1. Three Cd(II) coordination polymers based on a pyridyldicarboxylate: effect of coordinated water.
- Author
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Zhou, Hui-Fang, Wang, Zi-Yu, Liu, Bo, Wen, Gui-Lin, and Wang, Yao-Yu
- Subjects
CADMIUM compounds ,COORDINATION polymers ,CARBOXYLATES ,WATER chemistry ,PHTHALIC acid - Abstract
By systematic change of the solvothermal synthesis, three new coordination polymers, [Cd(L)∙(H
2 O)]∙2H2 O (1), [Cd(L)∙(H2 O)]∙H2 O (2), and [Cd(L)] (3), have been synthesized based on a tritopic ligand 4-(pyridin-3-yl)isophthalic acid (H2 L). Compounds 1 and 2 show very similar two-dimensional (2D) bilayers further linked by interlayer hydrogen bonds into three-dimensional (3D) supramolecular structures, while 3 displays a 3D structure constructed form one-dimensional (1D) Cd-carboxyl chains. Notably, 1 and 2 have a pair of unusual isomers with the opposite orientation of coordinated H2 O on the metal centers, leading to different hydrogen bonding interactions. Thermal stabilities and solid-state photoluminescences for 1-3 were also investigated. [ABSTRACT FROM AUTHOR]- Published
- 2018
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