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Start Over Author "De Winter T" Topic copper catalysts
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1. Heterogeneous copper-catalyzed direct reduction of C-glycosidic enones to saturated alcohols in water.

Author

Petitjean, L., de Winter, T. M., Petrovic, P. V., Coish, P., Hitce, J., Moreau, M., Bordier, T., Erythropel, H. C., and Anastas, P. T.

Subjects
*HETEROGENEOUS catalysis, *COPPER catalysts, *ALCOHOLS (Chemical class)
Abstract

We report a novel method for the reduction of α,β-unsaturated enones to the corresponding fully saturated alcohols in a single procedure. Remarkably, the method employs a heterogeneous copper catalyst in water and only requires resin-treatment for isolation of C-glycosidic alcohols as pure, diastereomeric mixtures. Our methodology was applied to the reduction of aromatic and aliphatic enones which furnished a library of C-glycosidic saturated alcohols from renewable sugars via a green and sustainable approach. [ABSTRACT FROM AUTHOR]

Published
2019
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