSTRACT FROM AUTHOR]

Aiming at the acid-etched freeze-thaw rock for geotechnical engineering in cold regions, chemical damage variables, freeze-thaw damage variables, and force damage variables were introduced to define the degree of degradation of rock materials, the law of damage evolution, the total damage variable of acid-corroded rock under the coupling action of freeze-thaw and confining pressure was deduced. The continuous damage mechanics theory was adopted to derive the damage evolution equation and constitutive model of acid-eroded rock under the coupling action of freeze-thaw and confining pressure. The theoretical derivation method was used to obtain the required model parameter expressions. Finally, the model's rationality and accuracy were verified by the triaxial compression test data of frozen-thawed rocks. Comparing the test curve's peak point with the peak point of the model theoretical curve, the results show that the two are in suitable agreement. The damage constitutive model can better reflect the stress-strain peak characteristics of rock during triaxial compression, verifying the rationality and reliability of the model and the method for determining the model parameters. The model extends the damage model of rock under the coupling action of freeze-thaw and confining pressure in the chemical environment and further reveals the damage mechanism and failure law of acid-corroded rock under the coupling action of freeze-thaw and confining pressure. [ABSTRACT FROM AUTHOR]

Based on Lemaitre's strain equivalence hypothesis theory, it is assumed that the strength of acid-etching rock microelements under the coupling effect of temperature and confining pressure follows the Weibull distribution. Under the hypothesis that micro-element damage meets the D-P criterion and based on continuum damage mechanics and statistical theory, chemical damage variables, thermal damage variables and mechanical damage variables were introduced in the construction of damage evolution equations and constitutive models for acid-etching rocks considering the coupled effects of temperature and confining pressure. The required model parameters were obtained by theoretical derivation, and the model was verified based on the triaxial compression test data of granite. Comparing the experimental stress-strain curve with the theoretical stress-strain curve, the results show that they were in good agreement. By selecting reasonable model parameters, the damage statistical constitutive model can accurately reflect the stress-strain curve characteristics of rock in the process of triaxial compression. The comparison between the experimental and theoretical results also verifies the reasonableness and reliability of the model. This model provides a new rock damage statistical constitutive equation for the study of rock mechanics and its application in engineering, and has certain reference significance for rock underground engineering. [ABSTRACT FROM AUTHOR]

Under the influence of external factors such as high temperature, chemical corrosion, and loading-unloading cycles, micro-cracks and pores may develop within rock structures. Continuum damage mechanics (CDM) characterizes these micro-defects arising within rocks, investigating the physico-mechanical behaviors of rocks in damaged states. This study, grounded in the theoretical framework of CDM and utilizing the Mohr-Coulomb failure criterion, integrates different probability distributions and damage coupling methods to develop three statistical damage models. The investigation primarily explores the effects of strength criteria, probability functions, and damage coupling mechanisms on the statistical damage models. In addressing the complex interplay between rock micro-defects and external stressors such as high temperatures and chemical corrosion, this study leverages the principles of CDM within the Mohr-Coulomb criterion framework. It advances the field by developing three innovative statistical damage models, enriched by diverse probability distributions and damage coupling methods. The research delineates the substantial impact of strength criteria, probability functions, and damage coupling mechanisms on the behavior of these models. Notably, it achieves a synthesis of theoretical constructs and experimental validation, demonstrating the models' capacity to reflect the nuanced behaviors of damaged rock accurately. Furthermore, this investigation contributes a methodological blueprint for statistical damage model construction, underscoring the critical selection of strength criteria and probability distributions. These efforts fortify the theoretical underpinnings necessary for the enhanced engineering application of statistics-driven damage analysis. • Novel statistical damage models for rocks developed by Continuum Damage Mechanics and Mohr-Coulomb criteria. • Comparative analysis of statistical damage constitutive models considering different forms of coupled total damage. • Comprehensive stress-strain analysis performed without segmentation or empirical fitting. • Models based on Weibull and power function distributions for enhanced physical interpretability. • Effective prediction of rock behavior in engineering applications. [ABSTRACT FROM AUTHOR]