1. Uniaxial deformation of an elastomer nanocomposite containing modified carbon nanofibers by in situ synchrotron X-ray diffraction
- Author
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Kelarakis, Antonis, Yoon, Kyunghwan, Sics, Igors, Somani, Rajesh H., Hsiao, Benjamin S., and Chu, Benjamin
- Subjects
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ELASTOMERS , *ETHYLENE , *PROPENE , *COPOLYMERS , *SYNCHROTRONS - Abstract
Abstract: Structure and property of a nanocomposite consisting of modified carbon nanofibers (MCNFs), homogenously dispersed in an elastomeric ethylene/propylene (EP) random copolymer (84.3wt% P) matrix, were studied by in situ synchrotron X-ray diffraction during uniaxial deformation. The MCNF acted as a nucleating agent for crystallization of the α-form of isotactic polypropylene (iPP) in the matrix. During deformation at room temperature, strain-induced crystallization took place, while the transformation from the γ phase to α phase also occurred for both unfilled and 10wt% MCNF-filled samples. The tensile strength of the filled material was consistently higher than that of pure copolymer. However, when compared with pure copolymer, the highly stretched nanocomposite exhibited a higher amount of unoriented crystals, a lower degree of crystal orientation and a higher amount of γ crystals. This behavior indicated that polymer crystals in the filled nanocomposite experienced a reduced load, suggesting an effective load transfer from the matrix to MCNFs. At elevated temperatures, the presence of MCNFs resulted in a thermally stable physically cross-linked network, which facilitated strain-induced crystallization and led to a remarkable improvement in the mechanical properties. For example, the toughness of the 10wt% nanocomposite was found to increase by a factor of 150 times at 55°C. [Copyright &y& Elsevier]
- Published
- 2005
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