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1. Increased catalytic activity of surface-immobilized palladium complexes in the fluorogenic deprotection of an alloc-derivatized coumarin.

Author

Fernandes A, Hensenne P, Mathy B, Guo W, Nysten B, Jonas AM, and Riant O

Subjects
Catalysis, Coordination Complexes chemistry, Coumarins chemistry, Molecular Structure, Coordination Complexes chemical synthesis, Coumarins chemical synthesis, Palladium chemistry, Silicon chemistry
Abstract

Catalytic surfaces have been prepared by complexation of palladium on self-assembled terpyridine monolayers on silicon. A reaction-based fluorogenic probe was developed to allow facile visualization of the catalytic potential of the surface. Superior activity of the immobilized catalyst compared with the homogeneous control reactions is demonstrated., (Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)

Published
2012
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