1. Synthesis and characterization of a coupled binuclear [Cu.sup.I]/[Cu.sup.III] complex
- Author
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Garcia-Lopez, Jesus, Yanez-Rodriguez, Victor, Roces, Laura, Garcia-Granda, Santiago, Martinez, Ana, Guevara-Garcia, Alfredo, Castro, German R., Jimenez-Villacorta, Felix, Iglesias, Maria J., and Ortiz, Fernando Lopez
- Subjects
Copper compounds -- Structure ,Copper compounds -- Chemical properties ,Ring formation (Chemistry) -- Analysis ,Organolithium compounds -- Structure ,Organolithium compounds -- Chemical properties ,Oxidation-reduction reaction -- Analysis ,Phosphazo compounds -- Structure ,Phosphazo compounds -- Chemical properties ,Chemistry - Abstract
The synthesis via reaction of [C.sub.[alpha],[C.sub.ortho] dilithiated phosphazene with CuBr and structural characterization of the binuclear mixed valence [[Cu.sup.I]([N.sub.2])/[Cu.sup.III]([C.sub.4])] complex displaying a metal-metal bond, as well as its applications in cyclopropanation and oxidation reactions, are described.
- Published
- 2010