1. Glass-phase coordination polymer displaying proton conductivity and guest-accessible porosity
- Author
-
Satoshi Horike, Chinmoy Das, Kayako Honjo, Yusuke Nishiyama, Susumu Kitagawa, and Munehiro Inukai
- Subjects
Materials science ,Proton ,Extended X-ray absorption fine structure ,010405 organic chemistry ,Coordination polymer ,Metals and Alloys ,General Chemistry ,Conductivity ,010402 general chemistry ,01 natural sciences ,Pyrophosphate ,Catalysis ,0104 chemical sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Ion ,chemistry.chemical_compound ,chemistry ,Chemical engineering ,Phase (matter) ,Materials Chemistry ,Ceramics and Composites ,Porosity - Abstract
We describe the preparation of the crystalline and glassy state of a coordination polymer displaying proton conduction and guest-accessible porosity. EXAFS and solid-state NMR analyses indicated that pyrophosphate and phosphate ions are the main proton transporters in the glass and that homogeneously distributed 5-chloro-1H-benzimidazole in the glass provides the porosity.
- Published
- 2019